The effect of Si on the growth kinetics of intermetallic compounds during the reaction of solid iron and molten aluminum was investigated with a scanning electron microscope coupled with an energy dispersive X-ray spe...The effect of Si on the growth kinetics of intermetallic compounds during the reaction of solid iron and molten aluminum was investigated with a scanning electron microscope coupled with an energy dispersive X-ray spectroscope, and hot-dip aluminized experiments. The results show that the intermetallic layer is composed of major Fe2Al5 and minor FeAl3. The Al-Fe-Si ternary phase, rl/rg, is formed in the Fe2Al5 layer. The tongue-like morphology of the Fe2Als layer becomes less distinct and disappears finally as the content of Si in aluminum bath increases. Si in the bath improves the prohibiting ability to the growth of Fe2Als and FeAl3. When the contents of Si are 0, 0.5%, 1.0%, 1.5%, 2.0% and 3.0%, the activation energies of Fe2Al5 are evaluated to be 207, 186, 169, 168, 167 and 172 kJ/mol, respectively. The reduction of the activation energy might result from the lattice distortion caused by Si atom penetrating into the Fe2Al5 phase. When Si atom occupies the vacancy site, it blocks easy diffusion path and results in the disappearance of tongue-like morphology.展开更多
Changes in tissue structure, rheological properties and water content of raw and heated sea cucumber meat were studied. Sea cucumber Stichopus japonicus was heated at 25℃, 70℃ and 100℃ water for 5 min. The structur...Changes in tissue structure, rheological properties and water content of raw and heated sea cucumber meat were studied. Sea cucumber Stichopus japonicus was heated at 25℃, 70℃ and 100℃ water for 5 min. The structural changes were observed using a light microscope and the rheological parameters （rupture strength, adhesive strength and deformation） determined using a texture meter. Microscopic photograph revealed that the structural change of heated meat was greater than that of raw meat. The rupture strength, adhesive strength and deformation of raw meat were smaller than those of the heated meat. Meanwhile, rheological parameters showed positive correlation with heating temperature. These changes are mainly caused by thermal denaturation and gelatinization of collagen during heating. These changes were also evidenced in observations using a light microscope and differential scanning calorimetry.展开更多
The grain growth and thermal stability of nanocrystalline Ni-TiO2composites were systematically investigated.Thenanocrystalline Ni-TiO2composites with different contents of TiO2were prepared via electroplating method ...The grain growth and thermal stability of nanocrystalline Ni-TiO2composites were systematically investigated.Thenanocrystalline Ni-TiO2composites with different contents of TiO2were prepared via electroplating method with the variation ofTiO2nano-particles concentration.The effect of TiO2content on the grain size,phase structure and microhardness was investigatedin detail.The corresponding grain growth and diffusion mechanisms during the heating process were also discussed.The optimalmicrohardness of HV50270was achieved for the composite with addition of20g/L TiO2nano-particles after annealing at400°C for90min.The calculation of the activation energy indicated that lattice diffusion dominated at high temperatures for thenanocrystalline Ni-TiO2composites.It was indicated that the increase of TiO2nano-particles content took effect on restricting thegrain growth at high temperatures by increasing the grain growth activation energy.展开更多
The first available label standardizing a zero-balanced type of building is the Swiss Standard Minergie-A. The standard prescribes an annual net zero primary energy balance for heating, domestic hot water and ventilat...The first available label standardizing a zero-balanced type of building is the Swiss Standard Minergie-A. The standard prescribes an annual net zero primary energy balance for heating, domestic hot water and ventilation. Electricity consumption for appliances and lighting is excluded. Additionally, Minergie-A is the first standard worldwide which includes a requirement in regard to embodied energy. Based on an analysis of 39 Minergie-A buildings, this paper shows that a wide range of different energy concepts and embodied energy strategies are possible in the scope of the label. The basis of all Minergie-A buildings is a well-insulated building envelope. However, the step from the Swiss Standard Minergie-A to a Net ZEB （net zero energy building） standard which includes electricity consumption for appliances and lighting is not a very big one. Increasing the size of the photovoltaic system is sufficient in most cases. Anyway, some of the Minergie-A buildings evaluated are also Net ZEBs. In this paper, it is also shown that the net zero balance during the operational phase of Net ZEBs clearly outweighs the increased embodied energy for additional materials in a life cycle energy analysis.展开更多
In this paper, we show that sweet quaternary ammonium, pyridinium, and imidazolium cyclamates are cheap, thermally stable, surface and biologically active ionic liquids, with potential application as feeding deterrents.
