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无烟煤微生物成气中间代谢产物组成及其转化 被引量:22
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作者 陈林勇 王保玉 +4 位作者 邰超 关嘉栋 赵晗 王美林 韩作颖 《煤炭学报》 EI CAS CSCD 北大核心 2016年第9期2305-2311,共7页
研究了煤生物成气过程中中间产物的变化规律与成气过程的相互关系。以10 kg沁水盆地山西寺河矿的无烟煤为底物,以寺河矿区煤层气井口出水为菌源,进行了煤生物成气模拟实验,利用气相色谱-质谱联用对不同成气阶段发酵液中间产物进行了分... 研究了煤生物成气过程中中间产物的变化规律与成气过程的相互关系。以10 kg沁水盆地山西寺河矿的无烟煤为底物,以寺河矿区煤层气井口出水为菌源,进行了煤生物成气模拟实验,利用气相色谱-质谱联用对不同成气阶段发酵液中间产物进行了分析。实验发现煤生物成气有2个主要的产气周期,芳香环、杂环化合物和苯衍生物在反应初期转化为VFA等,发生在第1个产气周期;而长链烷烃的生成有2个高峰期,分别对应2个产气周期。根据煤生物成气模拟实验中间代谢产物的实验结果,进一步选取乙酸钠、丙酸钠、丁酸钠、己酸为底物,仍以同一煤层气井口出水为菌源,进行产气实验模拟,结果显示乙酸、丙酸、丁酸可以产气,而己酸则对成气呈现抑制作用。以底物计算甲烷产生效率为丁酸>丙酸≈乙酸,丁酸约为乙酸和丙酸的4倍;而以碳数计算时甲烷产生效率则为丁酸>乙酸>丙酸,丁酸约为乙酸的2倍,说明不同的有机酸产甲烷时可能存在有机酸碳数奇偶性的差异。以上结果表明,VFA和长链烷烃在煤生物成气中发挥着重要的作用,而有关煤生物成气中VFA和长链烷烃的生成和转化以及其对成气的影响尚需进一步研究。 展开更多
关键词 生物成气 代谢产物 VFA 长链烷烃
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煤生物成气过程中溶解性有机物的光谱特征研究 被引量:7
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作者 赵同谦 李鹏 +5 位作者 邰超 象豫 李虹妍 马永霞 齐永安 张国成 《煤炭学报》 EI CAS CSCD 北大核心 2017年第S2期525-534,共10页
为进一步探讨煤生物成气过程中有机中间产物的变化特征,使用富集驯化后的底泥对3种煤样进行了煤生物成气模拟实验。对产气过程中产气量、液相样品中的可溶性有机质含量(总有机碳,TOC含量)、紫外和三维荧光光谱进行测定,并分析其耦合关... 为进一步探讨煤生物成气过程中有机中间产物的变化特征,使用富集驯化后的底泥对3种煤样进行了煤生物成气模拟实验。对产气过程中产气量、液相样品中的可溶性有机质含量(总有机碳,TOC含量)、紫外和三维荧光光谱进行测定,并分析其耦合关系。结果表明:3种煤样的产气过程均可分为3个产气周期:快速期、慢速期和产气停止期。成气过程中TOC含量总体下降,产气停止后含量有少量增高,TOC含量变化周期与产气时期具有一致性。紫外光谱及特征值显示产气过程中DOM分子量逐渐增大,芳构化程度增高,同时芳香环取代基上含氧官能团增多。荧光光谱显示成气过程中类蛋白荧光峰迅速降低,煤中的腐殖酸类物质转移到液相中,荧光基团中羰基、胺基和羟基含量增加。紫外和荧光光谱的变化与成气过程具有很好的耦合性,均表明煤中的有机质在微生物作用下进入液相并参与产气,但不同种类的物质对产气的作用不同。研究结论与此前GC-MS的相关研究结果相一致,且为煤生物成气过程中液相成分和性质的变化提供了参考。 展开更多
关键词 生物成气 溶解性有机物 紫外光谱 三维荧光光谱
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生物成气中离子和微量元素变化特征及健康风险评价 被引量:4
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作者 武俐 王海坡 +2 位作者 李鹏 赵同谦 曹斌 《煤炭学报》 EI CAS CSCD 北大核心 2021年第3期994-1002,共9页
向煤层中添加微生物群落和营养物质可产出甲烷,微生物在利用煤和营养物质进行成气时,典型离子与微量元素的质量浓度变化关系到周围环境安全性。为研究煤生物成气过程中液相微量元素的变化特征,选取河南平顶山、河南义马和山西长治3个地... 向煤层中添加微生物群落和营养物质可产出甲烷,微生物在利用煤和营养物质进行成气时,典型离子与微量元素的质量浓度变化关系到周围环境安全性。为研究煤生物成气过程中液相微量元素的变化特征,选取河南平顶山、河南义马和山西长治3个地区的煤样,开展模拟生物成气实验研究。利用离子色谱和电感耦合等离子质谱(ICP-MS)对成气过程中液相的Na^(+),NH_(4)^(+),K^(+),Cl^(-),PO_(4)^(3-)等常量离子与V,Cr,Mn,Co,Ni,Cu,Zn,As,Se,Ag,Cd,Sb,Ba,Ti,Pb等金属元素的质量浓度进行测定。结果表明,成气过程液相中,常量离子的质量浓度随产气时间增加基本保持稳定,微量元素的变化与产气过程有很强的相关性,成气过程中V,Ag和Cd未检出,而As,Ba,Co,Ni和Pb等微量元素的质量浓度均随产气时间的增加而升高,Pb,Se和Ti质量浓度的变化与煤样有关。Ba质量浓度最高,为23.88~144.79μg/L,As,Cu质量浓度分别为5.88~25.07,5.47~14.17μg/L,其他金属元素质量浓度较低。煤粉浸泡前10 d,溶液中Ba,Cu,Ni和Se的质量浓度逐渐升高,需特别关注。健康风险评价结果表明,非致癌物质Pb,Ni,Cu和Ba的风险范围在4.37×10^(-12)~1.48×10^(-9),远小于非致癌风险阈值1,其中,Cu的非致癌风险高于其他3种金属;致癌物As的风险范围在4.61×10^(-5)~1.96×10^(-4),均超过了致癌风险阈值1×10^(-6),表明As是煤生物成气过程中对健康危害最大的潜在污染物质,应引起高度关注。 展开更多
关键词 生物成气 常量离子 微量元素 健康风险评价 外源菌
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预处理前后厌氧条件下的生物成气实验模拟研究
