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操作参数对生物质再燃脱硝特性的影响 被引量:3
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作者 郝江涛 于伟 +1 位作者 卢平 祝秀明 《南京师范大学学报(工程技术版)》 CAS 2013年第4期29-34,共6页
以稻壳(RH)、木屑(SD)和生物质炭(BC)3种生物质为对象,利用携带流脱硝试验装置,研究了再燃区反应温度(T2)、再燃区化学计量比(SR2)、停留时间(τ)、NO初始浓度(CNO,in)、水蒸气含量、生物质种类及添加剂等对生物质再燃脱... 以稻壳(RH)、木屑(SD)和生物质炭(BC)3种生物质为对象,利用携带流脱硝试验装置,研究了再燃区反应温度(T2)、再燃区化学计量比(SR2)、停留时间(τ)、NO初始浓度(CNO,in)、水蒸气含量、生物质种类及添加剂等对生物质再燃脱硝效果的影响.结果表明:在T2=850℃-1150℃范围内,随着T2升高,再燃脱硝效率呈现逐渐上升的趋势.在SR2=0.5-1.0范围内,生物质再燃脱硝效率随着SR2降低而逐渐上升.在τ=0.5-1.3 s范围内,生物质再燃脱硝效率随着τ增加呈现先上升后趋于稳定的趋势.在CNO,in=300-600μL/L范围内,生物质再燃脱硝效率随着CNO,in增加逐渐增加,但当CNO,in〉400μL/L时,脱硝效率增加不明显.随着烟气中水蒸气含量增加,生物质再燃脱硝效率呈现先增加后降低并逐渐趋于平稳的趋势,模拟烟气中含有4%水蒸气时的脱硝效率最大.不同生物质的再燃脱硝效率显著不同,RH和SD的脱硝效率明显高于BC.添加剂对脱硝效果有一定的促进作用,其中, NaCl促进作用最为显著.添加剂(Fe2O3)浓度(50-150μmol/mol)对生物质再燃脱硝效率的影响不大. 展开更多
关键词 生物质再燃 脱硝 水蒸气 添加剂
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生物质再燃降低燃煤锅炉NO_x排放研究综述 被引量:5
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作者 林鹏云 罗永浩 胡元 《锅炉技术》 北大核心 2006年第3期68-71,共4页
我国能源结构以化石燃料为主,不可再生且污染严重,开发和推广应用可再生能源,逐步调整与优化能源结构,意义重大。生物质能是一种清洁可再生能源,也是当前世界能源研究热点之一。重点介绍了生物质再燃利用技术的原理和应用现状,生... 我国能源结构以化石燃料为主,不可再生且污染严重,开发和推广应用可再生能源,逐步调整与优化能源结构,意义重大。生物质能是一种清洁可再生能源,也是当前世界能源研究热点之一。重点介绍了生物质再燃利用技术的原理和应用现状,生物质再燃技术包括直接再燃、气化再燃以及高级再燃,使用生物质用于燃煤锅炉再燃,既可以合理利用生物质,又能有效降低燃煤锅炉的NOx排放,NOx减排率可达50%~90%,具有广阔的推广和应用前景。 展开更多
关键词 生物质 生物质再燃 燃煤锅炉 NOX减排
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生物质再燃焦管道喷射脱汞性能 被引量:1
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作者 卢平 史加腾 +1 位作者 叶扬天 蒋何伟 《化工进展》 EI CAS CSCD 北大核心 2019年第5期2461-2468,共8页
采用高温携带流反应装置在1050℃和1150℃条件下制备了稻壳再燃焦(RH1050和RH1150)和小麦秸秆再燃焦(WS1050和WS1150),并分别将其与燃煤灼烧飞灰混合制成相应的脱汞吸附剂。在吸附剂管道喷射脱汞实验装置上,研究了生物质种类、吸附温度... 采用高温携带流反应装置在1050℃和1150℃条件下制备了稻壳再燃焦(RH1050和RH1150)和小麦秸秆再燃焦(WS1050和WS1150),并分别将其与燃煤灼烧飞灰混合制成相应的脱汞吸附剂。在吸附剂管道喷射脱汞实验装置上,研究了生物质种类、吸附温度、初始汞浓度和烟气组分(SO_2、NO和HCl)对生物质再燃焦管道喷射脱汞性能的影响,并结合生物质及其再燃焦的理化特性分析,探讨了单质汞(Hg^0)脱除机理。结果表明:4种生物质再燃焦平均脱汞效率相差不大,约为30%,稻壳再燃焦的脱汞效率略高于小麦秸秆焦。随着吸附温度的升高,RH1050脱汞效率持续增加,RH1150脱汞效率则呈现波动变化趋势。随着初始汞浓度的升高,稻壳再燃焦的平均脱汞效率均呈现先增大后减小的趋势,初始汞浓度为25μg/m^3时RH1050和RH1150的平均脱汞效率最大,分别为35.6%和37.1%。SO_2对生物质再燃焦管道喷射脱汞具有一定的抑制作用,NO具有一定促进作用,而HCl的促进作用更为显著,且当HCl浓度大于50μL/L时,生物质再燃焦的平均脱汞效率均在90%以上。 展开更多
关键词 生物质再燃 生物质 管道喷射 脱汞 烟气组分
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生物质再燃异相还原NO的分子模拟 被引量:4
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作者 李颖 牛胜利 +2 位作者 路春美 王家兴 彭建升 《燃料化学学报》 EI CAS CSCD 北大核心 2020年第6期689-697,I0004,共10页
基于密度泛函理论和过渡态理论,在分子水平上对焦炭异相还原NO以及碱金属钠的作用机理进行探究。结合单点能的零点能校正以及过渡态的虚频验证,发现钠能够有效促进焦炭对于第一个NO分子的吸附。尽管钠不能改变反应步骤,但可将焦炭异相还... 基于密度泛函理论和过渡态理论,在分子水平上对焦炭异相还原NO以及碱金属钠的作用机理进行探究。结合单点能的零点能校正以及过渡态的虚频验证,发现钠能够有效促进焦炭对于第一个NO分子的吸附。尽管钠不能改变反应步骤,但可将焦炭异相还原NO决速步的活化能由121.04 kJ/mol降至100.62 kJ/mol;钠的存在使焦炭异相还原NO的指前因子增大且反应速率加快,增加了焦炭边缘的活性位点,强化了焦炭对于NO的异相还原性能。 展开更多
关键词 生物质再燃 异相还原 分子模拟 动力学计算
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生物质气化再燃特性实验研究 被引量:13
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作者 段佳 罗永浩 +3 位作者 晏乃强 陈祎 陆方 王清成 《燃料化学学报》 EI CAS CSCD 北大核心 2007年第2期245-248,共4页
