In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size d...In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size distribution, dilution, storage and folding endurance etc. Constitutes of basalt and wood fibers were determined by energy dispersion analysis X-ray which served as an accessory of scanning electron microscopy (SEM-EDAX). Naturally degradable ecocomposite was prepared by basalt and wood fibers. The results of SEM observation illustrated that the wood and basalt fibers were blended uniformly. The impact factors of beating degree, content of wood fibers and adhesive etc. were discussed. The structure of the naturally degradable ecocomposite was contrasted with that of pure wood fibers and the cause of excellent filtration performance was analyzed. Compared with traditional methods, it was of saving wood resource, a large amount of water and reducing second pollution. As a consequence, the ecocomposite harmonized with environment and accorded with requirement of benignly friendly environment.展开更多
A series of bifunctional catalysts composed of a component for higher alcohol synthesis (Cu-CoMn oxides, CCM) and an acidic zeolite (SAPO-34, ZSM-5, Y, MCM-41) were prepared for production of liquid hydrocarbon di...A series of bifunctional catalysts composed of a component for higher alcohol synthesis (Cu-CoMn oxides, CCM) and an acidic zeolite (SAPO-34, ZSM-5, Y, MCM-41) were prepared for production of liquid hydrocarbon directly from a bio-syngas through a one-stage pro-cess. The effects of zeolite type, zeolite content, Si/Al ratio and preparation method on catalyst texture and its reaction performance were investigated. Higher selectivities and yields of liquid products were obtained by using bifunctional catalysts. The yields of liquid hydrocarbons decreased in the order CCM-ZSM-5〉CCM-SAPO-34〉CCM-Y〉CCM-MCM-41. CCM-ZSM-5 (20wt%, Si/Al=100) prepared by coprecipitation method displayed the optimal catalytic performance with the highest CO conversion (76%) and yield of liquid products (30%). The catalysts were characterized by N2 adsorption/desorption, NH3-TPD, XRD, and H2-TPR analysis. The results showed that higher speci c surface areas and pore volumes of bifunctional catalysts were achieved by adding zeolites into CuCoMn precursors. Medium pore dimension and moderate acidity in CCM-ZSM-5 were observed, which proba-bly resulted in its excellent reaction performance. Additionally, a higher number of weaker acid sites (weak and/or medium acid sites) were formed by increasing ZSM-5 content in CCM-ZSM-5 or decreasing Si/Al ratio in ZSM-5. It was also seen that metal dispersion was higher and reducibility of metal ions was easier on the CCM-ZSM-5 catalyst prepared by coprecipitation. The higher alcohols-to-hydrocarbon process provides a promising route to hydrocarbon fuels via higher alcohols from syngas or biobased feedstocks.展开更多
In allusion to the characteristics of the open complex giant system, an open multilevel hierarchic intelligent control system is established for the eco-industrial system. With the idea of the open engineering system,...In allusion to the characteristics of the open complex giant system, an open multilevel hierarchic intelligent control system is established for the eco-industrial system. With the idea of the open engineering system, using the hall for workshop of metasynthetic engineering (HWME), intelligent control techniques, the expert system and the design of experiments are integrated within the framework of the nonlinear multiobjective decision support system to develop a robust, top-level design specification so as to make the system have the quality of adaptive control, self-organizing, self-learning and robustness. Finally, an illustrative example is given to clarify the effectiveness of the method.展开更多
Ag3PO4 powders were prepared through a precipitation reaction between AgNO3 and precipitating agent solutions that were prepared by adjusting the amount of H3PO4 in the Na3PO4 solutions. The Ag3PO4 powders prepared fr...Ag3PO4 powders were prepared through a precipitation reaction between AgNO3 and precipitating agent solutions that were prepared by adjusting the amount of H3PO4 in the Na3PO4 solutions. The Ag3PO4 powders prepared from the precipitation solution with a pH of 6 showed the highest photocatalytic activity for decolorizing the methylene blue and rhodamine B dyes. These Ag3PO4 powders were further modified by the addition of KBr solutions to obtain AgBr/Ag3PO4 powders and these photocatalysts can decolorize the anionic dyes as reactive orange and methyl orange. The reactive species involved in the photocatalytic degradation process were evaluated for their inhibitory activity using the appropriate scavengers. After photocatalysis, mass spectrometry confirmed that the dyes were degraded to smaller molecules. The ecotoxicities of the dye solutions before and after treatment were evaluated by studying their ability to inhibit the growth of the bioindicator Chlorella vulgaris.展开更多
Landscape ecology provides new theoretical frameworks and methodologies for understanding complex ecological phenomena at multiple scales.Studies of landscape ecology focus on understanding the dynamics of eco-logical...Landscape ecology provides new theoretical frameworks and methodologies for understanding complex ecological phenomena at multiple scales.Studies of landscape ecology focus on understanding the dynamics of eco-logical patterns and processes,and highlight the integration of multiple disciplines.In this paper,we discussed the problems and challenges that landscape ecology is currently facing,emphasizing the limitations of current methods used to describe dynamic landscape patterns and processes.We suggested that the focus should be on the integration of ground-based observation,mobile monitoring,transect survey,and remote-sensing monitoring,as well as improved coupling of experimental and model simulations.In addition,we outlined the research frontiers in landscape ecology,including scaling,integrated pattern and process modeling,and regional synthesis.Lastly,a brief review of pat-tern-process-scale coupling studies in China was provided.We concluded by pointing out that pattern-process-scale interactions,correlations between natural,economic,and social processes,and the coupling of human and natural systems will be major research areas in landscape ecology in the future.展开更多
