Triboluminescence,also as known as mechanoluminescence,is an attractive optical behavior that means the light emitted from specific organic and inorganic materials when they are subjected to external forces,such as cr...Triboluminescence,also as known as mechanoluminescence,is an attractive optical behavior that means the light emitted from specific organic and inorganic materials when they are subjected to external forces,such as crushing,deformation,cleaving,vibration.Inorganic triboluminescent materials show great potential for applications in sensing,such as stress sensing,damage detection.However,the triboluminescent mechanism of organic materials should be pushed further as well as their application.In this review,we summarized the history of development and possible mechanism of organic triboluminescent materials,and discussed various applications in sensing field.At the same time,inspired by the existing research progress in inorganic triboluminescent materials,we proposed the flourishing development prospects of organic triboluminescent materials in stress sensors,movement monitoring,imaging stress distribution,visualization of crack propagation,structural diagnosis,and other fields.展开更多
Time-resolved photoionization is a powerful experimental approach to unravel the excited state dynamics in isolated polyatomic molecules. Depending on species of the collected signals, different methods can be perform...Time-resolved photoionization is a powerful experimental approach to unravel the excited state dynamics in isolated polyatomic molecules. Depending on species of the collected signals, different methods can be performed: time-resolved ion yield spectroscopy (TR-IYS) and time-resolved photoelectron imaging (TR-PEI). In this review, the essential concepts linking photoionization measurement with electronic structure are presented, together with several important breakthroughs in experimentally distinguishing the oscillating wavepacket motion between different geometries. We illustrate how femtosecond TR-IYS and TR-PEI are employed to visualize the evolution of a coherent vibrational wavepacket on the excited state surface.展开更多
The ultrafast dissociation dynamics of NO2 molecules was investigated by femtosecond laser pump-probe mass spectra and ion images.The results show that the kinetic energy release of NO+ions has two components,0.05 eV ...The ultrafast dissociation dynamics of NO2 molecules was investigated by femtosecond laser pump-probe mass spectra and ion images.The results show that the kinetic energy release of NO+ions has two components,0.05 eV and 0.25 eV,and the possible dissociation channels have been assigned.The channel resolved transient measurement of NO^+provides a method to disentangle the contribution of ultrafast dissociation pathways,and the transient curves of NO^+ions at different kinetic energy release are fitted by a biexponential function.The fast component with a decay time of 0.25 ps is generated from the evolution of Rydberg states.The slow component is generated from two competitive channels,one of the channel is absorbing one 400nm photon to the excited state A^2B2,which has a decay time of 30.0ps,and the other slow channel is absorbing three 400nm photons to valence type Rydberg states which have a decay time less than 7.2ps.The channel and time resolved experiment present the potential of sorting out the complex ultrafast dissociation dynamics of molecules.展开更多
The national energy supplier (Eskom in South Africa) supplies electricity through thousands-of-kilometers of overhead power lines. The current methods of inspection of these overhead power lines are infrequent and e...The national energy supplier (Eskom in South Africa) supplies electricity through thousands-of-kilometers of overhead power lines. The current methods of inspection of these overhead power lines are infrequent and expensive. In this paper, the authors present the development of a prototype monitoring system for power line inspection in South Africa. The developed prototype monitoring system collects data (information) from the overhead power lines, is remotely accessible and fits into a power line robot. The prototype monitoring system makes use ofa PandaBoard (SBC) with GPS receiver and 5 MP camera to collect data. Hardware fatigue is the biggest problem faced on the overhead power lines and is captured by means of the 5 MP camera and is displayed on a website hosted by the PandaBoard via Wi-Fi. The monitoring system has low power consumption, is light weight, compact and easily collects data. The data obtained from the prototype monitoring system was satisfactory and provides an improved solution for monitoring power lines for Eskom in South Africa.展开更多
A colluvial landslide in a debris flow valley is a typical phenomena and is easily influenced by rainfall. The direct destructiveness of this kind of landslide is small, however, if failure occurs the resulting blocki...A colluvial landslide in a debris flow valley is a typical phenomena and is easily influenced by rainfall. The direct destructiveness of this kind of landslide is small, however, if failure occurs the resulting blocking of the channel may lead to a series of magnified secondary hazards. For this reason it is important to investigate the potential response of this type of landslide to rainfall. In the present paper, the Goulingping landslide, one of the colluvial landslides in the Goulingping valley in the middle of the Bailong River catchment in Gansu Province, China, was chosen for the study. Electrical Resistivity Tomography(ERT), Terrestrial Laser Scanning(TLS), together with traditional monitoring methods, were used to monitor changes in water content and the deformation of the landslide caused by rainfall. ERT was used to detect changes in soil water content induced by rainfall. The most significant findings were as follows:(1) the water content in the centralupper part(0~41 m) of the landslide was greaterthan in the central-front part(41~84 m) and(2) there was a relatively high resistivity zone at depth within the sliding zone. The deformation characteristics at the surface of the landslide were monitored by TLS and the results revealed that rainstorms caused three types of deformation and failure:(1) gully erosion at the slope surface;(2) shallow sliding failure;(3) and slope foot erosion. Subsequent monitoring of continuous changes in pore-water pressure, soil pressure and displacement(using traditional methods) indicated that long duration light rainfall(average 2.22 mm/d) caused the entire landslide to enter a state of creeping deformation at the beginning of the rainy season. Shear-induced dilation occurred for the fast sliding(30.09 mm/d) during the critical failure sub-phase(EF). Pore-water pressure in the sliding zone was affected by rainfall. In addition, the sliding L1 parts of the landslide exerted a discontinuous pressure on the L2 part. Through the monitoring and analysis, we conclude that this kind of landslide may have large deformation at the beginning and the late of the rainy season.展开更多