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作者 韩作颖 《知识经济》 2013年第10期109-109,112,共2页
为了模拟生物成气过程以及对比经过兼性好氧微生物预处理后的煤样产气过程是否发生了变化,在实验过程中加入培养基用以提高体系中产甲烷菌的活性。这一主旨对于如何改善体系中营养物质平衡,促进菌群良性生长具有指导意义。
关键词 厌氧条件 生物成气 培养基
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预处理时间对煤炭生物成气的影响研究 被引量:1
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作者 王美林 陈林勇 关嘉栋 《煤》 2018年第5期7-9,21,共4页
为了研究预处理时间对煤炭生物成气的影响,利用双氧水对寺河地区高阶煤进行预处理,并对预处理过的煤粉清洗干燥后进行生物成气试验。结果表明,经过双氧水处理后煤样的最高产气量是原煤产气量的2倍,而且,并不是预处理时间越长产气效果越... 为了研究预处理时间对煤炭生物成气的影响,利用双氧水对寺河地区高阶煤进行预处理,并对预处理过的煤粉清洗干燥后进行生物成气试验。结果表明,经过双氧水处理后煤样的最高产气量是原煤产气量的2倍,而且,并不是预处理时间越长产气效果越好,处理时间太长可能会抑制产气,经双氧水处理过48 h的煤样用于生物成气,成气效果优于其他处理时间的煤样。不同预处理时间的样品产气中的CH_4和CO_2含量随着实验时间的增加逐渐增大,基本都是在实验第5周达到最大值;在整个产气过程中CH_4的生成速率远远高于CO_2的生成速率。 展开更多
关键词 双氧水 生物成气 预处理 高阶煤
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煤体微生物厌氧发酵对裂隙发育的响应规律 被引量:3
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作者 肖栋 王恩元 +1 位作者 彭苏萍 吴俊勇 《煤炭学报》 EI CAS CSCD 北大核心 2017年第5期1207-1212,共6页
基于二维承载条件的煤岩变形过程中的裂隙空间空气渗流试验、梯度含氧水平的煤体微生物厌氧发酵影响试验、与不同煤体粒径的微生物发酵试验,测试了煤体比表面积、裂隙含氧量对煤体厌氧发酵的影响关系,推演了不同深度煤体裂隙发育对厌氧... 基于二维承载条件的煤岩变形过程中的裂隙空间空气渗流试验、梯度含氧水平的煤体微生物厌氧发酵影响试验、与不同煤体粒径的微生物发酵试验,测试了煤体比表面积、裂隙含氧量对煤体厌氧发酵的影响关系,推演了不同深度煤体裂隙发育对厌氧微生物的生物活性影响规律与关键控制因素。结果表明:空气渗流大于1%的煤体中,空气渗流导致的厌氧环境的破坏作用,是抑制煤体厌氧发酵的主控制因素,而且煤体裂隙发育越迅速,空气渗流作用越强,煤体厌氧发酵抑制受控范围越大;空气渗流小于1%的煤体中,在兼氧菌对少量渗流空气缓冲作用影响下,裂隙发育对煤体比表面积的扩大作用是促进煤体厌氧发酵的主控因素,裂隙发育越充分,煤体比表面积越大,煤体的厌氧发酵速率提升越高。 展开更多
关键词 厌氧 煤体生物发酵 裂隙发育 生物成气 瓦斯积聚
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不同菌源作用下煤微生物产甲烷的对比研究 被引量:5
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作者 罗永涛 邰超 +4 位作者 武俐 佘加平 郝春生 赵同谦 齐永安 《煤炭转化》 CAS CSCD 北大核心 2018年第6期48-57,共10页
以矿井水为本源菌,以沼液、活性污泥和底泥为外源菌.从微生物群落构成和产气特征两个方面,分析4种菌源作用下5种煤样的微生物气化过程和产甲烷的差异性.结果表明:4种菌源的微生物主要由细菌和古菌构成,细菌占85%以上,古菌占整个菌群的5... 以矿井水为本源菌,以沼液、活性污泥和底泥为外源菌.从微生物群落构成和产气特征两个方面,分析4种菌源作用下5种煤样的微生物气化过程和产甲烷的差异性.结果表明:4种菌源的微生物主要由细菌和古菌构成,细菌占85%以上,古菌占整个菌群的5.8%~9.5%.本源菌和外源菌的微生物群落构成有共性,也存在一定差异,主要体现在细菌的芽孢杆菌科和古菌的广古菌门,本源菌中几乎未检出芽孢杆菌科,而3种外源菌中均有检出,所占比例随成气时间增加而增加.本源菌中广古菌门的初始比例高于3种外源菌;4种菌源的优势菌群均为Methanomassiliicoccaceae科.本源菌和外源菌作用下煤产甲烷过程分为三个阶段,表明本源菌和外源菌具有相似的成气特征.不同菌源作用下煤产甲烷的效率不同.与外源菌相比,本源菌作用下不同煤样的甲烷产生效率无明显优势.成气过程中,本源菌产氢气体积分数比3种外源菌低一个数量级,氢气生成量很少,说明本源菌中的产氢微生物群落较少,证明二氧化碳的氢还原过程并不主导第二阶段甲烷的生成. 展开更多
关键词 生物成气 本源菌 外源菌 甲烷 菌群结构
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过量煤粉对煤炭生物制甲烷的抑制作用 被引量:4
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作者 陈林勇 李国富 +5 位作者 刘建民 任恒星 何环 苗彪 赵娜 宋燕莉 《煤炭转化》 CAS CSCD 北大核心 2021年第6期8-15,共8页
以河南义马煤样为底物,以实验室保存的煤层气井排采水为菌源,在无机盐培养基培养条件下进行了煤生物成气模拟及转接实验。结果表明:过量煤粉在成气过程中会产生对产甲烷有抑制作用的物质。煤粉用量的梯度实验证实,氢气是生物甲烷生成过... 以河南义马煤样为底物,以实验室保存的煤层气井排采水为菌源,在无机盐培养基培养条件下进行了煤生物成气模拟及转接实验。结果表明:过量煤粉在成气过程中会产生对产甲烷有抑制作用的物质。煤粉用量的梯度实验证实,氢气是生物甲烷生成过程中的重要限制因素,产甲烷过程呈现CO_(2)还原途径特征。煤粉过量(100 mL发酵液中加入12.5 g煤粉)时显示出明显的产甲烷抑制作用,增加煤粉量并未提高产气效率。煤中甲醇萃取物产甲烷实验证明,过量的煤粉产生的抑制物的质荷比为130.1,分子式可能为C_(6)H_(11)NO_(2)。 展开更多