Generative resources are mainly derived from the students (sometimes from the teachers), which is dynamically generated in the students' practice, self-inquiry, and cooperative communication. Gifted children refer ...Generative resources are mainly derived from the students (sometimes from the teachers), which is dynamically generated in the students' practice, self-inquiry, and cooperative communication. Gifted children refer to a group of children who have such characteristics as high IQ (intelligence quotient), strong creativity, and good personality. Their intelligence and capability have great potential for further development. As cognitive ability is one of the prominent characteristics of supernormal children, the lecturers can not only pay attention to teaching knowledge (facts teaching), but also need provide proper opportunities for them to develop their aggressiveness, creativities, and challenges when teaching these children. Because students are active in thinking, in the classroom, students often have some unexpected ideas, that is, the generation of the classroom, in the face of this situation, teachers should be how to do? A joke between students in the class, sparked the interest of a classmate, and then under the teachers' guidance, they invented a chemistry experiment instrument Ω type pipe, illustrated the importance of the teachers focus on creating teaching.展开更多
The species-area relationship (SAR) is one of the most fundamental concepts in community ecology and is helpful for biodiversity conservation. However, few studies have systematically addressed this topic for differ...The species-area relationship (SAR) is one of the most fundamental concepts in community ecology and is helpful for biodiversity conservation. However, few studies have systematically addressed this topic for different alpine grassland types on the Tibetan Plateau, China. We explored whether the plant composition of different functional groups affects the manner in which species richness inereases with increasing area at scales ≤ 1.0 m^2. We also compared species richness (S) within and across forbs, legumes, sedges and grasses, with sampling subplot area (A) increasing from 0.0625 m^2 to 1.0 m^2 between alpine meadow and steppe communities. We applied a logarithmic function (S = b0 + b1 ln A) to determine the slope and intercept of SAR curves within and across functional groups. The results showed that the logarithmic relationship holds true between species richness and sampling area at these small scales. Both the intercept and slope of the logarithmic forbs-area curves are significantly higher than those for the three other functional groups (P 〈 0.05). Forb accounts for about 91.9 % of the variation in the intercept and 75.0% of the variation in the slope of the SAR curve when all functional groups' data were pooled together. Our results indicated that the different SAR patterns should be linked with species dispersal capabilities, environmental filtering, and life form composition within alpine grassland communities. Further studies on the relationship between species diversity and ecosystem functions should specify the differential responses of different functional groups to variations in climate and anthropogenic disturbances.展开更多
Many studies have observed that leaf wax δDn-alkane values differed significantly between woods and grasses in modern plants, with grasses D-depleted by 40 %0-70 ‰. The reasons for the differences in leaf wax δDn-a...Many studies have observed that leaf wax δDn-alkane values differed significantly between woods and grasses in modern plants, with grasses D-depleted by 40 %0-70 ‰. The reasons for the differences in leaf wax δDn-alkane values between woods and grasses, however, remain unclear. In this study, we measured the δD values of soil water (δDsw), leaf water (δDlw), and leaf wax n-alkane (δDn-alkane) for woods and grasses. We found no significant differences in the δD values of soil water (P = 0.82) and leaf water (P= 0.74) between the two life forms of plants. Therefore, the differences in leaf wax δDn-alkane values between woods and grasses may correlate with inherent properties of different plant life forms, such as leaf structures, biosynthetic processes, and leaf morphologies. Moreover, it is also possible that soil water with different 6Dsw at different depths utilized by woods and grasses may be responsible for some of the differences in leaf wax δDn-alkane values between the two life forms of plants, if woods mainly use soil water from the 〉100 cm depth, whereas grasses mainly use soil water from the 〈100 cm depth. The results of this work allow us to better understand the leaf wax δDn-alkane values of different plant life forms in a region.展开更多
文摘In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size distribution, dilution, storage and folding endurance etc. Constitutes of basalt and wood fibers were determined by energy dispersion analysis X-ray which served as an accessory of scanning electron microscopy (SEM-EDAX). Naturally degradable ecocomposite was prepared by basalt and wood fibers. The results of SEM observation illustrated that the wood and basalt fibers were blended uniformly. The impact factors of beating degree, content of wood fibers and adhesive etc. were discussed. The structure of the naturally degradable ecocomposite was contrasted with that of pure wood fibers and the cause of excellent filtration performance was analyzed. Compared with traditional methods, it was of saving wood resource, a large amount of water and reducing second pollution. As a consequence, the ecocomposite harmonized with environment and accorded with requirement of benignly friendly environment.