A method using multiple mirror images of point charges is put forward to analyze the polarization of two identical conductor spheres in a uniform electrostatic field.By use of the method,the electric field distributio...A method using multiple mirror images of point charges is put forward to analyze the polarization of two identical conductor spheres in a uniform electrostatic field.By use of the method,the electric field distribution and the interaction force between two spheres can be calculated accurately even for very small gap between two spheres.Our results show that the magnitude of the product of the gap between two spheres and the local electric field in the center of the gap is approximately in the same order and the interaction between two spheres increases very fast as the two spheres are close to each other.We also show that the interaction force between two conductor spheres is almost same with that between two dielectric spheres with high permittivity.展开更多
The deformation of fully pearlitic steels during wire drawing has been investigated for botb longitudinal section and transverse section by back-scattered electron imaging (BSEI), electron back-scattered diffraction...The deformation of fully pearlitic steels during wire drawing has been investigated for botb longitudinal section and transverse section by back-scattered electron imaging (BSEI), electron back-scattered diffraction (EBSD), and transmission electron mi- croscope (TEM). The results show that a large number of deformation bands (DBs) composed of a mixture of kink-like bands and shear-like bands were observed both in the longitudinal section and the traverse section of the drawn wires. The formation of such bands involves two aspects: heterogeneous deformation in the scale of pearlite colonies and instability of fer- rite-cementite interfaces due to stress concentration during wire drawing. The development of suck bands in fully pearlitic steels dominates the formation of metallograpbic texture, reduces the pearlite interlamellar spacing and promotes the development of 〈 110〉 fiber crystalline texture of ferrite matrix during wire drawing.展开更多
基金Project(51703253)supported by the National Natural Science Foundation of ChinaProject(2020GXLH-Z-010)supported by Key Research and Development Program of Shaanxi Province,China+6 种基金Project(2020JQ-168)supported by Shaanxi Science and Technology Fund,ChinaProject(201906010091)supported by Pearl River Nova Program of Guangzhou,ChinaProject(cstc2020jcyj-msxm X0931)supported by Chongqing Science and Technology Fund,ChinaProject(2021A1515010633)supported by Guangdong Basic and Applied Basic Research Foundation,ChinaProject(202003N4060)supported by the Ningbo Natural Science Foundation,ChinaProject(SZKFJJ202001)supported by Henan Key Laboratory of Special Protective Materials,ChinaProject(2020Z073053007)supported by Aerospace Science Foundation of China。
文摘Triboluminescence,also as known as mechanoluminescence,is an attractive optical behavior that means the light emitted from specific organic and inorganic materials when they are subjected to external forces,such as crushing,deformation,cleaving,vibration.Inorganic triboluminescent materials show great potential for applications in sensing,such as stress sensing,damage detection.However,the triboluminescent mechanism of organic materials should be pushed further as well as their application.In this review,we summarized the history of development and possible mechanism of organic triboluminescent materials,and discussed various applications in sensing field.At the same time,inspired by the existing research progress in inorganic triboluminescent materials,we proposed the flourishing development prospects of organic triboluminescent materials in stress sensors,movement monitoring,imaging stress distribution,visualization of crack propagation,structural diagnosis,and other fields.
基金supported by the National Natural Science Foundation of China (No.21327804, No.21773299, No.91121006, No.21573279, No.11574351, No.11774385, No.11674355, No.21503270, and No.21303255)
文摘Time-resolved photoionization is a powerful experimental approach to unravel the excited state dynamics in isolated polyatomic molecules. Depending on species of the collected signals, different methods can be performed: time-resolved ion yield spectroscopy (TR-IYS) and time-resolved photoelectron imaging (TR-PEI). In this review, the essential concepts linking photoionization measurement with electronic structure are presented, together with several important breakthroughs in experimentally distinguishing the oscillating wavepacket motion between different geometries. We illustrate how femtosecond TR-IYS and TR-PEI are employed to visualize the evolution of a coherent vibrational wavepacket on the excited state surface.
基金supported by the National Natural Science Foundation of China(No.11704148,No.11847039,No.11534004)
文摘The ultrafast dissociation dynamics of NO2 molecules was investigated by femtosecond laser pump-probe mass spectra and ion images.The results show that the kinetic energy release of NO+ions has two components,0.05 eV and 0.25 eV,and the possible dissociation channels have been assigned.The channel resolved transient measurement of NO^+provides a method to disentangle the contribution of ultrafast dissociation pathways,and the transient curves of NO^+ions at different kinetic energy release are fitted by a biexponential function.The fast component with a decay time of 0.25 ps is generated from the evolution of Rydberg states.The slow component is generated from two competitive channels,one of the channel is absorbing one 400nm photon to the excited state A^2B2,which has a decay time of 30.0ps,and the other slow channel is absorbing three 400nm photons to valence type Rydberg states which have a decay time less than 7.2ps.The channel and time resolved experiment present the potential of sorting out the complex ultrafast dissociation dynamics of molecules.