关键词 生物成气 甲醇萃取物 抑制物 质荷比 CO2还原途径
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Conversion of Bio-syngas to Liquid Hydrocarbon over CuCoMn-Zeolite Bifunctional Catalysts 被引量:1
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作者 张朝霞 毕培燕 +1 位作者 姜沛汶 李全新 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第5期573-581,I0004,共10页
A series of bifunctional catalysts composed of a component for higher alcohol synthesis (Cu-CoMn oxides, CCM) and an acidic zeolite (SAPO-34, ZSM-5, Y, MCM-41) were prepared for production of liquid hydrocarbon di... A series of bifunctional catalysts composed of a component for higher alcohol synthesis (Cu-CoMn oxides, CCM) and an acidic zeolite (SAPO-34, ZSM-5, Y, MCM-41) were prepared for production of liquid hydrocarbon directly from a bio-syngas through a one-stage pro-cess. The effects of zeolite type, zeolite content, Si/Al ratio and preparation method on catalyst texture and its reaction performance were investigated. Higher selectivities and yields of liquid products were obtained by using bifunctional catalysts. The yields of liquid hydrocarbons decreased in the order CCM-ZSM-5〉CCM-SAPO-34〉CCM-Y〉CCM-MCM-41. CCM-ZSM-5 (20wt%, Si/Al=100) prepared by coprecipitation method displayed the optimal catalytic performance with the highest CO conversion (76%) and yield of liquid products (30%). The catalysts were characterized by N2 adsorption/desorption, NH3-TPD, XRD, and H2-TPR analysis. The results showed that higher speci c surface areas and pore volumes of bifunctional catalysts were achieved by adding zeolites into CuCoMn precursors. Medium pore dimension and moderate acidity in CCM-ZSM-5 were observed, which proba-bly resulted in its excellent reaction performance. Additionally, a higher number of weaker acid sites (weak and/or medium acid sites) were formed by increasing ZSM-5 content in CCM-ZSM-5 or decreasing Si/Al ratio in ZSM-5. It was also seen that metal dispersion was higher and reducibility of metal ions was easier on the CCM-ZSM-5 catalyst prepared by coprecipitation. The higher alcohols-to-hydrocarbon process provides a promising route to hydrocarbon fuels via higher alcohols from syngas or biobased feedstocks. 展开更多
关键词 BIFUNCTIONAL CuCoMn-zeolite Higher alcohols-to-hydrocarbon process Bio-syngas conversion Liquid hydrocarbon synthesis
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Production of Mixed Alcohols from Bio-syngas over Mo-based Catalyst
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作者 仇松柏 黄伟伟 +2 位作者 徐勇 刘璐 李全新 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2011年第1期77-84,I0004,共9页