文摘A series of bifunctional catalysts composed of a component for higher alcohol synthesis (Cu-CoMn oxides, CCM) and an acidic zeolite (SAPO-34, ZSM-5, Y, MCM-41) were prepared for production of liquid hydrocarbon directly from a bio-syngas through a one-stage pro-cess. The effects of zeolite type, zeolite content, Si/Al ratio and preparation method on catalyst texture and its reaction performance were investigated. Higher selectivities and yields of liquid products were obtained by using bifunctional catalysts. The yields of liquid hydrocarbons decreased in the order CCM-ZSM-5〉CCM-SAPO-34〉CCM-Y〉CCM-MCM-41. CCM-ZSM-5 (20wt%, Si/Al=100) prepared by coprecipitation method displayed the optimal catalytic performance with the highest CO conversion (76%) and yield of liquid products (30%). The catalysts were characterized by N2 adsorption/desorption, NH3-TPD, XRD, and H2-TPR analysis. The results showed that higher speci c surface areas and pore volumes of bifunctional catalysts were achieved by adding zeolites into CuCoMn precursors. Medium pore dimension and moderate acidity in CCM-ZSM-5 were observed, which proba-bly resulted in its excellent reaction performance. Additionally, a higher number of weaker acid sites (weak and/or medium acid sites) were formed by increasing ZSM-5 content in CCM-ZSM-5 or decreasing Si/Al ratio in ZSM-5. It was also seen that metal dispersion was higher and reducibility of metal ions was easier on the CCM-ZSM-5 catalyst prepared by coprecipitation. The higher alcohols-to-hydrocarbon process provides a promising route to hydrocarbon fuels via higher alcohols from syngas or biobased feedstocks.
文摘In allusion to the characteristics of the open complex giant system, an open multilevel hierarchic intelligent control system is established for the eco-industrial system. With the idea of the open engineering system, using the hall for workshop of metasynthetic engineering (HWME), intelligent control techniques, the expert system and the design of experiments are integrated within the framework of the nonlinear multiobjective decision support system to develop a robust, top-level design specification so as to make the system have the quality of adaptive control, self-organizing, self-learning and robustness. Finally, an illustrative example is given to clarify the effectiveness of the method.
基金supported from Prince of Songkla University under contract number SCI570276Sthe Center of Excellence for Innovation in Chemistry(PERCH-CIC), Office of the Higher Education Commission, Ministry of Education
文摘Ag3PO4 powders were prepared through a precipitation reaction between AgNO3 and precipitating agent solutions that were prepared by adjusting the amount of H3PO4 in the Na3PO4 solutions. The Ag3PO4 powders prepared from the precipitation solution with a pH of 6 showed the highest photocatalytic activity for decolorizing the methylene blue and rhodamine B dyes. These Ag3PO4 powders were further modified by the addition of KBr solutions to obtain AgBr/Ag3PO4 powders and these photocatalysts can decolorize the anionic dyes as reactive orange and methyl orange. The reactive species involved in the photocatalytic degradation process were evaluated for their inhibitory activity using the appropriate scavengers. After photocatalysis, mass spectrometry confirmed that the dyes were degraded to smaller molecules. The ecotoxicities of the dye solutions before and after treatment were evaluated by studying their ability to inhibit the growth of the bioindicator Chlorella vulgaris.
