Rapid detection and risk assessment of soil contamination at lead smelting site based on machine learning

A general prediction model for seven heavy metals was established using the heavy metal contents of 207soil samples measured by a portable X-ray fluorescence spectrometer(XRF)and six environmental factors as model correction coefficients.The eXtreme Gradient Boosting(XGBoost)model was used to fit the relationship between the content of heavy metals and environment characteristics to evaluate the soil ecological risk of the smelting site.The results demonstrated that the generalized prediction model developed for Pb,Cd,and As was highly accurate with fitted coefficients(R^(2))values of 0.911,0.950,and 0.835,respectively.Topsoil presented the highest ecological risk,and there existed high potential ecological risk at some positions with different depths due to high mobility of Cd.Generally,the application of machine learning significantly increased the accuracy of pXRF measurements,and identified key environmental factors.The adapted potential ecological risk assessment emphasized the need to focus on Pb,Cd,and As in future site remediation efforts.

CHANGES OF ATMOSPHERIC CO_2, PHOTOSYNTHESIS OF THE GRASS LAYER AND SOIL CO_2 EVOLUTION IN A TYPICAL TEMPERATE DECIDUOUS FOREST STAND IN THE MOUNTAINOUS AREAS OF BEIJING

Middle-sized chambers (40cmx40cmx20 cm) and an infrared gas analyzer (IRGA) were used for the measurement of net photosynthesis of the grass layer and soil CO2 evolution, in Quercus liaotungensis Koidz. forest, which is a typical temperate forest ecosystem in the mountainous areas of Beijing. Changes of CO2 concentrations in both the atmosphere (2m above canopy) and the forest canopy (2m below the top of the canopy) together with those of net photosynthesis and soil CO2 evolution were also examined, in order to find the characteristics of CO2 exchange between the different components of the temperate forest ecosystem and the atmosphere. Atmospheric CO2 averaged (323+10) and (330+1) mol mol-1 respectively in summer and autumn. During the 24-hour measurements, large differences as much as -46 and -61 mol mol-1 respectively in the atmosphere and forest were found. Net photosynthesis of the grass layer in summer was (2. 59 9+ 1.05) mol CO2 m-2 S-1, two times of that in autumn, (1.31+0.39) mol CO2 s-1 In summer, there was much more CO2 evolved from soil than in autumn, averaging (5.18+0.75) mol CO2 m-2 s-1 and (1.96 + 0.57) (mol CO2 m-2 s-1, respectively. A significant correlation was found between soil CO2 evolution and ground temperature, with F =-0.864 2+0.310 1X,r=0.7164, P<0.001 (n=117). Both the minimal atmospheric CO2 level and the maximum net photosynthesis occurred around 14:00; and an increase in atmospheric CO2 and of soil CO2 evolution during night times were also found to be remarkable.

光辉灿烂带来的污染

19世纪70年代后期,美国发明家爱迪生通过电能、光能转换实验,制造出了相当于同时点燃数百根蜡烛亮度的白炽灯泡。此后又经过10年的努力,实现了集中供电,形成大范围的电灯照明系统,为世界带来了一片光明。

EXAMINATION OF SILICATE LIMITATION OF PRIMARY PRODUCTION IN JIAOZHOU BAY, CHINA I. SILICATE BEING A LIMITING FACTOR OF PHYTOPLANKTON PRIMARY PRODUCTION