A series of Mo-based catalysts prepared by sol-gel method using citric acid as complexant were successfully applied in the high efficient production of mixed alcohols from bio-syngas, derived from the biomass gasifica... A series of Mo-based catalysts prepared by sol-gel method using citric acid as complexant were successfully applied in the high efficient production of mixed alcohols from bio-syngas, derived from the biomass gasification. The Cu1Co1Fe1MO1Zn0.5-6%K catalyst exhibited a higher activity on the space-time yield of mixed alcohols, compared with the other Mobased catalysts. The carbon conversion significantly increases with rising temperature below 340 ℃, but the alcohol selectivity has an opposite trend. The maximum mixed alcohols yield derived from biomass gasification is 494.8 g/(kg catal·h) with the C2+ (C2-C6 higher alcohols) alcohols of 80.4% under the tested conditions. The alcohol distributions are consistent with the Schulz-Flory plots, except methanol. In the alcohols products, the C2+ alcohols (higher alcohols) dominate with a weight ratio of 70%-85%. The Mo-based cata- lysts have been characterized by X-ray diffraction and N2 adsorption/desorption. The clean bio-fules of mixed alcohols derived from bio-syngas with higher octane values could be used as transportation fuels or petrol additives. 展开更多
关键词 Biomass Bio-syngas Mixed alcohol Mo-based catalyst Biomass Bio-syngas Mixed alcohol Mo-based catalyst
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Bio-methanol from Bio-oil Reforming Syngas Using Dual-reactor
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作者 叶同奇 颜世志 +3 位作者 徐勇 仇松柏 刘勇 李全新 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2011年第4期457-463,I0004,共8页
A dual-reactor, assembled with the on-line syngas conditioning and methanol synthesis, was successfully applied for high efficient conversion of rich CO2 bio-oil derived syngas to bio-methanol. In the forepart catalys... A dual-reactor, assembled with the on-line syngas conditioning and methanol synthesis, was successfully applied for high efficient conversion of rich CO2 bio-oil derived syngas to bio-methanol. In the forepart catalyst bed reactor, the catalytic conversion can effectively adjust the rich-CO2 crude bio-syngas into the CO-containing bio-syngas using the CuZnA1Zr catalyst. After the on-line syngas conditioning at 450℃, the CO2/CO ratio in the blo- syngas significantly decreased from 6.3 to 1.2. In the rearward catalyst bed reactor, the conversion of the conditioned bio-syngas to bio-methanol shows the maximum yield about 1.21 kg/(kgcatarh) MeOH with a methanol selectivity of 97.9% at 260 ~C and 5.05 MPa using conventional CuZnA1 catalyst, which is close to the level typically obtained in the conventional methanol synthesis process using natural gas. The influences of temperature, pressure and space velocity on the bio-methanol synthesis were also investigated in detail. 展开更多