基金Project (51071135) supported by the National Natural Science Foundation of ChinaProject (20114301110005) supported by the Ph. D.Programs Foundation of Ministry of Education of ChinaProject (10XZX15) supported by the Science Foundation of Xiangtan University,China
文摘The effect of Si on the growth kinetics of intermetallic compounds during the reaction of solid iron and molten aluminum was investigated with a scanning electron microscope coupled with an energy dispersive X-ray spectroscope, and hot-dip aluminized experiments. The results show that the intermetallic layer is composed of major Fe2Al5 and minor FeAl3. The Al-Fe-Si ternary phase, rl/rg, is formed in the Fe2Al5 layer. The tongue-like morphology of the Fe2Als layer becomes less distinct and disappears finally as the content of Si in aluminum bath increases. Si in the bath improves the prohibiting ability to the growth of Fe2Als and FeAl3. When the contents of Si are 0, 0.5%, 1.0%, 1.5%, 2.0% and 3.0%, the activation energies of Fe2Al5 are evaluated to be 207, 186, 169, 168, 167 and 172 kJ/mol, respectively. The reduction of the activation energy might result from the lattice distortion caused by Si atom penetrating into the Fe2Al5 phase. When Si atom occupies the vacancy site, it blocks easy diffusion path and results in the disappearance of tongue-like morphology.
基金supported by the proiect sponsored by the Scientific Research Foundation for Returned Overseas Chinese Scholars,State Education Ministry(SRF for ROCS,SEM)the Natural Science Foundation of Shandong(No.2004BSO7003)and Qingdao(No.04-2-JZ-110)
文摘Changes in tissue structure, rheological properties and water content of raw and heated sea cucumber meat were studied. Sea cucumber Stichopus japonicus was heated at 25℃, 70℃ and 100℃ water for 5 min. The structural changes were observed using a light microscope and the rheological parameters （rupture strength, adhesive strength and deformation） determined using a texture meter. Microscopic photograph revealed that the structural change of heated meat was greater than that of raw meat. The rupture strength, adhesive strength and deformation of raw meat were smaller than those of the heated meat. Meanwhile, rheological parameters showed positive correlation with heating temperature. These changes are mainly caused by thermal denaturation and gelatinization of collagen during heating. These changes were also evidenced in observations using a light microscope and differential scanning calorimetry.
基金Project(51401024)supported by the National Natural Science Foundation of ChinaProject(20150942006)supported by Basic Research Program of Beijing Institute of Technology,China
文摘The grain growth and thermal stability of nanocrystalline Ni-TiO2composites were systematically investigated.Thenanocrystalline Ni-TiO2composites with different contents of TiO2were prepared via electroplating method with the variation ofTiO2nano-particles concentration.The effect of TiO2content on the grain size,phase structure and microhardness was investigatedin detail.The corresponding grain growth and diffusion mechanisms during the heating process were also discussed.The optimalmicrohardness of HV50270was achieved for the composite with addition of20g/L TiO2nano-particles after annealing at400°C for90min.The calculation of the activation energy indicated that lattice diffusion dominated at high temperatures for thenanocrystalline Ni-TiO2composites.It was indicated that the increase of TiO2nano-particles content took effect on restricting thegrain growth at high temperatures by increasing the grain growth activation energy.
文摘The first available label standardizing a zero-balanced type of building is the Swiss Standard Minergie-A. The standard prescribes an annual net zero primary energy balance for heating, domestic hot water and ventilation. Electricity consumption for appliances and lighting is excluded. Additionally, Minergie-A is the first standard worldwide which includes a requirement in regard to embodied energy. Based on an analysis of 39 Minergie-A buildings, this paper shows that a wide range of different energy concepts and embodied energy strategies are possible in the scope of the label. The basis of all Minergie-A buildings is a well-insulated building envelope. However, the step from the Swiss Standard Minergie-A to a Net ZEB （net zero energy building） standard which includes electricity consumption for appliances and lighting is not a very big one. Increasing the size of the photovoltaic system is sufficient in most cases. Anyway, some of the Minergie-A buildings evaluated are also Net ZEBs. In this paper, it is also shown that the net zero balance during the operational phase of Net ZEBs clearly outweighs the increased embodied energy for additional materials in a life cycle energy analysis.
基金the National Science Centre (Poland) for financial support (7548/B/H03/2011/40)
文摘In this paper, we show that sweet quaternary ammonium, pyridinium, and imidazolium cyclamates are cheap, thermally stable, surface and biologically active ionic liquids, with potential application as feeding deterrents.
