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四苯基卟啉和金属卟啉的制备 被引量:19
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作者 杨彪 刘云 肖德宝 《精细化工》 EI CAS CSCD 北大核心 1998年第1期53-55,共3页
采用二甲苯为溶剂,对硝基苯甲酸催化,苯甲醛和吡咯反应合成四苯基卟啉(TPP),产率可达554%;另外,用DMF为溶剂,TPP与醋酸锌反应生成金属卟啉锌(TPPZn),产率可达976%。
关键词 金属化 合成 甲苯基卟啉
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ISOSBESTIC DUAL WAVELENGTH SPEOTROPHOTOMETRIC SIMULTANEOUS DETERMINATION OF ZINC AND OADMIUM USING meso-TETRAKIS[4-(TRIMETHYLAMMONIUM) PHENYL] PORPHINE
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作者 肖新亮 张淑芬 +2 位作者 刘瑞贤 沈含熙 杨俊佼 《Transactions of Tianjin University》 EI CAS 1995年第2期118+115-118,共5页
Iin this paper an isosbestic dual--wavelength spectrophotometric method for the simultaneous determination of zinc and cadmium using meso--tetrakis [4-(trimethylammonium) phenyl] porphine has been developed. The inter... Iin this paper an isosbestic dual--wavelength spectrophotometric method for the simultaneous determination of zinc and cadmium using meso--tetrakis [4-(trimethylammonium) phenyl] porphine has been developed. The interference from excess of reagent was masked by adding lead ions solution.The molar absorptivities (Ae) for zinc and cadmium were 6. 54 × 105 and 4. 27 × 105 L. mol-1. cm-1,respectively. The method could be used to determine zinc and cadmium in synthetic mixtures, and the satisfied results were obtained. 展开更多
关键词 dual-wavelength spectrophotometry zinc and cadmium determination meso--tetrakis [4(trimethylammonium) phenyl] porphine
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