文摘The national energy supplier (Eskom in South Africa) supplies electricity through thousands-of-kilometers of overhead power lines. The current methods of inspection of these overhead power lines are infrequent and expensive. In this paper, the authors present the development of a prototype monitoring system for power line inspection in South Africa. The developed prototype monitoring system collects data (information) from the overhead power lines, is remotely accessible and fits into a power line robot. The prototype monitoring system makes use ofa PandaBoard (SBC) with GPS receiver and 5 MP camera to collect data. Hardware fatigue is the biggest problem faced on the overhead power lines and is captured by means of the 5 MP camera and is displayed on a website hosted by the PandaBoard via Wi-Fi. The monitoring system has low power consumption, is light weight, compact and easily collects data. The data obtained from the prototype monitoring system was satisfactory and provides an improved solution for monitoring power lines for Eskom in South Africa.
基金funded by International S&T Cooperation Program of China (ISTCP) (Grant No. 2013DFE23030)the Fundamental Research Funds for the Central Universities (Grant No. lzujbky-2014-273 and lzujbky-2015-133)
文摘A colluvial landslide in a debris flow valley is a typical phenomena and is easily influenced by rainfall. The direct destructiveness of this kind of landslide is small, however, if failure occurs the resulting blocking of the channel may lead to a series of magnified secondary hazards. For this reason it is important to investigate the potential response of this type of landslide to rainfall. In the present paper, the Goulingping landslide, one of the colluvial landslides in the Goulingping valley in the middle of the Bailong River catchment in Gansu Province, China, was chosen for the study. Electrical Resistivity Tomography(ERT), Terrestrial Laser Scanning(TLS), together with traditional monitoring methods, were used to monitor changes in water content and the deformation of the landslide caused by rainfall. ERT was used to detect changes in soil water content induced by rainfall. The most significant findings were as follows:(1) the water content in the centralupper part(0~41 m) of the landslide was greaterthan in the central-front part(41~84 m) and(2) there was a relatively high resistivity zone at depth within the sliding zone. The deformation characteristics at the surface of the landslide were monitored by TLS and the results revealed that rainstorms caused three types of deformation and failure:(1) gully erosion at the slope surface;(2) shallow sliding failure;(3) and slope foot erosion. Subsequent monitoring of continuous changes in pore-water pressure, soil pressure and displacement(using traditional methods) indicated that long duration light rainfall(average 2.22 mm/d) caused the entire landslide to enter a state of creeping deformation at the beginning of the rainy season. Shear-induced dilation occurred for the fast sliding(30.09 mm/d) during the critical failure sub-phase(EF). Pore-water pressure in the sliding zone was affected by rainfall. In addition, the sliding L1 parts of the landslide exerted a discontinuous pressure on the L2 part. Through the monitoring and analysis, we conclude that this kind of landslide may have large deformation at the beginning and the late of the rainy season.
基金Supported by Guizhou Provincial Science and Technology Foundation (Z103167)Youth Foundation of Guizhou University (X092012)+1 种基金the National Basic Research Program of China under Grant No. 2009CB930800National Natural Science Foundation of China under Grant Nos. 10674157 and 10875166
文摘A method using multiple mirror images of point charges is put forward to analyze the polarization of two identical conductor spheres in a uniform electrostatic field.By use of the method,the electric field distribution and the interaction force between two spheres can be calculated accurately even for very small gap between two spheres.Our results show that the magnitude of the product of the gap between two spheres and the local electric field in the center of the gap is approximately in the same order and the interaction between two spheres increases very fast as the two spheres are close to each other.We also show that the interaction force between two conductor spheres is almost same with that between two dielectric spheres with high permittivity.
基金supported by the Fundamental Research Funds for the Central Universities of China(Grant No.XDJK2013C088)Postdoctoral Science Foundation Funded Project of Chongqing(Grant No.XM201329)
文摘The deformation of fully pearlitic steels during wire drawing has been investigated for botb longitudinal section and transverse section by back-scattered electron imaging (BSEI), electron back-scattered diffraction (EBSD), and transmission electron mi- croscope (TEM). The results show that a large number of deformation bands (DBs) composed of a mixture of kink-like bands and shear-like bands were observed both in the longitudinal section and the traverse section of the drawn wires. The formation of such bands involves two aspects: heterogeneous deformation in the scale of pearlite colonies and instability of fer- rite-cementite interfaces due to stress concentration during wire drawing. The development of suck bands in fully pearlitic steels dominates the formation of metallograpbic texture, reduces the pearlite interlamellar spacing and promotes the development of 〈 110〉 fiber crystalline texture of ferrite matrix during wire drawing.