The study results of the effects of temperature and ionic strength on the adsorption kineties of Pb ̄2+ and Cu ̄2+ bylatosol, red soil and kaolinte coated with Mn oxide showed that Pb ̄2+ and Cu ̄2+ adsorption by all ...The study results of the effects of temperature and ionic strength on the adsorption kineties of Pb ̄2+ and Cu ̄2+ bylatosol, red soil and kaolinte coated with Mn oxide showed that Pb ̄2+ and Cu ̄2+ adsorption by all samples, as awhole, increased with missing temperature. Temperature also increased both values of X_m (the amount of ionadsorbed at equilibrium) and k (kinetica constant) of Pb ̄2+ and Cu ̄2+. The activation energies of Pb ̄2+ adsorption werekaolin-Mn >red soil>goethite and those of Cu ̄2+ were latosol> red soil > kaolin-Mn >goethite. For a given singlesample the activation energy of Cu ̄2+ was greater than that of Pb ̄2+. Raising ionic strength decreased the adsorptionof Pb ̄2+ and Cu ̄2+ by latosol, red soil and kaolinite coated with Mn oxide but increased Pb ̄2+ and Cu ̄2+ adsorption bygoethite. The contrary results could be explained by the different changes in ion forms of Pb ̄2+ or Cu ̄2+ and in surfacecbarge characteristics of latosol, red soil, kaolin-Mn and goethite. Increasing supporting electrolyte concentration in-creased X_m and k in goethite systems but decreased X_m and k in kaolin-Mn systems. All the time-dependent data fit-ted the surface second-order equation very well.展开更多
Interaction between beta-lactum antibiotic drug ciprofloxacin hydrochloride(CFH)and cationic surfactant cetyltrimethylammonium bromide(CTAB)was performed conductometrically in aqueous as well as in the occurrence of d...Interaction between beta-lactum antibiotic drug ciprofloxacin hydrochloride(CFH)and cationic surfactant cetyltrimethylammonium bromide(CTAB)was performed conductometrically in aqueous as well as in the occurrence of different salts(NaCl,KCl as well as NH_4Cl)over the temperature range of 298.15–323.15 K at the regular interval of 5 K.CFH drug has been suggested for the treatment of bacterial infections such as urinary tract infections and acute sinusitis.A clear critical micelle concentration(CMC)was obtained for pure CTAB as well as(CFH+CTAB)mixed systems.The decrease in CMC values of CTAB caused by the addition of CFH reveals the existence of the interaction between the components and therefore it is the indication of micelle formation at lower concentration of CTAB and their CMC values further decrease in attendance of salts.A nonlinear behavior in the CMC versus T plot was observed in all the cases.The ΔG_m^0 values are found to be negative in present study systems demonstrated the stability of the solution.The values of ΔH_m^0 and ΔS_m^0 reveal the existence of hydrophobic and electrostatic interactions between CFH and CTAB.The thermodynamic properties of transfer for the micellization were also evaluated and discussed in detail.Molecular dynamic simulation disclosed that environment of water and salts have impact on the hydrophobic interaction between CFH and CTAB.In water and salts,CTAB adopts spherical micelle in which charged hydrophilic groups are interacted with waters whereas hydrophobic tails form the core of the micelle.This hydrophobic core region is highly conserved and protected.In addition,micelle formation is more favorable in aqueous Na Cl solution than other solutions.展开更多
Electrical power supply to communities isolated from urban areas is typically complex and expensive. Their geographical situation and the lack of infrastructure and qualified workforce impede the provision of electric...Electrical power supply to communities isolated from urban areas is typically complex and expensive. Their geographical situation and the lack of infrastructure and qualified workforce impede the provision of electricity. Many are the sources of energy available, but few are appropriate or sustainable. Combustion of diesel fuel is a good technical solution; however, it is neither economic nor environmentally tenable. This paper presents the advantages of using biomass as an energy source, along with its potential increase in efficiency when steam is generated in specific circumstances of temperature and pressure.展开更多
