Reaction of the trivacant heteropolyanions α A PW9O349- with CH3SiCl3 leads to the formation of the organosilyl derivative (TBA)3[α A PW9O34(CH3SiO)3(CH3Si)]. The crystal X ray diffraction analysis shows that the cr...Reaction of the trivacant heteropolyanions α A PW9O349- with CH3SiCl3 leads to the formation of the organosilyl derivative (TBA)3[α A PW9O34(CH3SiO)3(CH3Si)]. The crystal X ray diffraction analysis shows that the crystalbelongs to orthorhombic with space group Pca21, M=3177.09 and the unit cell parameters: a=25.761(5)?,b=14.519(3)?,c=24.396(5)?.V=9124(3)?3,Z=4,Dc=2.225g·cm-3,μ(MoKα)=11.438mm-1,F(000)=5464,R=0.0561,Rw=0.0866. The anion consists of one α A PW9O349- anion linked by three CH3SiO+ groups, whichattached to the fourth CH3Si through three Si O Si bridges.展开更多
We sampled the sediments of the East China Sea during 2005 and 2006, and analysed the contents of the biogenic matters: biogenic silica, organic carbon, and organic nitrogen. From the surface distribution we found the...We sampled the sediments of the East China Sea during 2005 and 2006, and analysed the contents of the biogenic matters: biogenic silica, organic carbon, and organic nitrogen. From the surface distribution we found the contents of these substances to be in the ranges of 0.72%-1.64%, 0.043%-0.82%, and 0.006%-0.11%, respectively. Their distributions were similar to each other, being high inside the Hangzhou Bay and low outside the bay. The vertical variations of the contents were also similar. In order to discuss the relation between them we analysed the variations of content with depth. They increased in the first 7 cm and then decreased with depth. The peaks were found at depths between 20 to 25 cm. The distribution of carbonate showed an opposite trend to that of biogenic matters. The content of total carbon was relatively stable with respect to depth, and the ratio of high organic carbon to carbonate showed a low burial efficiency of carbonate, which means that the main burial of carbon is organic carbon. In order to discuss the source of organic matters, the ratio of organic carbon to organic nitrogen was calculated, which was 8.01 to 9.65, indicating that the organic matter in the sediments was derived mainly from phytoplankton in the seawater.展开更多
A field experiment was carried out in Cd-contaminated rice fields in a county of Hengyang to explore the effects of different types of remediation agents on the contents of soil available Cd and rice Cd,and rice yield...A field experiment was carried out in Cd-contaminated rice fields in a county of Hengyang to explore the effects of different types of remediation agents on the contents of soil available Cd and rice Cd,and rice yield by using one rice variety Longliangyouhuazhan,and 4 kinds of remediation agents:DG foliar control agent,SMA microbial inoculant,XFJ organic fertilizer and LXM calcium-and silicon-based passivator as test materials.The results showed that compared with CK,after applying DG foliar control agent,soil available Cd content increased rather than decreased,whereas rice Cd content decreased,not reaching a significant level.When applied with SMA microbial inoculant,soil pH value,soil available Cd and rice Cd contents showed a downward then upward trend with the increase of its application rates.Between 3 levels of SMA treatments,the content of soil available Cd in SMA2 was the lowest,decreased by 8.59%in comparison with CK,contrarily,two other SMA treatments were increasing instead of decreasing in the content of soil available Cd.The application of XFJ organic fertilizer and LXM calcium-and silicon-based passivator increased soil pH value,and reduced soil available Cd and rice Cd contents;the contents of soil available Cd and rice Cd decreased with their application rates increasing.Compared with CK,XFJ3 reduced soil available Cd content by 9.40%,and significantly reduced rice Cd content by 57.28%.In LXM3 treatment,soil available Cd content reduced by 14.57%,rice Cd content was 71.57%lower than CK,reaching the lowest level.In general,LXM calcium-and silicon-based passivator had the best Cd reduction effect,with the optimal application amount of 6000 kg/hm^(2).展开更多
文摘Reaction of the trivacant heteropolyanions α A PW9O349- with CH3SiCl3 leads to the formation of the organosilyl derivative (TBA)3[α A PW9O34(CH3SiO)3(CH3Si)]. The crystal X ray diffraction analysis shows that the crystalbelongs to orthorhombic with space group Pca21, M=3177.09 and the unit cell parameters: a=25.761(5)?,b=14.519(3)?,c=24.396(5)?.V=9124(3)?3,Z=4,Dc=2.225g·cm-3,μ(MoKα)=11.438mm-1,F(000)=5464,R=0.0561,Rw=0.0866. The anion consists of one α A PW9O349- anion linked by three CH3SiO+ groups, whichattached to the fourth CH3Si through three Si O Si bridges.
基金supported by the National Key Basic Research Program (973) (Grant No. 2010CB428701)
文摘We sampled the sediments of the East China Sea during 2005 and 2006, and analysed the contents of the biogenic matters: biogenic silica, organic carbon, and organic nitrogen. From the surface distribution we found the contents of these substances to be in the ranges of 0.72%-1.64%, 0.043%-0.82%, and 0.006%-0.11%, respectively. Their distributions were similar to each other, being high inside the Hangzhou Bay and low outside the bay. The vertical variations of the contents were also similar. In order to discuss the relation between them we analysed the variations of content with depth. They increased in the first 7 cm and then decreased with depth. The peaks were found at depths between 20 to 25 cm. The distribution of carbonate showed an opposite trend to that of biogenic matters. The content of total carbon was relatively stable with respect to depth, and the ratio of high organic carbon to carbonate showed a low burial efficiency of carbonate, which means that the main burial of carbon is organic carbon. In order to discuss the source of organic matters, the ratio of organic carbon to organic nitrogen was calculated, which was 8.01 to 9.65, indicating that the organic matter in the sediments was derived mainly from phytoplankton in the seawater.
文摘A field experiment was carried out in Cd-contaminated rice fields in a county of Hengyang to explore the effects of different types of remediation agents on the contents of soil available Cd and rice Cd,and rice yield by using one rice variety Longliangyouhuazhan,and 4 kinds of remediation agents:DG foliar control agent,SMA microbial inoculant,XFJ organic fertilizer and LXM calcium-and silicon-based passivator as test materials.The results showed that compared with CK,after applying DG foliar control agent,soil available Cd content increased rather than decreased,whereas rice Cd content decreased,not reaching a significant level.When applied with SMA microbial inoculant,soil pH value,soil available Cd and rice Cd contents showed a downward then upward trend with the increase of its application rates.Between 3 levels of SMA treatments,the content of soil available Cd in SMA2 was the lowest,decreased by 8.59%in comparison with CK,contrarily,two other SMA treatments were increasing instead of decreasing in the content of soil available Cd.The application of XFJ organic fertilizer and LXM calcium-and silicon-based passivator increased soil pH value,and reduced soil available Cd and rice Cd contents;the contents of soil available Cd and rice Cd decreased with their application rates increasing.Compared with CK,XFJ3 reduced soil available Cd content by 9.40%,and significantly reduced rice Cd content by 57.28%.In LXM3 treatment,soil available Cd content reduced by 14.57%,rice Cd content was 71.57%lower than CK,reaching the lowest level.In general,LXM calcium-and silicon-based passivator had the best Cd reduction effect,with the optimal application amount of 6000 kg/hm^(2).
