The title compound (C20H30N4O6, Mr = 422.48) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in the triclinic system, space group P with cell parameters: a = 8.330...The title compound (C20H30N4O6, Mr = 422.48) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in the triclinic system, space group P with cell parameters: a = 8.330(2), b = 8.468(2), c = 16.017(3) ? ?= 97.30(3), ?= 92.33(3), ?= 103.94(3)? V = 1084.7(4) ?, Dc = 1.294 g/cm3, Z = 2, F(000) = 452 and ?= 0.096 mm-1. The structure was refined to R = 0.0483 for 3732 observed reflections with I > 2s(I) and wR = 0.1335 for 4828 unique reflections. The hydantoin rings are planar and the two ring planes of one molecule are paralleled to each other.展开更多
The universe is life, which includes galaxies, living beings, society and man-made worlds. The universe is unified in life and thought. The universal grand unified theory is a theory to completely unify all phenomena ...The universe is life, which includes galaxies, living beings, society and man-made worlds. The universe is unified in life and thought. The universal grand unified theory is a theory to completely unify all phenomena in the universe with a fundamental mode (structural mode, operational mode, generation mode and evolution mode). The book of changes of China: The great ultimate - two states - four images - eight hexagrams are life science and thought science theories, which represent the fundamental mode of universal unification, i.e. represent l) structural mode, operational mode, generation mode and evolution mode of life; 2) the four states that life has simultaneously: 0 dimension, ] dimension, 2 dimension, 3 dimension, and these four states have different structural and operational modes respectively; 3) the breathing and four seasonal trajectories of celestial bodies; 4) three generation modes of life: generation by transformation, generation by augmentation, and self-generation; 5) five dynamics systems inside life; 6) the sublimation and degration of life in the universe, the unification of religion and science; 7) the classification mode of the universal being; 8) the derivation mode of life; 9) the transformation between different forms of life in the universe; 10) the unification of six grand forces in the universe. All life systems in the universe: galaxy, organism, society, man-made worlds as well as cognitive science, natural science, social science are all in conform with the mode of the book of changes.展开更多
Bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)] I and bis-[oxo-bis(-ferrocenoyl- propionyloxy di-n-propyltin)] II were synthesized and their crystal structures have been determined by X-ray diffraction analysis. The...Bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)] I and bis-[oxo-bis(-ferrocenoyl- propionyloxy di-n-propyltin)] II were synthesized and their crystal structures have been determined by X-ray diffraction analysis. The compound I2C6H6 ([(FcC6H4COOSnPr2)2O]22C6H6 or C92H108Fe4O10Sn42C6H6, Mr = 2384.16) is of triclinic, space group P?with a = 12.826(4), b = 13.099(5), c = 17.539(5) ? = 78.229(5), ?= 71.852(5), = 62.746(5)? V = 2483(1) ?, Z = 1, Dc = 1.490 g/cm3, = 0.71073 ? (MoK? =1.611 mm-1 and F(000) = 1128. The structure was refined to R = 0.0491 and wR = 0.1053 for 4690 unique reflections with I > 2(I). The compound IIC6H6 ([(FcCOCH2CH2COOSnPr2)2O]2C6H6 or C80H108Fe4O14Sn4C6H6, Mr = 2115.93) is of triclinic, space group P?with a = 11.260(4), b = 14.126(5), c = 15.961(6) ? = 91.400(6), = 110.654(6), = 104.931(6), V = 2277(1) 3, Z = 1, Dc = 1.510 g/cm3, = 0.71073 ? (MoK? = 1.750 mm-1 and F(000) = 1046. The structure was refined to R = 0.0466 and wR = 0.1138 for 5061 unique reflections with I > 2(I). The two compounds have the similar structures: both are dimers containing centrosymmetric Sn2O2 cores. But there are some differences in the ligating modes between the carboxylate groups and the Sn atoms.展开更多
Algeria registers only 0.25 ha of agricultural surface per capita. This indicates very low agricultural capacities. Otherwise agricultural activities are concentrated in a narrow fringe of the Northern part of the cou...Algeria registers only 0.25 ha of agricultural surface per capita. This indicates very low agricultural capacities. Otherwise agricultural activities are concentrated in a narrow fringe of the Northern part of the country where the dominant climate is semi-arid with very irregular rainfalls. A majority of farms produces its main part of income from cereal crops--livestock association system. However, the diversity of the climate and the physical environment, on one hand, and the agricultural policies on the other hand, induce major transformations in this system. Transformations are also the result of a significant demographic growth in rural area. In this context, significant issues appear in term of resource's uses and systems' sustainability. To shed light in the actual situation, this study, based on a survey of 90 owners, shows that: the intensification can constitute a threat on the pastoral resources; the weakness of the farms encourages the generalization of practices characterised by a weak feed autonomy and a bad management of stock fodders; the animal interspecific integration and partial intensification are positive if they follow models which ensure autonomy, performance and optimal pastoral resource management.展开更多
