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3种生物纤维素膜的结构与性能 被引量:3
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作者 张传杰 王柳 +2 位作者 王治凯 薛青芳 朱平 《功能材料》 EI CAS CSCD 北大核心 2011年第S4期617-620,共4页
采用无风电热干燥、真空干燥和冷冻干燥等3种方式处理生物纤维素凝胶膜,制备了3种生物纤维素膜(BC1、BC2、BC3),然后研究了其SEM形貌、IR、XRD和物理机械性能、孔隙率、吸液量、保液量、水蒸气透过率、透光率和热稳定性能。结果表明BC1... 采用无风电热干燥、真空干燥和冷冻干燥等3种方式处理生物纤维素凝胶膜,制备了3种生物纤维素膜(BC1、BC2、BC3),然后研究了其SEM形貌、IR、XRD和物理机械性能、孔隙率、吸液量、保液量、水蒸气透过率、透光率和热稳定性能。结果表明BC1的表面致密,BC2的孔洞和裂缝较BC1明显,BC3具有层状和孔洞结构。3种BC膜的晶型都是纤维素Ⅰ,但是BC1的结晶度为73.9%,BC2的结晶度为63.8%,BC3的结晶度为58.2%。BC1的弹性模量、断裂强度、透光率和热稳定性最好,BC3的孔隙率、吸液量、保液量和透湿性能最优异,BC2的各项性能处于BC1和BC3之间。 展开更多
关键词 生物纤维素膜 电热干燥 真空干燥 冷冻干燥 结构与性能
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CMC/Tb-Eu荧光性膜的结构与性能分析 被引量:2
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作者 叶君 付紫昌 熊犍 《华南理工大学学报(自然科学版)》 EI CAS CSCD 北大核心 2019年第8期113-119,共7页
采用流延法制备了含有CMC/Tb-Eu(CTE)的羧甲基纤维素(CMC)复合荧光膜,研究了CTE悬浮液的流变性能,并由傅里叶变换红外光谱(FTIR)、原子力显微镜(AFM)、荧光光谱(FL)以及力学测试对复合膜的结构与性能进行了表征.流变学结果表明,质量分数... 采用流延法制备了含有CMC/Tb-Eu(CTE)的羧甲基纤维素(CMC)复合荧光膜,研究了CTE悬浮液的流变性能,并由傅里叶变换红外光谱(FTIR)、原子力显微镜(AFM)、荧光光谱(FL)以及力学测试对复合膜的结构与性能进行了表征.流变学结果表明,质量分数为2%~6%的CTE悬浮液保持了CMC溶液剪切变稀的流变特征.FTIR表明:膜的形成过程并未改变CTE粒子的化学结构,即Tb^3+或Eu^3+与CMC发生配位和离子交换反应;当激发波长为374nm时,复合膜发射Tb^3+和Eu^3+的特征荧光光谱,其中在543nm处的发射峰荧光强度最大,为Tb^3+的5D4→7F5发射;当CTE添加量为0.2g时,膜的荧光强度最强.力学性能显示,CTE含量增加可同时提升膜的拉伸模量和抗张强度,断裂伸长率变化没有显著性差异,膜的最大拉伸模量为4.179GPa,最大抗张强度为78.76MPa. 展开更多
关键词 纤维素生物荧光 制备 非牛顿流体 结构 荧光性能 力学性质
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Preparation of High Quality Indium Tin Oxide Film on a Microbial Cellulose Membrane Using Radio Frequency Magnetron Sputtering 被引量:2
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作者 杨加志 赵成刚 +3 位作者 刘晓丽 于俊伟 孙东平 唐卫华 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第2期179-184,共6页
Microbial cellulose (MC) membranes produced by Acetobacter xylinum NUST4.1,were used as flexible substrates for the fabrication of transparent indium tin oxide (ITO) electrodes.Transparent and conductive ITO thin ... Microbial cellulose (MC) membranes produced by Acetobacter xylinum NUST4.1,were used as flexible substrates for the fabrication of transparent indium tin oxide (ITO) electrodes.Transparent and conductive ITO thin films were deposited on MC membrane at room temperature using radio frequency (RF) magnetron sputtering.The optimum ITO deposition conditions were achieved by examining crystalline structure,surface morphology and op-toelectrical characteristics with X-ray diffraction (XRD),scanning electron microscopy (SEM),atomic force mi-croscopy (AFM),and UV spectroscopy.The sheet resistance of the samples was measured with a four-point probe and the resistivity of the film was calculated.The results reveal that the preferred orientation of the deposited ITO crystals is strongly dependent upon with oxygen content (O2/Ar,volume ratio) in the sputtering chamber.And the ITO crystalline structure directly determines the conductivity of ITO-deposited films.High conductive [sheet resis-tance ~120 Ω·square-1 (Ω·sq-1)] and transparent (above 76%) ITO thin films (240 nm thick) were obtained with a moderate sputtering power (about 60 W) and with an oxygen flow rate of 0.25 ml·min-1 (sccm) during the deposi-tion.These results show that the ITO-MC electrodes can find their potential application in optoelectrical devices. 展开更多
关键词 thin films magnetron sputtering microbial cellulose membrane optical properties indium tin oxide
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Study on the Treatment of Cellulosic Ethanol
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作者 Zhihui Shi Jizu Yuan Zonghua Wang 《Journal of Environmental Science and Engineering》 2010年第1期20-24,共5页
Wastewater from the production of cellulosic ethanol was treated by the processes of internal micro-electrolysis method +ABR+UASB +MBR. The results of running indicated that, when COD is 12000 mg/L and HRT of UASB ... Wastewater from the production of cellulosic ethanol was treated by the processes of internal micro-electrolysis method +ABR+UASB +MBR. The results of running indicated that, when COD is 12000 mg/L and HRT of UASB is 48 h, the COD removal rate reaches 72% and HRT of MBR is 20 h, COD removal rate is between 80.8% and 87.5%. The effluent COD concentration stabilized at 301- 537 mg/L, it indicates that the MBR system has a strong ability to resist impact load. 展开更多
关键词 Cellulosic ethanol MICRO-ELECTROLYSIS UASB MBR.
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Production of D-p-Hydroxyphenylglycine from DL-5-p-Hydroxyphenyl Hydantoin by Immobilized Pseudomonas Putida Cells in a Hollow Fiber Membrane Bioreactor
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作者 张铭俊 张衍坤 +2 位作者 李京华 李曙光 虞星炬 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1999年第1期86-90,共5页
An immobilized cell membrane bioreaction system was developed to promote cell stability. The hollow fiber membrane bioreactor with immobilized Pseudomonas putida cells, operating in continual repeated batch operation ... An immobilized cell membrane bioreaction system was developed to promote cell stability. The hollow fiber membrane bioreactor with immobilized Pseudomonas putida cells, operating in continual repeated batch operation mode was used for producing D-p-hydroxyphenylglycine from DL-5-p-hydroxyphenyl hydantoin. The concentration of N-carbamyl-D-p-hydroxyphenylglycine and D-p-hydroxyphenylglycine in the efflux was analyzed by high performance liquid chromatography at different intervals. 展开更多
关键词 D-P-HYDROXYPHENYLGLYCINE immobilized Pseudomonas putida cells hollow fiber mem-brane bioreactor
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