关键词 Bio-methanol Bio-syngas CuZnA1Zr catalyst On-line syngas conditioning
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Study on fluidized-bed pyrolysis of waste paper
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作者 肖刚 池涌 +3 位作者 倪明江 岑可法 肖睿 黄亚继 《Journal of Southeast University(English Edition)》 EI CAS 2007年第2期285-288,共4页
A lab-scale fluidized bed is setup and pyrolysis experiments are carried out. When temperature ranges from 400 to 700 ℃, the yields of solid residue, bio-oil and syngas range from 36% to 18%, 19% to 30% and 9% to 42%... A lab-scale fluidized bed is setup and pyrolysis experiments are carried out. When temperature ranges from 400 to 700 ℃, the yields of solid residue, bio-oil and syngas range from 36% to 18%, 19% to 30% and 9% to 42%, respectively, and the mass balance of pyrolysis ranges from 80% to 95%. At 400 to 700 ℃, the characteristics of bio-oil are similar and the heat value is about 10 MJ/kg. When the temperature is over 600℃, the yield of syngas increases approximately twice as much as that at 500 ℃. The yields of CO2 and CO increase from 70 to 230 L/kg and 50 to 106 L/kg, respectively, while the yield of syngas only increases about 5% when the temperature increases from 600 to 700 ℃. The results indicate that the pyrolysis mechanism of waste paper is similar from 400 to 700 ℃, while the yield of syngas can be affected by secondary pyrolysis of bio-oil. 展开更多
关键词 waste paper fluidized bed PYROLYSIS SYNGAS BIO-OIL
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不同菌源降解乙酸的产气效果及代谢途径
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作者 王美林 《能源与环保》 2018年第5期84-87,90,共5页
为了研究不同菌源降解乙酸的产气效果和代谢途径,选用煤层水和污泥2种产甲烷菌菌源进行了为期56 d的生物成气试验,分析了2种菌源降解乙酸的最佳浓度、抑制浓度及产气规律,并分析了2种菌源降解乙酸的代谢途径。结果表明,煤层水菌源和污... 为了研究不同菌源降解乙酸的产气效果和代谢途径,选用煤层水和污泥2种产甲烷菌菌源进行了为期56 d的生物成气试验,分析了2种菌源降解乙酸的最佳浓度、抑制浓度及产气规律,并分析了2种菌源降解乙酸的代谢途径。结果表明,煤层水菌源和污泥菌源都能降解乙酸产气,并且在乙酸浓度为0.5‰时产气最佳,但是当乙酸浓度大于5‰时,产甲烷过程受到抑制;2种菌源降解乙酸的产气过程都经历了产气量缓慢增加阶段—急剧增加阶段—相对稳定阶段3个阶段,而且大量产气基本在21~42 d时。通过分析产气中的各组分含量,初步判断实验中煤层水菌源生成甲烷的代谢途径主要为二氧化碳还原,污泥菌源生成甲烷的代谢途径主要为乙酸发酵。 展开更多
关键词 产甲烷菌 生物成气 乙酸 成气效果 代谢途径
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Preparation of Bio-hydrogen and Bio-fuels from Lignocellulosic Biomass Pyrolysis-Oil
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作者 姜沛汶 吴小平 +1 位作者 刘俊旭 李全新 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2016年第5期635-643,I0002,共10页
