在新型电力系统构建过程中,电力客户用电状态识别与评估将成为其参与需求响应、虚拟电厂等新兴业务的重要基础。以保障重要电力客户安全用电为出发点,挖掘应用电力大数据,提出了一种基于层次分析法(analytic hierarchy process,AHP)-优...在新型电力系统构建过程中,电力客户用电状态识别与评估将成为其参与需求响应、虚拟电厂等新兴业务的重要基础。以保障重要电力客户安全用电为出发点,挖掘应用电力大数据,提出了一种基于层次分析法(analytic hierarchy process,AHP)-优劣解距离法(technique for order preference by similarity to an ideal solution,TOPSIS)的重要电力客户用电状态评估方法。首先搭建了基于Hadoop架构的用电大数据分析平台,为大数据分析提供高性能平台支撑。然后从电压、负荷和综合三类维度构建了9项评估指标,用以描述重要电力客户的用电状态。最后采用AHP-TOPSIS算法分别对电压类、负荷类、综合类指标进行分项评估分析,得出了三类指标各自的用电状态评估值,再通过变权重加权求和的方式确定重要电力客户的用电状态评分。经过算例分析和现场验证,证明了模型和算法的合理性、可行性,该方法有助于促进客户故障事后抢修向事前预警转变,具有保障安全用电、支撑精准巡视、服务主动抢修的多重功效。展开更多
The electrochemical and corrosion?wear behaviors of TC4 alloy in artificial seawater were studied. And the influences of electrochemical state on passive behavior, failure mechanism of passive film and corrosion?wear ...The electrochemical and corrosion?wear behaviors of TC4 alloy in artificial seawater were studied. And the influences of electrochemical state on passive behavior, failure mechanism of passive film and corrosion?wear synergy were emphatically analyzed. The corrosion?wear analysis of the alloy was fulfilled by methods of mass loss, electrochemical testing and scanning electron microscope (SEM). It can be observed that the cathodic shift of open circuit potential and three order of magnitude increase of current density can be obtained during corrosion?wear process. Total corrosion?wear loss increases with increasing applied potential, confirming the synergy between wear and corrosion. High polarisation potential results in low coefficient of friction and high corrosion rate. The relative contribution of pure mechanical wear to total material loss deceases obviously with the increase of potential from open circuit potential to 0.9 V during corrosion?wear. Contributions of wear-induced-corrosion and corrosion-induced-wear are significant especially at higher potentials.展开更多
Efficient numerical solver for the SchrSdinger equation is very important in physics and chemistry. The finite element discrete variable representation (FE-DVR) was first proposed by Rescigno and Mc-Curdy [Phys. Rev...Efficient numerical solver for the SchrSdinger equation is very important in physics and chemistry. The finite element discrete variable representation (FE-DVR) was first proposed by Rescigno and Mc-Curdy [Phys. Rev. A 62, 032706 (2000)] for solving quantum-mechanical scattering problems. In this work, an FE-DVR method in a mapped coordinate was proposed to improve the efficiency of the original FE-DVR method. For numerical demonstration, the proposed approach is applied for solving the electronic eigenfunctions and eigenvalues of the hydrogen atom and vibrational states of the electronic state 3E+ of the Cs2 molecule which has long-range interaction potential. The numerical results indicate that the numerical efficiency of the original FE-DVR has been improved much using our proposed mapped coordinate scheme.展开更多
The thesis researches the safety infonnation and control system (SICS) design principle and introduces engineering application in CPR1000 nuclear power station in China. The SICS provides sufficient control and moni...The thesis researches the safety infonnation and control system (SICS) design principle and introduces engineering application in CPR1000 nuclear power station in China. The SICS provides sufficient control and monitoring means to bring and maintain the plant in a safe state as a backup of main computerized control mean (MCM), in any plant conditions that are probable during a planed or unplanned unavailability of the MCM. The successful engineering applications of SICS in different digital I&C system platform are introduced in the paper. The thesis gives the research conclusion for new general SICS of digital I&C system.展开更多