Detailed information about the crustal structure is essential for better understanding the occurrence and mechanisms of earthquakes and volcanoes.Here we present a study of the upper crustal P-wave velocity structure ...Detailed information about the crustal structure is essential for better understanding the occurrence and mechanisms of earthquakes and volcanoes.Here we present a study of the upper crustal P-wave velocity structure of two seismically and volcanically active areas in northern Iran using the two-dimensional Pg travel time tomography method.The imaging results suggest low velocities in the upper crust beneath the Damavand and Sahand-Sabalan volcanic areas in the central and western parts of northern Iran,respectively.The upper crustal low velocities in these two areas roughly coincide with previously imaged low Pn velocity anomalies,suggesting that the Late Cenozoic volcanic activity was probably caused by the upwelling of hot materials from the mantle.The image feature of the Pg velocity structure beneath the Sahand-Sabalan volcanic area further indicates that the hot materials stored in the upper crust beneath Sahand may be larger in size than those stored beneath Sabalan.Comparison of the Pg velocity images with the earthquake distribution in north Iran suggests that earthquakes mainly occur at moderately low velocity or low to high velocity boundary areas instead of significantly low or high velocity regions.The anisotropy results show that the Pg wave fast direction is consistent with the GPS direction at high Pg velocity areas and the fast direction is inconsistent with the GPS direction but consistent with the strike direction of faults at low velocity areas.Our new upper crustal structural images provide the basic observation for better understanding of the regional seismicity and volcanism,and link the surface geological phenomena to deep crustal and mantle processes associated with the active tectonics in northern Iran.展开更多
基金This project was supported by the National Natural Science Foundation of China (No 39870983)
文摘The title compound (C20H30N4O6, Mr = 422.48) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in the triclinic system, space group P with cell parameters: a = 8.330(2), b = 8.468(2), c = 16.017(3) ? ?= 97.30(3), ?= 92.33(3), ?= 103.94(3)? V = 1084.7(4) ?, Dc = 1.294 g/cm3, Z = 2, F(000) = 452 and ?= 0.096 mm-1. The structure was refined to R = 0.0483 for 3732 observed reflections with I > 2s(I) and wR = 0.1335 for 4828 unique reflections. The hydantoin rings are planar and the two ring planes of one molecule are paralleled to each other.
文摘The universe is life, which includes galaxies, living beings, society and man-made worlds. The universe is unified in life and thought. The universal grand unified theory is a theory to completely unify all phenomena in the universe with a fundamental mode (structural mode, operational mode, generation mode and evolution mode). The book of changes of China: The great ultimate - two states - four images - eight hexagrams are life science and thought science theories, which represent the fundamental mode of universal unification, i.e. represent l) structural mode, operational mode, generation mode and evolution mode of life; 2) the four states that life has simultaneously: 0 dimension, ] dimension, 2 dimension, 3 dimension, and these four states have different structural and operational modes respectively; 3) the breathing and four seasonal trajectories of celestial bodies; 4) three generation modes of life: generation by transformation, generation by augmentation, and self-generation; 5) five dynamics systems inside life; 6) the sublimation and degration of life in the universe, the unification of religion and science; 7) the classification mode of the universal being; 8) the derivation mode of life; 9) the transformation between different forms of life in the universe; 10) the unification of six grand forces in the universe. All life systems in the universe: galaxy, organism, society, man-made worlds as well as cognitive science, natural science, social science are all in conform with the mode of the book of changes.