Jiaozhou Bay data collected from May 1991 to February 1994, in 12 seasonal investigations, and provided the authors by the Ecological Station of Jiaozhou Bay, were analyzed to determine the spatiotemporal variations in temperature, light, nutrients (NO - 3 N, NO - 2 N, NH + 4 N, SiO 2- 3 Si, PO 3- 4 P), phytoplankton, and primary production in Jiaozhou Bay. The results indicated that only silicate correlated well in time and space with, and had important effects on, the characteristics, dynamic cycles and trends of, primary production in Jiaozhou Bay. The authors developed a corresponding dynamic model of primary production and silicate and water temperature. Eq.(1) of the model shows that the primary production variation is controlled by the nutrient Si and affected by water temperature; that the main factor controlling the primary production is Si; that water temperature affects the composition of the structure of phytoplankton assemblage; that the different populations of the phytoplankton assemblage occupy different ecological niches for C , the apparent ratio of conversion of silicate in seawater into phytoplankton biomas and D , the coefficient of water temperature’s effect on phytoplankton biomass. The authors researched the silicon source of Jiaozhou Bay, the biogeochemical sediment process of the silicon, the phytoplankton predominant species and the phytoplankton structure. The authors considered silicate a limiting factor of primary production in Jiaozhou Bay, whose decreasing concentration of silicate from terrestrial source is supposedly due to dilution by current and uptake by phytoplankton; quantified the silicate assimilated by phytoplankton, the intrinsic ratio of conversion of silicon into phytoplankton biomass, the proportion of silicate uptaken by phytoplankton and diluted by current; and found that the primary production of the phytoplankton is determined by the quantity of the silicate assimilated by them. The phenomenon of apparently high plant nutrient concentrations but low phytoplankton biomass in some waters is reasonably explained in this paper.

Application of first order rate kinetics to explain changes in bloom toxicity——the importance of understanding cell toxin quotas

Cyanobacteria are oxygenic photosynthetic Gram-negative bacteria that can form potentially toxic blooms in eutrophic and slow flowing aquatic ecosystems. Bloom toxicity varies spatially and temporally, but understanding the mechanisms that drive these changes remains largely a mystery. Changes in bloom toxicity may result from changes in intracellular toxin pool sizes of cyanotoxins with differing molecular toxicities, and/or from changes in the cell concentrations of toxic and non-toxic cyanobacterial species or strains within bloom populations. We show here how first-order rate kinetics at the cellular level can be used to explain how environmental conditions drive changes in bloom toxicity at the ecological level. First order rate constants can be calculated for changes in cell concentration( μ_c : specific cell division rate) or the volumetric biomass concentration( μ_g : specific growth rate) between short time intervals throughout the cell cycle. Similar first order rate constants can be calculated for changes in nett volumetric cyanotoxin concentration( μ_(tox) : specific cyanotoxin production rate) over similar time intervals. How μ_c(or μ_g) covaries with μ tox over the cell cycle shows conclusively when cyanotoxins are being produced and metabolised, and how the toxicity of cells change in response to environment stressors. When μ_(tox)/μ_c >1, cyanotoxin cell quotas increase and individual cells become more toxic because the nett cyanotoxin production rate is higher than the cell division rate. When μ_(tox)/μ_c =1, cell cyanotoxin quotas remains fixed because the nett cyanotoxin production rate matches the cell division rate. When μ_(tox)/μ_c <1, the cyanotoxin cell quota decreases because either the nett cyanotoxin production rate is lower than the cell division rate, or metabolic breakdown and/or secretion of cyanotoxins is occurring. These fundamental equations describe cyanotoxin metabolism dynamics at the cellular level and provide the necessary physiological background to understand how environmental stressors drive changes in bloom toxicity.

Microfluidic technology for multiphase emulsions morphology adjustment and functional materials preparation

Multiphase emulsions could be used as templates in considerable fields such as coating, optical materials, stan- dard particles and biomedicine. Among various emulsion forming methods, microfluidic technology, with good monodispersity, high controllability and operation simplicity, has been widely used in the preparation of multi- phase emulsions with different systems. This review would focus on the basic principles of forming multiphase emulsions, the recent progress in controlling multiphase flow in microfluidics, and preparation of functional ma- terials with microfluidics mainly by the authors＇ research group. We believe that the review will contribute to the readers in this prospective area very well. ~ 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.