This article describes comparison of the anchoring effect on electronic properties of the helicene-like bibenzothiophene between o-carborane and 5,6-dicarba-nido-decaborane. The o-carborane and nido-decaborane-fused b...This article describes comparison of the anchoring effect on electronic properties of the helicene-like bibenzothiophene between o-carborane and 5,6-dicarba-nido-decaborane. The o-carborane and nido-decaborane-fused bibenzothiophenes were simultaneously obtained in the same reaction and successfully isolated. Initially, the X-ray single crystal analysis revealed that the helicene-like distorted structure was realized in the nido-decaborane-fused bibenzothiophene. From optical measurements in the solution state, distinct different characteristics depending on the type of anchors were observed. It was summarized that the absorption and luminescent properties originated from weak π-conjugation at the bibenzothiophene moiety in the o-carboranefused compound were obtained, whereas robust π-conjugation and significant emission from the intramolecular charge transfer state were detected from the nido-decaborane-fused compound. These data can be explained by the theoretical results that π-conjugation was restrictedly developed within the bibenzothiophene moiety in frontier orbitals of the o-carborane-fused compound. In contrast, π-conjugation can be constructed even through the distorted bibenzothiophene because of the nido-decaborane unit. Moreover, the intramolecular charge transfer state should be realized because of electronic interaction involving the nido-decaborane unit in the excited state. Furthermore, it was demonstrated that the nido-decaborane-fused compound possessed solid-state emission and mechanochromic luminescent properties. The π-conjugation on the distorted structure supported by the nido-decaborane anchor should play a significant role in suppressing aggregation-caused quenching followed by presenting solid-state emission with stimuli responsiveness.展开更多
By using scanning tunneling microscopy(STM)/spectroscopy(STS), we systematically characterize the electronic structure of lightly doped 1 T-TiSe_2, and demonstrate the existence of the electronic inhomogeneity and the...By using scanning tunneling microscopy(STM)/spectroscopy(STS), we systematically characterize the electronic structure of lightly doped 1 T-TiSe_2, and demonstrate the existence of the electronic inhomogeneity and the pseudogap state. It is found that the intercalation induced lattice distortion impacts the local band structure and reduce the size of the charge density wave(CDW) gap with the persisted 2 × 2 spatial modulation. On the other hand, the delocalized doping electrons promote the formation of pseudogap. Domination by either of the two effects results in the separation of two characteristic regions in real space, exhibiting rather different electronic structures. Further doping electrons to the surface confirms that the pseudogap may be the precursor for the superconducting gap. This study suggests that the competition of local lattice distortion and the delocalized doping effect contribute to the complicated relationship between charge density wave and superconductivity for intercalated 1 T-TiSe_2.展开更多
Using time-resolved techniques of 337 and 248 nm laser flash photolysis, the photo physical and photochemical processes of riboflavin (RF, vitamin B2) were studied in detail in aqueous solution. The excited triplet st...Using time-resolved techniques of 337 and 248 nm laser flash photolysis, the photo physical and photochemical processes of riboflavin (RF, vitamin B2) were studied in detail in aqueous solution. The excited triplet state of riboflavin (3RF*) was produced with 337 nm laser, while under 248 nm irradiation, both3RF* and hydrated electron (eaq) formed from photoionization could be detected. Photobiological implications have been inferred on the basis of reactivity of3RF* including energy transfer, electron transfer and hydrogen abstraction. The RF·+ was generated by oxidation of SO4 ·-radical with the aim of confirming the results of photolysis.展开更多