A experimental study of characteristics of NO reduction by a simulating production gas of biomass gasification was performed in a ceramic flow reactor heated by an electric furnace.The gas was composed of CO,CO2,CH4,H... A experimental study of characteristics of NO reduction by a simulating production gas of biomass gasification was performed in a ceramic flow reactor heated by an electric furnace.The gas was composed of CO,CO2,CH4,H2 and N2,and the temperature used in the experiments ranged from 1 000 ℃ to 1 400 ℃.The influence of the inlet concentration of oxygen(0%~5%),the local equivalence ratio,φ(0.5~2.28),and the reactor temperatures was studied to analyse the characteristics of biomass gasification-reburning.The results indicate that more consumption of reducting agent is needed to increase the NO reduction efficiency in pyrolysis condition.The suitable values of the local equivalence ratio,φ,could make the NO reduction efficiency in oxidation condition higher than that in pyrolysis condition.The local equivalence ratio is an important parameter for NO reduction,and higher NO reduction efficiency can be obtained when φ varies between 0.8 and 1.1.The reduction of NO is favored at high temperatures. 展开更多
关键词 生物质气化再燃 NO还原 当量比 温度
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生物质气再燃特性试验研究 被引量:2
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作者 段佳 罗永浩 +1 位作者 陈祎 陆方 《华电技术》 CAS 2006年第12期100-103,共4页
在天然气等气体燃料再燃研究的基础上,开展了生物质气再燃的研究.采用配制混合气的方法对生物质气化气还原NO的特性进行了试验研究.模拟的生物质气化气由CO,CO2,CH4,H2,N2构成.试验在电加热的刚玉管流反应器中进行,试验温度为1 000℃~1... 在天然气等气体燃料再燃研究的基础上,开展了生物质气再燃的研究.采用配制混合气的方法对生物质气化气还原NO的特性进行了试验研究.模拟的生物质气化气由CO,CO2,CH4,H2,N2构成.试验在电加热的刚玉管流反应器中进行,试验温度为1 000℃~1 400℃.研究了反应器入口氧气质量分数(0~5 %)、当地当量比φ(0.5~2.28)以及反应器温度等因素对还原NO的影响,并分析了生物质气化再燃的特性.得出结论:当量比值是影响NO还原率的重要因素,φ=0.8~1.1是NO还原率较高区域;提高温度有利于提高NO还原率. 展开更多
关键词 生物质气化再燃 NO还原 当量比 温度
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生物质气再燃喷口摆角改变耦合燃煤锅炉燃烧特性数值模拟 被引量:5
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作者 张小桃 张卫东 +3 位作者 张程俞 慕昊良 刘昊明 王爱军 《能源研究与管理》 2021年第1期50-56,62,共8页
为了研究再燃喷口竖直摆动角度对煤粉耦合生物质气再燃锅炉燃烧特性的影响,基于Fluent模拟软件搭建生物质气再燃锅炉模型,对某电厂600 MW燃煤锅炉耦合2台20 t/h秸秆气化炉再燃系统进行再燃喷口摆动角度分别为0°、±15°、&... 为了研究再燃喷口竖直摆动角度对煤粉耦合生物质气再燃锅炉燃烧特性的影响,基于Fluent模拟软件搭建生物质气再燃锅炉模型,对某电厂600 MW燃煤锅炉耦合2台20 t/h秸秆气化炉再燃系统进行再燃喷口摆动角度分别为0°、±15°、±25°等5种工况燃烧过程进行数值模拟,分析燃烧区、折焰角及炉膛出口处烟气速度场及温度场分布特征。结果表明:生物质气再燃工况下炉内燃烧区温度变化趋势大致相同;改变再燃风喷口竖直摆动角度对炉内燃烧稳定性会造成影响;当再燃风喷口向下摆动角度过大(工况1)时,再燃风气流会扰动主燃区烟气气流,影响主燃区煤粉的燃烧;随着再燃喷口摆角向上倾斜,炉膛出口烟气温度偏差和温度分布不均匀系数M逐渐增大,再燃喷口摆角为+25°(工况4)时的M值最大,可达5.80%。在不影响炉内主燃区燃烧的同时,再燃喷口摆角为-15°时,炉膛出口烟气温度偏差最小。再燃喷口摆角向下倾斜一定角度,有利于减小炉膛出口热偏差。 展开更多
关键词 生物质再燃 摆动角度 数值模拟 热偏差
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Biomass gasification and Polish coal-fired boilers for process of reburning in small boilers 被引量:5
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作者 Hrycko Piotr Lasek Janusz Matuszek Katarzyna 《Journal of Central South University》 SCIE EI CAS 2013年第6期1623-1630,共8页
Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out us... Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out using an integrated system consisting of the boiler and a fixed-bed 60 kW (GazEla) gasification reactor.The process gas was continuously introduced above the coal burner of the boiler.The process parameters of the boiler and the gasifier were also measured and compared with the other units.Characteristic NOx emissions from automatic and manually operated boilers were also presented. 展开更多
关键词 NOx rebuming coal combustion biomass gasification
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Challenges on the Quality of Biomass Derived Products for Bringing Them into the Fuels Market
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作者 Magdalena Ramirez Vicente Sanchez 《Journal of Energy and Power Engineering》 2012年第3期321-328,共8页