Chlorophyll-a Fluorescence in Ecology： Theoretical Considerations and Examples around Marine Macroalgae

Over the last decades, the usage of PAM （pulse amplitude modulated） fluorometers for assessment of chlorophyll-a fluorescence variations became widely applied on marine macroalgae physiology and ecophysiology researches. Due to the increased use of these methods, a large number of studies, mainly relating to macroalgae ecology and physiology were worldwide reported. In this context, it was also created a mismatch of concepts about fluorescence of the chlorophyll-a and its application. Under this background, this study compile and summarize the state of the art knowledge regarding to the chlorophyll fluorescence, contextualizing the use of the PAM method with the main factors regulating photosynthesis （light, temperature, salinity nitrogen and phosphorus） in marine macroalgae. Moreover, this study also references the most used terms and shows some examples found in literature about the applicability of fluorescence parameters. The herein findings and the discussed examples, helps to emphasize the importance of fluorescence usage, that highlights the understanding of photosynthetic responses in macroalgal physiology and ecology.

Photo-induced self-formation of dual-cocatalysts on semiconductor surface

Cocatalyst plays key roles in photogenerated charge separation and surface catalytic reactions in photocatalysis.However,it is not clear if the chemical states of cocatalysts changed or remains unchanged under photocatalytic reaction conditions.Herein,taking NaTaO3 as an example,we systemically investigated the chemical states of nickel‐based cocatalysts during photocatalytic water splitting reaction.It was found that photo‐induced self‐formation of Ni and NiO cocatalyst species take place on the surface of NaTaO3 nanocrystals.The self‐formation of dual‐cocatalysts not only occurs on 26‐facet NaTaO3,but also takes place on a more general 6‐facet NaTaO3.Our work clarified that the chemical states of cocatalysts are changing and the redox dual‐cocatalysts are redistributed on the semiconductor surface owing to the reaction induced by photogenerated charges under the condition of photocatalytic reactions.

Advance and application of lake optics research

The mainstreams of lake optics research in recent decades include optical properties of lakewater, observation, transmission and calculation of underwater radiation, determination of absorption coefficient S of yellow substance, influence of UV-B radiation of lake primary productivity by bio-optical model. Major lake optics applications, such as calculation of lake primary productivity and chl-a, analysis of factors restricting eu- trophication, and protection against lake eutrophication are summarized.

Experi mental study on a novel polarization state generator

In this letter,a new polarization state generator(PSG) is presented,which can generate an output with arbitrary state of polarization(SOP).This PSG consists of a linear polarizer,a rotatable quarter-waveplate,and a rotatable half-waveplate.The PSG can be used to study the polarization-related effects on optical components and on optical fiber communication systems.

Ecological Functions of PV Power Plants in the Desert and Gobi

Photovoltaic （PV） power generation is an emerging energy industry that is developing rapidly. A number of PV power plants have been established in the desert and Gobi areas in northwest China in recent years. Is there any ecological significance to the establishment of PV power plants？ If yes, what is it？ This paper tries to find the answer by analyzing meteorological data from the Hexi Corridor as well as the observational data of light and vegetation in the Minqin desert area. The results show that the solar energy converted from 1 m2 of PV panels is equivalent to the solar energy that is utilized by 260.75 m2 of desert plants in the desert area. In China, there is vast area of desert and Gobi, with frequent dust storms and aeolian sand, as well as rich sunlight resources. Therefore, to develop the PV industry in the desert and Gobi regions will not only create considerable economic benefits, but will also be of great ecological significance. On the one hand, PV can effectively regulate thermodynamic equilibrium on the surface, helping to prevent sandstorms and reduce aeolian sand. The development of the PV industry is a win-win that generates economic returns and provides ecological protection by combating desertification. On the other hand, the PV industry can be developed without taking up arable land or other types of land. There are frequently high winds in the desert and Gobi region. PV power plants, together with wind power generation, are useful to transform and consume the power source that creates duststorms and aeolian sandflow in the desert and Gobi areas. This results in fewer sandstorms and reduced aeolian sandflow.