OBJECTIVE:To investigate the effect of didrovaltrate on L-type calcium current(I Ca-L) in rabbit ventricular myocytes.METHODS:We used the whole cell patch clamp recording technique.RESULTS:Didrovaltrate at concentrati...OBJECTIVE:To investigate the effect of didrovaltrate on L-type calcium current(I Ca-L) in rabbit ventricular myocytes.METHODS:We used the whole cell patch clamp recording technique.RESULTS:Didrovaltrate at concentrations of 30 μg/L and 100 μg/L significantly decreased peak I Ca-L(I Ca-Lmax) from(6.01±0.48) pA/pF to(3.45±0.27) pA/pF and(2.16 ± 0.19) pA/pF(42.6% and 64.1%,n=8,P< 0.01),respectively.Didrovaltrate shifted upwards the current-voltage curves of I Ca-L without changing their active,peak and reverse potentials.Didrovaltrate affected the steady-state inactivation of I Ca-L.The half activation potential(V 1/2) was significantly shifted from(-26 ± 2) to(-36 ± 3) mV(n=6,P<0.05),with a significant change in the slope factor(k)(from 8.8 ± 0.8 to 11.1 ± 0.9,n=6,P<0.05).Didrovaltrate did not affect the activation curve.CONCLUSION:Didrovaltrate blocks I Ca-L in a concentration-dependent manner and probably inhibits I Ca-L in its inactive state,which may contribute to its cardiovascular effect.展开更多
文摘在新型电力系统构建过程中,电力客户用电状态识别与评估将成为其参与需求响应、虚拟电厂等新兴业务的重要基础。以保障重要电力客户安全用电为出发点,挖掘应用电力大数据,提出了一种基于层次分析法(analytic hierarchy process,AHP)-优劣解距离法(technique for order preference by similarity to an ideal solution,TOPSIS)的重要电力客户用电状态评估方法。首先搭建了基于Hadoop架构的用电大数据分析平台,为大数据分析提供高性能平台支撑。然后从电压、负荷和综合三类维度构建了9项评估指标,用以描述重要电力客户的用电状态。最后采用AHP-TOPSIS算法分别对电压类、负荷类、综合类指标进行分项评估分析,得出了三类指标各自的用电状态评估值,再通过变权重加权求和的方式确定重要电力客户的用电状态评分。经过算例分析和现场验证,证明了模型和算法的合理性、可行性,该方法有助于促进客户故障事后抢修向事前预警转变,具有保障安全用电、支撑精准巡视、服务主动抢修的多重功效。
基金Project(LSL-1310)supported by the Open Project of State Key Laboratory of Solid Lubrication,ChinaProjects(2014QN013,2015GJB004)supported by the Research Foundation of Henan University of Science and Technology,China
文摘The electrochemical and corrosion?wear behaviors of TC4 alloy in artificial seawater were studied. And the influences of electrochemical state on passive behavior, failure mechanism of passive film and corrosion?wear synergy were emphatically analyzed. The corrosion?wear analysis of the alloy was fulfilled by methods of mass loss, electrochemical testing and scanning electron microscope (SEM). It can be observed that the cathodic shift of open circuit potential and three order of magnitude increase of current density can be obtained during corrosion?wear process. Total corrosion?wear loss increases with increasing applied potential, confirming the synergy between wear and corrosion. High polarisation potential results in low coefficient of friction and high corrosion rate. The relative contribution of pure mechanical wear to total material loss deceases obviously with the increase of potential from open circuit potential to 0.9 V during corrosion?wear. Contributions of wear-induced-corrosion and corrosion-induced-wear are significant especially at higher potentials.
文摘Efficient numerical solver for the SchrSdinger equation is very important in physics and chemistry. The finite element discrete variable representation (FE-DVR) was first proposed by Rescigno and Mc-Curdy [Phys. Rev. A 62, 032706 (2000)] for solving quantum-mechanical scattering problems. In this work, an FE-DVR method in a mapped coordinate was proposed to improve the efficiency of the original FE-DVR method. For numerical demonstration, the proposed approach is applied for solving the electronic eigenfunctions and eigenvalues of the hydrogen atom and vibrational states of the electronic state 3E+ of the Cs2 molecule which has long-range interaction potential. The numerical results indicate that the numerical efficiency of the original FE-DVR has been improved much using our proposed mapped coordinate scheme.
文摘The thesis researches the safety infonnation and control system (SICS) design principle and introduces engineering application in CPR1000 nuclear power station in China. The SICS provides sufficient control and monitoring means to bring and maintain the plant in a safe state as a backup of main computerized control mean (MCM), in any plant conditions that are probable during a planed or unplanned unavailability of the MCM. The successful engineering applications of SICS in different digital I&C system platform are introduced in the paper. The thesis gives the research conclusion for new general SICS of digital I&C system.