文摘Bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)] I and bis-[oxo-bis(-ferrocenoyl- propionyloxy di-n-propyltin)] II were synthesized and their crystal structures have been determined by X-ray diffraction analysis. The compound I2C6H6 ([(FcC6H4COOSnPr2)2O]22C6H6 or C92H108Fe4O10Sn42C6H6, Mr = 2384.16) is of triclinic, space group P?with a = 12.826(4), b = 13.099(5), c = 17.539(5) ? = 78.229(5), ?= 71.852(5), = 62.746(5)? V = 2483(1) ?, Z = 1, Dc = 1.490 g/cm3, = 0.71073 ? (MoK? =1.611 mm-1 and F(000) = 1128. The structure was refined to R = 0.0491 and wR = 0.1053 for 4690 unique reflections with I > 2(I). The compound IIC6H6 ([(FcCOCH2CH2COOSnPr2)2O]2C6H6 or C80H108Fe4O14Sn4C6H6, Mr = 2115.93) is of triclinic, space group P?with a = 11.260(4), b = 14.126(5), c = 15.961(6) ? = 91.400(6), = 110.654(6), = 104.931(6), V = 2277(1) 3, Z = 1, Dc = 1.510 g/cm3, = 0.71073 ? (MoK? = 1.750 mm-1 and F(000) = 1046. The structure was refined to R = 0.0466 and wR = 0.1138 for 5061 unique reflections with I > 2(I). The two compounds have the similar structures: both are dimers containing centrosymmetric Sn2O2 cores. But there are some differences in the ligating modes between the carboxylate groups and the Sn atoms.
文摘Algeria registers only 0.25 ha of agricultural surface per capita. This indicates very low agricultural capacities. Otherwise agricultural activities are concentrated in a narrow fringe of the Northern part of the country where the dominant climate is semi-arid with very irregular rainfalls. A majority of farms produces its main part of income from cereal crops--livestock association system. However, the diversity of the climate and the physical environment, on one hand, and the agricultural policies on the other hand, induce major transformations in this system. Transformations are also the result of a significant demographic growth in rural area. In this context, significant issues appear in term of resource's uses and systems' sustainability. To shed light in the actual situation, this study, based on a survey of 90 owners, shows that: the intensification can constitute a threat on the pastoral resources; the weakness of the farms encourages the generalization of practices characterised by a weak feed autonomy and a bad management of stock fodders; the animal interspecific integration and partial intensification are positive if they follow models which ensure autonomy, performance and optimal pastoral resource management.
基金supported by the Strategic Priority Research Program(B) of the Chinese Academy of Sciences(Grant No.XDB03010800)the National Natural Science Foundation of China (Grant Nos.41225016,41304065 & 41674066)
文摘Detailed information about the crustal structure is essential for better understanding the occurrence and mechanisms of earthquakes and volcanoes.Here we present a study of the upper crustal P-wave velocity structure of two seismically and volcanically active areas in northern Iran using the two-dimensional Pg travel time tomography method.The imaging results suggest low velocities in the upper crust beneath the Damavand and Sahand-Sabalan volcanic areas in the central and western parts of northern Iran,respectively.The upper crustal low velocities in these two areas roughly coincide with previously imaged low Pn velocity anomalies,suggesting that the Late Cenozoic volcanic activity was probably caused by the upwelling of hot materials from the mantle.The image feature of the Pg velocity structure beneath the Sahand-Sabalan volcanic area further indicates that the hot materials stored in the upper crust beneath Sahand may be larger in size than those stored beneath Sabalan.Comparison of the Pg velocity images with the earthquake distribution in north Iran suggests that earthquakes mainly occur at moderately low velocity or low to high velocity boundary areas instead of significantly low or high velocity regions.The anisotropy results show that the Pg wave fast direction is consistent with the GPS direction at high Pg velocity areas and the fast direction is inconsistent with the GPS direction but consistent with the strike direction of faults at low velocity areas.Our new upper crustal structural images provide the basic observation for better understanding of the regional seismicity and volcanism,and link the surface geological phenomena to deep crustal and mantle processes associated with the active tectonics in northern Iran.