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对甲基茴香醚和茴香醛的气相色谱法分离分析 被引量:1
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作者 刘敬兰 陈连文 张宏坤 《分析试验室》 CAS CSCD 北大核心 2004年第2期66-67,共2页
采用OV 101毛细柱对由对甲基茴香醚间接电氧化合成茴香醛的产物进行了分离分析,内标法定量,苯甲酸乙酯为内标物,反应物对甲基茴香醚和产物茴香醛均在0.5~4.0g/L范围内呈良好的线性关系,检测限分别为8.1ng和12.4ng。
关键词 甲基茴香醚 茴香 毛细管气相色谱法 分离 间接电氧化合成
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载溴树脂作为3-甲基茴香醚的溴化剂 被引量:1
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作者 阳年发 梁文杰 +1 位作者 杨利文 林原斌 《化学试剂》 CAS CSCD 1997年第6期361-362,371,共3页
制备了一种新型的溴化试剂——载溴阴离子交换树脂。在间甲基茴香醚的溴化中,这种溴化剂有良好的选择性及稳定性,产物4-溴-3-甲基茴香醚的产率高达89.2%。
关键词 载溴树脂 甲基茴香醚 溴化剂
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5-甲基-2-硝基茴香醚的合成研究
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作者 卢爱党 李银辉 +1 位作者 韩健 陈建新 《河北工业大学学报》 CAS 2015年第5期79-82,共4页
以5-甲基-2-硝基苯酚为原料,在碳酸钾的丙酮溶液中与碘甲烷作用,制备5-甲基-2-硝基茴香醚.考察了不同反应温度、反应时间、投料比、搅拌方式对反应物转化率的影响,确定在40~45℃、机械搅拌、(酚)∶(K2CO3)∶(CH3I)=1∶3∶1.5的反... 以5-甲基-2-硝基苯酚为原料,在碳酸钾的丙酮溶液中与碘甲烷作用,制备5-甲基-2-硝基茴香醚.考察了不同反应温度、反应时间、投料比、搅拌方式对反应物转化率的影响,确定在40~45℃、机械搅拌、(酚)∶(K2CO3)∶(CH3I)=1∶3∶1.5的反应条件下,反应5 h,反应物转化率可达99%.所得产物化学结构经1H NMR、13C NMR表征确认.通过反应规模的放大验证该方法的适用性. 展开更多
关键词 5-甲基-2-硝基苯酚 5-甲基-2-硝基茴香 合成 条件优化 化反应
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Pomegranate (Punica granatum L.) Peel Extract as a Source of Natural Antioxidant
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作者 A.Padmaja N.B.L.Prasad 《Journal of Food Science and Engineering》 2011年第3期171-182,共12页
An increase in the demand for natural additives has shifted the attention from synthetic to natural antioxidants. Antioxidative components from pomegranate peel were extracted by using different solvents like methanol... An increase in the demand for natural additives has shifted the attention from synthetic to natural antioxidants. Antioxidative components from pomegranate peel were extracted by using different solvents like methanol, ethanol, acetone, chloroform and ethyl acetate. All the extracts were tested for Total phenolic content (TPC) and the methanol which proved to be best in extracting the phenolic compounds was used to assess the antioxidant property by using different methods like Diphenyl piridyl picryl hydrazyl (DPPH), Relative reducing power (RRP), Beta carotene bleaching and Ferric thiocyanate (FTC). The antioxidant activity (AA) of pomegranate peel extract (PPE) was compared with Butylated hydroxyl toluene (BHT) and Butylated hydroxyl anisole (BHA). The methanolic extract was examined by Liquid Chromatography and Mass Spectroscopy (LCMS) and the spectra showed the presence of different phenolic compounds. The extracts were tested for their efficiency in preventing rancidity of Refined Bleached Deodorized Soybean oil (RBDSBO) in comparison with BHT and control at 200 ppm concentration. The PPE proved to be best in preventing rancidity. Owing to the present results, the studies can further be extended to exploit the PPE for application into different food products. 展开更多
关键词 Pomegranate peel phenolics extraction antioxidant activity soybean oil
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