Calcium sulfoaluminate,3CaO·3Al2O3·CaSO4,has been widely recognized in the realms of high-temperature combustion and cement chemistry.However,the lack of relevant thermodynamic data limits the progress of it...Calcium sulfoaluminate,3CaO·3Al2O3·CaSO4,has been widely recognized in the realms of high-temperature combustion and cement chemistry.However,the lack of relevant thermodynamic data limits the progress of its research and development.Through comparative calculations using several different approaches,we obtain the thermochemical properties of 3CaO·3Al2O3·CaSO4 in this work,such as its standard formation enthalpy,Gibbs free en- ergy of formation,entropy,and molar heat capacity.With these fundamental data,thermodynamic calculations become possible for reactions involving this mineral.It is found that some reactions proposed in literature to generate this mineral may not proceed thermodynamically.展开更多
Forests play an important role in mitigating climate change by absorbing carbon from atmosphere. The global forests sequestrated 2.4±0.4 Pg C y^-1 from 1990 to 2007, while the quantitative assessment on the carbo...Forests play an important role in mitigating climate change by absorbing carbon from atmosphere. The global forests sequestrated 2.4±0.4 Pg C y^-1 from 1990 to 2007, while the quantitative assessment on the carbon sequestration potential （CSP） of global forests has much uncertainty. We collected and compiled a database of site above-ground biomass （AGB） of global mature forests, and obtained AGB carbon carrying capacity （CCC） of global forests by interpolating global mature forest site data. The results show that： （i） at a global scale, the AGB of mature forests decline mainly from tropical forests to boreal forests, and the maximum AGB occurs in middle latitude regions; （ii） temperature and precipitation are main factors influencing the AGB of mature forests; and （iii） the above-ground biomass CCC of global forests is about 586.2±49.3 Pg C, and with CSP of 313.4 Pg C. Therefore, achieving CCC of the existing forests by reducing human disturbance is an option for mitigating greenhouse gas emission.展开更多
基金Supported by the National Natural Science Foundation of China(50906046)the National High-Tech Research and Development Program of China(2009AA05Z303)the Program for New Century Excellent Talents in University(NCET-10-0529)
文摘Calcium sulfoaluminate,3CaO·3Al2O3·CaSO4,has been widely recognized in the realms of high-temperature combustion and cement chemistry.However,the lack of relevant thermodynamic data limits the progress of its research and development.Through comparative calculations using several different approaches,we obtain the thermochemical properties of 3CaO·3Al2O3·CaSO4 in this work,such as its standard formation enthalpy,Gibbs free en- ergy of formation,entropy,and molar heat capacity.With these fundamental data,thermodynamic calculations become possible for reactions involving this mineral.It is found that some reactions proposed in literature to generate this mineral may not proceed thermodynamically.
基金the National Basic Research Program of China (2010CB833504)the CAS Strategic Priority Research Program (XDA05050600)the National Natural Science Foundation of China (30590381)
文摘Forests play an important role in mitigating climate change by absorbing carbon from atmosphere. The global forests sequestrated 2.4±0.4 Pg C y^-1 from 1990 to 2007, while the quantitative assessment on the carbon sequestration potential （CSP） of global forests has much uncertainty. We collected and compiled a database of site above-ground biomass （AGB） of global mature forests, and obtained AGB carbon carrying capacity （CCC） of global forests by interpolating global mature forest site data. The results show that： （i） at a global scale, the AGB of mature forests decline mainly from tropical forests to boreal forests, and the maximum AGB occurs in middle latitude regions; （ii） temperature and precipitation are main factors influencing the AGB of mature forests; and （iii） the above-ground biomass CCC of global forests is about 586.2±49.3 Pg C, and with CSP of 313.4 Pg C. Therefore, achieving CCC of the existing forests by reducing human disturbance is an option for mitigating greenhouse gas emission.