In recent years, production of engine fuels and energy from biomass has drawn much interest. In this work, we conducted a novel integrated process for the preparation of bio-hydrogen and bio-fuels using lignocellulosi... In recent years, production of engine fuels and energy from biomass has drawn much interest. In this work, we conducted a novel integrated process for the preparation of bio-hydrogen and bio-fuels using lignocellulosic biomass pyrolysis-oil (bio-oil). The process includes (i) the production of bio-hydrogen or bio-syngas by the catalytic cracking of bio-oil, (ii) the adjustment of bio-syngas, and (iii) the production of bio-fuels by ole nic polymerization (OP) together with Fischer-Tropsch synthesis (FTS). Under the optimal conditions, the yield of bio-hydrogen was 120.9 g H2/(kg bio-oil). The yield of hydrocarbon bio-fuels reached 526.1 g/(kg bio-syngas) by the coupling of OP and FTS. The main reaction pathways (or chemical processes) were discussed based on the products observed and the catalyst property. 展开更多
关键词 Biomass pyrolysis-oil BIO-HYDROGEN Olefins polymerization Fischer-Tropsch synthesis BIO-FUELS
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Life Cycle Cost of Electricity Generation from Biomass Gasifier 被引量:5
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作者 Debabrata Lahiri Gokul Achariee 《Journal of Energy and Power Engineering》 2013年第11期2060-2067,共8页
India is having more than 500,000 villages of which about 85% have been electrified. But as per RGGVY (Rejiv Gandhi Grammen Vidyutikaran Yojana), the rate of village electrification is much lower as household connec... India is having more than 500,000 villages of which about 85% have been electrified. But as per RGGVY (Rejiv Gandhi Grammen Vidyutikaran Yojana), the rate of village electrification is much lower as household connectivity has been fairly low. The rest 15% villages and a larger proportion of households have to be electrified. Villages have been a major concern as cost of electrification is fairly high. The most favored alternative to any kind of users is generation of electricity from diesel generating sets and renewable sources of energy. But the capital cost of renewable energy equipments is fairly high. Gradually, there is a reduction in the prices of these systems due to availability of better technological options and they are becoming competitive to grid electricity. In this paper, an attempt has been made to calculate the cost of production of electricity from stand-alone, off-grid devices biomass gasifiers (both dual fuel and pure gas type) and compare with that of diesel generating sets by using the concept of LCC (life cycle costing) and Homer software. It is found that the cost of per unit electricity generation (kWh) has been always the lowest in comparison to diesel generating sets even if the price of biomass increases to some extent. 展开更多
关键词 Biomass gasifier DIESEL OFF-GRID life cycle costing.