Effect of atmospheric aerosol on surface ozone variation over the Pearl River Delta region

Our analysis of the surface aerosol and ultraviolet （UV） measurements in Pearl River Delta （PRD） region shows that the surface UV radiation is reduced by more than 50% due to high aerosol concentrations. This has important impacts on urban ecosystem and photochemistry, especially on ozone photochemical production over the region. The quantitative effect of aerosols on surface ozone is evaluated by analyzing surface observations （including ozone, ultraviolet radiation, aerosol radiative parameters） and by using radiative and chemical models. A case study shows that the aerosol concentrations and UV radiation are significantly correlated with ozone concentrations. The correlation coefficient between the aerosol optical depth （AOD） and the PM10 mass concentration is very high, with a maximum of 0.98, and the AOD and UV radiation/ozone is anti- correlated, with a correlation coefficient of-0.90. The analysis suggests that ozone productivity is significantly decreased due to the reduction of UV radiation. The noon-time ozone maximum is considerably depressed when AOD is 0.6, and is further decreased when AOD is up to 1.2 due to the reduction of ozone photochemical productivity. Because the occurring probability of aerosol optical depth for AOD550m≥0.6 and AOD340mm ≥1.0 is 47, and 55% respectively during the dry season （October, November, December, January）, this heavy aerosol condition explains the low ozone maximum that often occurs in the dry season over the Guangzhou region. The analysis also suggests that the value of single scattering albedo （SSA） is very sensitive to the aerosol radiative effect when the radiative and chemical models are applied, implying that the value of SSA needs to be carefully studied when the models are used in calculating ozone production.

Ecophysiological Characteristics of Parthenocissus quinquefolia Planch under Different Soil Moisture Conditions

In order to offer scientific base for the cultivation of Parthenocissus quinquefolia planch in barren mountainous areas, the paper studied the light response characteristics of the photosynthetic rate （Pn）, transpiration rate （Tt） and water use efficiency （WUE） that two-year-old P. quinquefolia planch leaf has under different soil moisture conditions with CIRAS-2 portable photosynthesis system made in PPS corporation in England. The results indicated that the Pn, Tr and WUE of P. quinquefolia planch leaf had notable threshold of responses to the variation of soil moisture and photosynthetic active radiation （PAR）. The Po of P. quinquefolia planch was at a relatively high level when the volumetric water content （VWC） was 12.6%-20.7% and relative water content （RWC） 45.2%-74.3%. When VWC was about 18.3%, the Pn and Tr reached the highest value while the WUE was relatively low. When the VWC was about 12.6% （RWC was about 45.2%）, the WUE reached the highest level. The fitting soil moisture range which could keep Pn and WUE at relatively high level was 12.6%-18.3% for VWC and 45.2%-65.7% for RWC. Out of this range, Pn and WUE would descend obviously. In the fitting range of VWC, the Pn and WUE maintained a high level when the PAR range was 400-1000 umol·m^-2·s^-1, otherwise, the WUE would fall, and the most suitable PAR was 800 umol·m^-2·s^-1. In view of the above results, we conclude that the P. quinquefolia planch can adapt to a wide range of illumination intensity. It has the property of strong drought-resistance but can not stand the high soil moisture environment. Therefore, it is a suitable vine for the afforestation in barren mountainous areas.

A dynamic optical arbitrary waveform generator based on cross phase modulation

In this paper, a dynamic optical arbitrary waveform generator(OAWG) based on cross phase modulation(XPM) is proposed. According to the characteristics of XPM, the nonlinear phase shift of signal can be changed along with the pump power. The amplitude of signal can be changed by controlling the phase shift at one arm of a Mach-Zehnder interferometer(MZI) using XPM effect between signal and pump. Therefore, the phase and amplitude of the optical frequency comb(OFC) can be controlled by two pump arrays. As a result, different kinds of waveforms can be synthesized. Due to the ultrafast response of XPM, the generated waveform could be dynamically updated with an ultrafast frequency. The waveform fidelity is affected by the updating frequency.