基金supported by Konica Minolta Science and Technology Foundation (for K.T.)a Grant-in-Aid for Scientific Research on Innovative Areas "New Polymeric Materials Based on Element-Blocks (No.2401)" (JP24102013)
文摘This article describes comparison of the anchoring effect on electronic properties of the helicene-like bibenzothiophene between o-carborane and 5,6-dicarba-nido-decaborane. The o-carborane and nido-decaborane-fused bibenzothiophenes were simultaneously obtained in the same reaction and successfully isolated. Initially, the X-ray single crystal analysis revealed that the helicene-like distorted structure was realized in the nido-decaborane-fused bibenzothiophene. From optical measurements in the solution state, distinct different characteristics depending on the type of anchors were observed. It was summarized that the absorption and luminescent properties originated from weak π-conjugation at the bibenzothiophene moiety in the o-carboranefused compound were obtained, whereas robust π-conjugation and significant emission from the intramolecular charge transfer state were detected from the nido-decaborane-fused compound. These data can be explained by the theoretical results that π-conjugation was restrictedly developed within the bibenzothiophene moiety in frontier orbitals of the o-carborane-fused compound. In contrast, π-conjugation can be constructed even through the distorted bibenzothiophene because of the nido-decaborane unit. Moreover, the intramolecular charge transfer state should be realized because of electronic interaction involving the nido-decaborane unit in the excited state. Furthermore, it was demonstrated that the nido-decaborane-fused compound possessed solid-state emission and mechanochromic luminescent properties. The π-conjugation on the distorted structure supported by the nido-decaborane anchor should play a significant role in suppressing aggregation-caused quenching followed by presenting solid-state emission with stimuli responsiveness.
基金supported by the Ministry of Science and Technology of China(2014CB921103,2013CB922103,2016YFA0300400,2015CB921202)the National Natural Science Foundation of China(11774149,11374140,11190023,11774152,51372112,11574133)+1 种基金NSF Jiangsu Province(BK20150012)the Open Research Fund Program of the State Key Laboratory of Low-Dimensional Quantum Physics
文摘By using scanning tunneling microscopy(STM)/spectroscopy(STS), we systematically characterize the electronic structure of lightly doped 1 T-TiSe_2, and demonstrate the existence of the electronic inhomogeneity and the pseudogap state. It is found that the intercalation induced lattice distortion impacts the local band structure and reduce the size of the charge density wave(CDW) gap with the persisted 2 × 2 spatial modulation. On the other hand, the delocalized doping electrons promote the formation of pseudogap. Domination by either of the two effects results in the separation of two characteristic regions in real space, exhibiting rather different electronic structures. Further doping electrons to the surface confirms that the pseudogap may be the precursor for the superconducting gap. This study suggests that the competition of local lattice distortion and the delocalized doping effect contribute to the complicated relationship between charge density wave and superconductivity for intercalated 1 T-TiSe_2.
基金the National Natural Science Foundation of China (Grant No. 39830090).
文摘Using time-resolved techniques of 337 and 248 nm laser flash photolysis, the photo physical and photochemical processes of riboflavin (RF, vitamin B2) were studied in detail in aqueous solution. The excited triplet state of riboflavin (3RF*) was produced with 337 nm laser, while under 248 nm irradiation, both3RF* and hydrated electron (eaq) formed from photoionization could be detected. Photobiological implications have been inferred on the basis of reactivity of3RF* including energy transfer, electron transfer and hydrogen abstraction. The RF·+ was generated by oxidation of SO4 ·-radical with the aim of confirming the results of photolysis.
基金Supported by the Chinese National Science Foundation (No.81170090)the Science Foundation for Distinguished Young Scholars of Fujian Province(No.2009D015)+1 种基金the Science Foundation for Distinguished Young Scholars of Xiamen(No.3502Z20116009)the Science Foundation of Science and Technology of the Bureau of Xiamen(No. 3502Z20094006)
文摘OBJECTIVE:To investigate the effect of didrovaltrate on L-type calcium current(I Ca-L) in rabbit ventricular myocytes.METHODS:We used the whole cell patch clamp recording technique.RESULTS:Didrovaltrate at concentrations of 30 μg/L and 100 μg/L significantly decreased peak I Ca-L(I Ca-Lmax) from(6.01±0.48) pA/pF to(3.45±0.27) pA/pF and(2.16 ± 0.19) pA/pF(42.6% and 64.1%,n=8,P< 0.01),respectively.Didrovaltrate shifted upwards the current-voltage curves of I Ca-L without changing their active,peak and reverse potentials.Didrovaltrate affected the steady-state inactivation of I Ca-L.The half activation potential(V 1/2) was significantly shifted from(-26 ± 2) to(-36 ± 3) mV(n=6,P<0.05),with a significant change in the slope factor(k)(from 8.8 ± 0.8 to 11.1 ± 0.9,n=6,P<0.05).Didrovaltrate did not affect the activation curve.CONCLUSION:Didrovaltrate blocks I Ca-L in a concentration-dependent manner and probably inhibits I Ca-L in its inactive state,which may contribute to its cardiovascular effect.