US EPA recently issued the final definition for a renewable fuel establishes rule for the revised Renewable Fuel Standard RFS the compliance for each part of its name: (i) to II (Renewable Fuel Standard). The mai... US EPA recently issued the final definition for a renewable fuel establishes rule for the revised Renewable Fuel Standard RFS the compliance for each part of its name: (i) to II (Renewable Fuel Standard). The main be a fuel and (ii) to be produced from renewable biomass. This paper addresses the challenges faced by biomass derived fuels on meeting the specifications of those fuels (gasoline, diesel and heating oil). Biomass-derived products contain oxygenates, some of which might enhance certain fuel specifications, but some others may have deteriorating effects. On directly derived from biomass pyrolysis have been demonstrated to the basis of available data published in the literature, the fuels be far from the concept of "substantially similar" transportation fuels. Upgrading is required to convert pyrolysis products into fuels that meet specifications. The economical viability of upgrading still faces confirmation, and imposes several technical challenges for truly attractive cost-effective approaches. 展开更多
关键词 Biomass-derived fuels ASTM specifications QUALITY UPGRADING RFS II.
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Evaluation of solar aided biomass power generation systems with parabolic trough field 被引量:15
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作者 HOU HongJuan YANG YongPing +3 位作者 HU Eric SONG JiFeng DONG ChangQing MAO Jian 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第6期1455-1461,共7页
Solar and biomass are both renewable energy resources.Using biomass as fuel is becoming more and more attractive after governments increase the tariff for the electricity from the renewable sources.However the costs o... Solar and biomass are both renewable energy resources.Using biomass as fuel is becoming more and more attractive after governments increase the tariff for the electricity from the renewable sources.However the costs of power from a biomass power generation plant depend greatly on the availability and quality of the biomass resource.The commercialization of solar alone thermal power generation is hindered by its high initial investment and low thermal efficiency.In this paper,a concept of integrating solar into a biomass power generation system is put forward.In the system the oil heated by a parabolic trough solar field is used to replace the extraction steam to preheat the feed water(entering a biomass boiler) and the previous extraction steam thus saved can continue to do work in the lower stages of turbine.The performance of the hybrid system with different replacements is analyzed and compared through two typical solar aided biomass generating units.The results show that the integration not only reduces the consumption of biomass fuel(at the same generation capacity) but is also proved to be an efficient way to convert solar thermal energy into power.The results also show that with the same solar aperture area,the higher the grade of the replaced extraction steam,the better the thermal performance and economy. 展开更多
关键词 solar thermal power biomass power aided
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