The mathematic model of combined converter with two different flow modes of gas-cooled reactor was established. The effects of gas flow mode in gas-cooled reactor on combined converter was investigated with the yield ...The mathematic model of combined converter with two different flow modes of gas-cooled reactor was established. The effects of gas flow mode in gas-cooled reactor on combined converter was investigated with the yield of methanol was 1 400 kt/a. The results show that if the flow mode of the cooling pipe gas and the catalytic bed gas change from countercurrent to concurrent, the catalytic bed temperature distribution does not fit the most optimum temperature curve of reversible exothermic reaction and the heat duty of heat changer in whole process increased seriously, which means that there is much more equipment investment and more operating cost. The gas flow mode of gas-cooled reactor affects the methanol yield slightly. There- fore, the countercurrent gas flow mode of gas-cooled reactor is more lucrative in the combined converter process.展开更多
In order to study the theoretical cycle characteristic of [mmim]DMP （1-methyl-3-methylimidazolium dimethyl- phosphate）/methanol absorption refrigeration, the modified UNIFAC group contribution model and the Wilson m...In order to study the theoretical cycle characteristic of [mmim]DMP （1-methyl-3-methylimidazolium dimethyl- phosphate）/methanol absorption refrigeration, the modified UNIFAC group contribution model and the Wilson model are established through correlating the experimental vapor pressure data of [mmim]DMP/methanol at T= 280~370 K and methanol mole fraction x= 0.529-0.965. Thermodynamic performances of absorption refrigera- tion utilizing [mmim]DMP/methanol, LiBr/H20 and H20/NH3 are investigated and compared with each other under the same operating conditions. From the results, some conclusions are obtained as follows： 1） the circula- tion ratio of the [mmim]DMP/methanol absorption refrigeration is higher than that of the LiBr/H2O absorption refrigeration, but still can be acceptable and tolerable. 2） The COP of the [mmim]DMP/methanol absorption refrigeration is smaller than that of the LiBr/H2O absorption refrigeration, while it is higher than that of the H2O/NH3 absorption refrigeration under most operating conditions. 3） The [mmim]DMP/methanol absorption refrigeration are still available with high COP when the heat source temperature is too high to drive LiBr/H2O absorption refrigeration.展开更多
文摘The mathematic model of combined converter with two different flow modes of gas-cooled reactor was established. The effects of gas flow mode in gas-cooled reactor on combined converter was investigated with the yield of methanol was 1 400 kt/a. The results show that if the flow mode of the cooling pipe gas and the catalytic bed gas change from countercurrent to concurrent, the catalytic bed temperature distribution does not fit the most optimum temperature curve of reversible exothermic reaction and the heat duty of heat changer in whole process increased seriously, which means that there is much more equipment investment and more operating cost. The gas flow mode of gas-cooled reactor affects the methanol yield slightly. There- fore, the countercurrent gas flow mode of gas-cooled reactor is more lucrative in the combined converter process.
基金supported by the National Basic Research Program of China (973 Program) under Grant No.2012CB933200the National Natural Science Fundation of China under Grant No.51276180
文摘In order to study the theoretical cycle characteristic of [mmim]DMP （1-methyl-3-methylimidazolium dimethyl- phosphate）/methanol absorption refrigeration, the modified UNIFAC group contribution model and the Wilson model are established through correlating the experimental vapor pressure data of [mmim]DMP/methanol at T= 280~370 K and methanol mole fraction x= 0.529-0.965. Thermodynamic performances of absorption refrigera- tion utilizing [mmim]DMP/methanol, LiBr/H20 and H20/NH3 are investigated and compared with each other under the same operating conditions. From the results, some conclusions are obtained as follows： 1） the circula- tion ratio of the [mmim]DMP/methanol absorption refrigeration is higher than that of the LiBr/H2O absorption refrigeration, but still can be acceptable and tolerable. 2） The COP of the [mmim]DMP/methanol absorption refrigeration is smaller than that of the LiBr/H2O absorption refrigeration, while it is higher than that of the H2O/NH3 absorption refrigeration under most operating conditions. 3） The [mmim]DMP/methanol absorption refrigeration are still available with high COP when the heat source temperature is too high to drive LiBr/H2O absorption refrigeration.