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Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion 被引量:1
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作者 马庆兰 黄强 +3 位作者 陈光进 王秀林 孙长宇 杨兰英 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第3期295-300,共6页
The systematic experimental studies were performed on the hydrate formation kinetics and gas-hydrate equilibrium for a simulated catalytic cracking gas in the water-in-oil emulsion. The effect of temperature, pressure... The systematic experimental studies were performed on the hydrate formation kinetics and gas-hydrate equilibrium for a simulated catalytic cracking gas in the water-in-oil emulsion. The effect of temperature, pressure and initial gas-liquid ratio on the hydrate formation was studied, respectively. The data were obtained at pressures ranging from 3.5 to 5 MPa and temperatur.es from 274.15 to 277.15 K. The results showed that hydrogen and methane can be separated Irom the (~2+ ti'action by tOrming hydrate at around 273.15 K which is much higher temperature than that of the cryogenic separation method, and the hydrate formation rate can be enhanced in the wa- ter-in-oil emulsion compared to pure water. The experiments provided the basic data for designing the industrial process, and setting the suitable operational conditions. The measured data ot gas-hydrate equilibria were compared with the predictions by using the Chen-Guo hydrate thermodynamic model. 展开更多
关键词 HYDRATE catalytic cracking dry gas SEPARATION EMULSION
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Environmental change and its effects on inter-decadal variations of diatom production, species composition and frustule dissolution in a coastal marginal sea
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作者 Rediat ABATE 高亚辉 +4 位作者 陈长平 梁君荣 陈蔚芳 孙琳 Demeke KIFILE 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2017年第6期1362-1373,共12页
The implications of climate change during the second half of the 20th century have been reported throughout the world. Although marginal seas are sensitive to climate change and anthropogenic impacts, relatively littl... The implications of climate change during the second half of the 20th century have been reported throughout the world. Although marginal seas are sensitive to climate change and anthropogenic impacts, relatively little attention has been given to the South East Asian marginal seas. Thus, to bridge this gap in knowledge, a sediment core was collected from the coastal areas of the Leizhou Peninsula in the South China Sea (SCS) to study the inter-decadal climate change and its consequences using diatom species composition as a proxy record. Diatom absolute abundance varied from 2 300 to 68 000 and averaged 16 000 valves per gram of dry weight (v/gdw). The fractional dissolution index (F~) was usually below 0.5, which indicates low to moderate preservation of diatom valves at coastal area of the SCS. At the inter-decadal time scale, total diatom abundance was high for the period after 1972, which coincided with 1) increased percentage of planktonic diatom abundance and F~; 2) emergence and dominance of high productivity indicative cosmopolitan species such as Thalassionema nitzschioides and Paralia sulcata (their relative abundance increased from 〈1.5% to 〉7% for the period before and after 1972, respectively); 3) decreased relative abundance of the small-sized eutrophication indicative species, Cyclotella striata, from 70% to 40%. This study reveals that variations in the abundance of diatoms preserved in the sediment was a function of both production and dissolution/preservation of diatom valves, which in turn was intimately connected to the prevailing environmental/climatic conditions. In conclusion, these data reveal the existence of substantial changes in the coastal SCS in response to the 1970s climate shift that was recorded in different parts of the world. 展开更多
关键词 benthic diatoms dissolution index planktonic diatoms primary productivity South China Sea
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Torrefied Pellets as Fuel for Two-Stage Technology of Biomass Conversion into Synthesis Gas
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作者 Victor Zaichenko Valentin Kosov Julia Kuzmina Vladimir Lavrenov 《Journal of Energy and Power Engineering》 2014年第1期79-84,共6页
One of the most important properties of the torrefied pellets, along with high calorific value, is their hydrophobicity. Inability to absorb moisture and self-destruct under its influence determine possibility of usin... One of the most important properties of the torrefied pellets, along with high calorific value, is their hydrophobicity. Inability to absorb moisture and self-destruct under its influence determine possibility of using of pellets in the pyrolysis reactor. For the technology of two-stage thermal processing of biomass, developed at the Joint Institute for High Temperatures, the amount of synthesis gas which can be obtained from one kilogram of torrefied pellets is also important. A construction of the pilot torrefaction reactor powered by flue gas is shown. The results of experimental investigations of hydrophobicity of torrefied pellets produced by the reactor and quantity of synthesis gas which can be obtained by two-stage thermal processing of the pellets are presented. It is shown that torrefaction allows simplifying the process of conversion of pellets into synthesis gas without significant reduction in the volume of the gas. 展开更多
关键词 Biomass conversion TORREFACTION PYROLYSIS syngas.