基金Under the auspices of National Natural Science Foundation of China (No.40930528)State Forestry Administration of China (No.201004058)
文摘Landscape ecology provides new theoretical frameworks and methodologies for understanding complex ecological phenomena at multiple scales.Studies of landscape ecology focus on understanding the dynamics of eco-logical patterns and processes,and highlight the integration of multiple disciplines.In this paper,we discussed the problems and challenges that landscape ecology is currently facing,emphasizing the limitations of current methods used to describe dynamic landscape patterns and processes.We suggested that the focus should be on the integration of ground-based observation,mobile monitoring,transect survey,and remote-sensing monitoring,as well as improved coupling of experimental and model simulations.In addition,we outlined the research frontiers in landscape ecology,including scaling,integrated pattern and process modeling,and regional synthesis.Lastly,a brief review of pat-tern-process-scale coupling studies in China was provided.We concluded by pointing out that pattern-process-scale interactions,correlations between natural,economic,and social processes,and the coupling of human and natural systems will be major research areas in landscape ecology in the future.
文摘Generative resources are mainly derived from the students (sometimes from the teachers), which is dynamically generated in the students' practice, self-inquiry, and cooperative communication. Gifted children refer to a group of children who have such characteristics as high IQ (intelligence quotient), strong creativity, and good personality. Their intelligence and capability have great potential for further development. As cognitive ability is one of the prominent characteristics of supernormal children, the lecturers can not only pay attention to teaching knowledge (facts teaching), but also need provide proper opportunities for them to develop their aggressiveness, creativities, and challenges when teaching these children. Because students are active in thinking, in the classroom, students often have some unexpected ideas, that is, the generation of the classroom, in the face of this situation, teachers should be how to do? A joke between students in the class, sparked the interest of a classmate, and then under the teachers' guidance, they invented a chemistry experiment instrument Ω type pipe, illustrated the importance of the teachers focus on creating teaching.
基金supported by the Chinese Academy of Sciences (Grant Nos.XDB03030401,KZCXZ-XB3-08)the State Scholarship Fund of the China Scholarship Council (Grant No.201400260118)the International Postdoctoral Exchange Fellowship Program 2014 by the Office of China Postdoctoral Council (Grant No.20140041)
文摘The species-area relationship (SAR) is one of the most fundamental concepts in community ecology and is helpful for biodiversity conservation. However, few studies have systematically addressed this topic for different alpine grassland types on the Tibetan Plateau, China. We explored whether the plant composition of different functional groups affects the manner in which species richness inereases with increasing area at scales ≤ 1.0 m^2. We also compared species richness (S) within and across forbs, legumes, sedges and grasses, with sampling subplot area (A) increasing from 0.0625 m^2 to 1.0 m^2 between alpine meadow and steppe communities. We applied a logarithmic function (S = b0 + b1 ln A) to determine the slope and intercept of SAR curves within and across functional groups. The results showed that the logarithmic relationship holds true between species richness and sampling area at these small scales. Both the intercept and slope of the logarithmic forbs-area curves are significantly higher than those for the three other functional groups (P 〈 0.05). Forb accounts for about 91.9 % of the variation in the intercept and 75.0% of the variation in the slope of the SAR curve when all functional groups' data were pooled together. Our results indicated that the different SAR patterns should be linked with species dispersal capabilities, environmental filtering, and life form composition within alpine grassland communities. Further studies on the relationship between species diversity and ecosystem functions should specify the differential responses of different functional groups to variations in climate and anthropogenic disturbances.
文摘Many studies have observed that leaf wax δDn-alkane values differed significantly between woods and grasses in modern plants, with grasses D-depleted by 40 %0-70 ‰. The reasons for the differences in leaf wax δDn-alkane values between woods and grasses, however, remain unclear. In this study, we measured the δD values of soil water (δDsw), leaf water (δDlw), and leaf wax n-alkane (δDn-alkane) for woods and grasses. We found no significant differences in the δD values of soil water (P = 0.82) and leaf water (P= 0.74) between the two life forms of plants. Therefore, the differences in leaf wax δDn-alkane values between woods and grasses may correlate with inherent properties of different plant life forms, such as leaf structures, biosynthetic processes, and leaf morphologies. Moreover, it is also possible that soil water with different 6Dsw at different depths utilized by woods and grasses may be responsible for some of the differences in leaf wax δDn-alkane values between the two life forms of plants, if woods mainly use soil water from the 〉100 cm depth, whereas grasses mainly use soil water from the 〈100 cm depth. The results of this work allow us to better understand the leaf wax δDn-alkane values of different plant life forms in a region.