The crystal structure,formation kinetics and micro-morphology of CaO·SiO2 during high-temperature sintering process were studied in low-calcium system by XRD,FT-IR,Raman and SEM-EDS methods.When the molar ratio o...The crystal structure,formation kinetics and micro-morphology of CaO·SiO2 during high-temperature sintering process were studied in low-calcium system by XRD,FT-IR,Raman and SEM-EDS methods.When the molar ratio of CaCO3 to SiO2 is 1.0,β-2CaO·SiO2 forms firstly during the heating process,and then CaO·SiO2 is generated by the transformation reaction of pre-formed 2CaO·SiO2 with SiO2.3CaO·SiO2 and 3CaO·2SiO2 do not form either in the heating or sintering process.Rising the sintering temperature and prolonging the holding time promote the phase transition of 2CaO·SiO2 to CaO·SiO2,resulting in the sintered products a small blue shift and broadening in Raman spectra.The content of CS can reach 97.4%when sintered at 1400℃ for 1 h.The formation kinetics of CaO·SiO2 follows the second-order chemical reaction model,and the corresponding apparent activation energy and pre-exponential factor are 505.82 kJ/mol and 2.16×10^14 s^−1 respectively.展开更多
OBJECTIVE:To investigate the biological macro-idea and criterion of osteopathic fracture immobilization in China's traditional Mongolian medicine.METHODS:Based on biological naturalism regarding the relationship b...OBJECTIVE:To investigate the biological macro-idea and criterion of osteopathic fracture immobilization in China's traditional Mongolian medicine.METHODS:Based on biological naturalism regarding the relationship between man and universe(including psychosomatic integration) in osteopathic fracture immobilization in China's traditional Mongolian medicine,we used modern physiopsychological and biomechanical principles and methods to investigate the biological macro-characteristics of humanization,behaviorism,and wholism in "dynamic" fixation of fractures.RESULTS:Osteopathic fracture immobilization in China's traditional Mongolian medicine is based on the fixation criterion of macro-idea and method as well as on geometry,mechanics,motion,and stress and psychological stability in "non-sheltered fixation" of fractures contained in the life view of nature,regarding the relationship between man and universe(including psychosomatic integration) and on harmony between the limbs and the whole body,between body and function,and between man and nature.CONCLUSIONS:Osteopathic fracture immobilization in China's traditional Mongolian medicine is fixation without trauma or shelter.The principle and method of whole,dynamic,and functional fixation of fractures is not only radical,but also represents a new direction for developing the principle and method of fracture immobilization.展开更多
基金Projects(51674075,51774079)supported by the National Natural Science Foundation of ChinaProject(2018YFC1901903)supported by the National Key R&D Program of ChinaProject(N182508026)supported by the Fundamental Research Funds for the Central Universities of China。
文摘The crystal structure,formation kinetics and micro-morphology of CaO·SiO2 during high-temperature sintering process were studied in low-calcium system by XRD,FT-IR,Raman and SEM-EDS methods.When the molar ratio of CaCO3 to SiO2 is 1.0,β-2CaO·SiO2 forms firstly during the heating process,and then CaO·SiO2 is generated by the transformation reaction of pre-formed 2CaO·SiO2 with SiO2.3CaO·SiO2 and 3CaO·2SiO2 do not form either in the heating or sintering process.Rising the sintering temperature and prolonging the holding time promote the phase transition of 2CaO·SiO2 to CaO·SiO2,resulting in the sintered products a small blue shift and broadening in Raman spectra.The content of CS can reach 97.4%when sintered at 1400℃ for 1 h.The formation kinetics of CaO·SiO2 follows the second-order chemical reaction model,and the corresponding apparent activation energy and pre-exponential factor are 505.82 kJ/mol and 2.16×10^14 s^−1 respectively.
基金Supported by State Natural Science Fund No. 30960518the Major Projects in Inner Mongolian Sci-Tech Plan 2010-2012
文摘OBJECTIVE:To investigate the biological macro-idea and criterion of osteopathic fracture immobilization in China's traditional Mongolian medicine.METHODS:Based on biological naturalism regarding the relationship between man and universe(including psychosomatic integration) in osteopathic fracture immobilization in China's traditional Mongolian medicine,we used modern physiopsychological and biomechanical principles and methods to investigate the biological macro-characteristics of humanization,behaviorism,and wholism in "dynamic" fixation of fractures.RESULTS:Osteopathic fracture immobilization in China's traditional Mongolian medicine is based on the fixation criterion of macro-idea and method as well as on geometry,mechanics,motion,and stress and psychological stability in "non-sheltered fixation" of fractures contained in the life view of nature,regarding the relationship between man and universe(including psychosomatic integration) and on harmony between the limbs and the whole body,between body and function,and between man and nature.CONCLUSIONS:Osteopathic fracture immobilization in China's traditional Mongolian medicine is fixation without trauma or shelter.The principle and method of whole,dynamic,and functional fixation of fractures is not only radical,but also represents a new direction for developing the principle and method of fracture immobilization.
