Pjridine has been generally synthesized by aldehydes and ammonia in a turbulent fluidized-bed reactor. In this paper, a novel riser reactor was proposed for pyridine synthesis. Experiment result showed that the yield ...Pjridine has been generally synthesized by aldehydes and ammonia in a turbulent fluidized-bed reactor. In this paper, a novel riser reactor was proposed for pyridine synthesis. Experiment result showed that the yield of pyridine and 3-picoline decreased, but the selectivity of pyridine over 3-picoline increased compared to turbulent fluidized-bed reactor. Based on experimental data, a modified kinetic model was used for the determination of optimal operating condition for riser reactor. The optimal operating condition of riser reactor given by this modified model was as follows： The reaction temperature of 755 K, catalyst to feedstock ratio （CTFR） of 87, residence timeof3.8sandinitialacetaldehydesconcentrationof0.0029mol.L-1 （acetaldehydes to formaldehydes ratio by mole （ATFR） of 0.65 and ammonia to aldehydes ratio by mole （ATAR） of 0.9, water contention of 63wt% （formaldehyde solution））.展开更多
The interaction between CO2 laser and polyformaldehyde(POM)is quite important in the research of laser irradiation effects and mechanisms.At this time,the accuracy of the existing mass-ablation models for POM irradiat...The interaction between CO2 laser and polyformaldehyde(POM)is quite important in the research of laser irradiation effects and mechanisms.At this time,the accuracy of the existing mass-ablation models for POM irradiated by CO2 laser is poor compared with the experimental data.Based on the energy distribution deposited in the POM target,the active area excited by laser is divided into four slices,the ablation slice(the temperature-rising slice,the perturbation slice,and the undisturbed slice),and a slicing response model for the mass ablation of POM induced by pulsed CO2 laser irradiation in vacuum is developed.A formula is deduced to predict the ablated mass areal density from the model and is verified with data from several studies and our own experiments.The results show that our model fits the experimental data quite well before the shielding effect of ablation products becomes notable.The applicability of the model to other materials and the mass ablation in atmosphere are also briefly explored.展开更多
基金Supported by the National Basic Research Program of China(973 Program,2012CB215000)
文摘Pjridine has been generally synthesized by aldehydes and ammonia in a turbulent fluidized-bed reactor. In this paper, a novel riser reactor was proposed for pyridine synthesis. Experiment result showed that the yield of pyridine and 3-picoline decreased, but the selectivity of pyridine over 3-picoline increased compared to turbulent fluidized-bed reactor. Based on experimental data, a modified kinetic model was used for the determination of optimal operating condition for riser reactor. The optimal operating condition of riser reactor given by this modified model was as follows： The reaction temperature of 755 K, catalyst to feedstock ratio （CTFR） of 87, residence timeof3.8sandinitialacetaldehydesconcentrationof0.0029mol.L-1 （acetaldehydes to formaldehydes ratio by mole （ATFR） of 0.65 and ammonia to aldehydes ratio by mole （ATAR） of 0.9, water contention of 63wt% （formaldehyde solution））.
基金supported by the National Natural Science Foundation of China(Grant No.51306203)the Advancing Research Program of NUDT(Grant No.JC14-01-02)
文摘The interaction between CO2 laser and polyformaldehyde(POM)is quite important in the research of laser irradiation effects and mechanisms.At this time,the accuracy of the existing mass-ablation models for POM irradiated by CO2 laser is poor compared with the experimental data.Based on the energy distribution deposited in the POM target,the active area excited by laser is divided into four slices,the ablation slice(the temperature-rising slice,the perturbation slice,and the undisturbed slice),and a slicing response model for the mass ablation of POM induced by pulsed CO2 laser irradiation in vacuum is developed.A formula is deduced to predict the ablated mass areal density from the model and is verified with data from several studies and our own experiments.The results show that our model fits the experimental data quite well before the shielding effect of ablation products becomes notable.The applicability of the model to other materials and the mass ablation in atmosphere are also briefly explored.