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Effects of transport on aerosols over the eastern slope of the Tibetan Plateau:synergistic contribution of Southeast Asia and the Sichuan Basin 被引量:1
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作者 SU Hong-Juan XIN Jin-Yuan +8 位作者 MA Yong-Jing LIU Zirui WEN Tian-Xue WANG Shi-Gong FAN Guang-Zhou LI Wei WANG Lu HE Zhi-Ming WANG Yue-Si 《Atmospheric and Oceanic Science Letters》 CSCD 2018年第5期425-431,共7页
The aerosol optical properties and chemical components of PM2.1(particulate matter with a diameter of 2.1μm or less)were investigated at Mount Gongga on the eastern slope of the Tibetan Plateau from April 2012 to Dec... The aerosol optical properties and chemical components of PM2.1(particulate matter with a diameter of 2.1μm or less)were investigated at Mount Gongga on the eastern slope of the Tibetan Plateau from April 2012 to December 2014.The annual mean aerosol optical depth(AOD)was 0.35±0.23,and the?ngstr?m exponent was 1.0±0.38.The AOD exhibited higher values in summer and winter,but lower values in spring and autumn.Dividing the observational periods into dry and wet seasons,the authors found that the concentrations of K^+,elemental carbon,secondary inorganic aerosols,and primary and secondary organic carbon in the dry(wet)season were 0.29(0.21),0.88(0.60),7.4(4.5),7.5(5.1),and 3.9(12)μg m?3,respectively.Combined with trajectory analysis,the authors found that higher concentrations of K^+,elemental carbon,and primary organic carbon indicated the effects of biomass burning from Southeast Asia during the dry season.However,the oxidation of volatile organic compounds was the main source of aerosols during the wet season,which originated from the Sichuan Basin. 展开更多
关键词 Tibetan Plateau aerosol optical depth aerosol components biomass burning regional transport
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Chemical and Biological Assessments of the Essential Oils of Chrysophyllum albidum G, Don
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作者 Fatimah Temitayo Ishola Sherifat Adeyinka Aboaba +1 位作者 Muhammad Iqbal Choudhary Olusegun Ekundayo 《Journal of Agricultural Science and Technology(A)》 2017年第4期234-245,共12页
The chemical compositions of the essential oils obtained from six tree parts of Chrysophyllum albidum (Sapotaceae) were extracted by hydrodistillation and analyzed by gas chromatography (GC) and gas chromatography... The chemical compositions of the essential oils obtained from six tree parts of Chrysophyllum albidum (Sapotaceae) were extracted by hydrodistillation and analyzed by gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). A total of 65, 33, 45, 21, 25 and 18 compounds, representing 79.49%, 100%, 90.81%, 98.43%, 96.62% and 98.37% of the total oil, were identified in the fruit bark, root bark, stem bark, seed bark, leaf and seed, respectively. The dominant compounds in the essential oils in six tree parts were m-xylene (66.7%; seed), p-xylene (21.4%; seed bark), a-farnesene (38.1%; leaf), hexadecanoic acid (14.7%; stem bark), m-xylene (53.1%; root bark) and hexadecanoic acid (12.7%; fruit bark). The essential oils were evaluated for their antibacterial, antioxidant and insecticidal activities using Alamar blue assay, DPPH radical scavenging activity and contact toxicity test, respectively. The oils displayed moderate antibacterial potentials to some tested organisms and low radical scavenging activity to DPPH. Rhyzopertha dominica was susceptible to C. albidum stem bark essential oil only. 展开更多
关键词 Chrysophyllum albidum essential oil gas chromatography antioxidant activity insecticidal activity Alamar blue assay.
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