Decrease or enlargement of the number of pairinos in nuclei and as free nucleons, pairinos, electrinos, positpinos is a factor of destabilization in the matter and or environment. For the benefit of a electronic-posit...Decrease or enlargement of the number of pairinos in nuclei and as free nucleons, pairinos, electrinos, positpinos is a factor of destabilization in the matter and or environment. For the benefit of a electronic-positron structure the representations about an annihilation of the electronic-positron pairs, formation in substance electronic-positron of pairs under activity action of a gamma radiation, electronic and positron character of a beta radiation in nuclei are worked. Terminology: positrino, electrino, pairino. The new mechanism of a physical phenomenon, well explored to the present moment, with the conventional interpretation - mechanism of an annihilation of a free positron on electrons of substance is offered. That is the conventional point of view is those, that during annihilation the electron bums down, disappears or is transmuted into a gamma-quantum. In opinion of the author any facts or the proofs of such interpretation do not exist. The following mechanism therefore is offered: an electron and positron at coming together are discharged by two gamma-quantum and form pairino (unloaded electron - positron state with gravitational mass "m" about 2 eV, with compensation by electric charge, about an electrino by positrino interaction); that is the mechanism "cold" (low, is less than 10 KeV, energies) synthesis of pairino. The given mechanism of phenomenon of annihilation is more realistic.展开更多
Early and accurate fault detection and diagnosis for renewable energy systems can increase their safety and ensure the continuity of their service. This paper presents a comprehensive review of different fault detecti...Early and accurate fault detection and diagnosis for renewable energy systems can increase their safety and ensure the continuity of their service. This paper presents a comprehensive review of different fault detection and diagnosis methods for hybrid renewable energy systems consisting of a wind turbine power generator, a PV (photovoltaic) array, a PEM (polymer electrolyte membrane) fuel cell and a battery storage system. The need of batteries to store the generated power from the solar panel, wind turbine or PEM fuel cell is also emphasized. Finally, an overview of the current methods used in the diagnosing of the lead-acid battery degradation is given.展开更多
In this study, a novel design concept for PEMFC (polymer electrolyte membrane fuel cell) stacks is presented with single cells inserted in pockets surrounded by a hydraulic medium. The hydraulic pressure introduces ...In this study, a novel design concept for PEMFC (polymer electrolyte membrane fuel cell) stacks is presented with single cells inserted in pockets surrounded by a hydraulic medium. The hydraulic pressure introduces necessary compression forces to the membrane electrode assembly of each cell within a stack. Moreover, homogeneous cell cooling is achieved by this medium. First, prototypes presented in this work indicate that, upscaling of cells for the novel stack design is possible without significant performance losses. Due to its modularity and scalability, this stack design meets the requirements for large PEMFC units.展开更多
The conventional collector for diaspore mineral is oleic acid,which is highly insoluble and must be used in high dosage in bauxite flotation,that is the great drawback of oleic acid in use.Octylic hydroxamic acid was ...The conventional collector for diaspore mineral is oleic acid,which is highly insoluble and must be used in high dosage in bauxite flotation,that is the great drawback of oleic acid in use.Octylic hydroxamic acid was synthesized,and its collecting ability to certain minerals in bauxite:diaspore and kaolinite were studied.The collecting power of various reagents to diaspore in an incremental sequence was shown as follows:oleic acid<octylic hydroxamic acid,while the incremental sequence of the collecting power to kaolinite was like this:octylic hydroxamic acid < oleic acid.It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity,and octylic hydroxamic acid was chosen to use in the following experiments.Reduced zeta potential showed the adsorption of the anionic collector on the mineral.By the adsorptive capability and IR(infrared ray)tests,the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption,which was greater than that of oleic acid,as it was absorption by hydrogen bond.展开更多
High-precision sensing of vectorial forces has broad impact on both fundamental research and technological applications such as the examination of vacuum fluctuations and the detection of surface roughness of nanostru...High-precision sensing of vectorial forces has broad impact on both fundamental research and technological applications such as the examination of vacuum fluctuations and the detection of surface roughness of nanostructures.Recent years have witnessed much progress on sensing alternating electromagnetic forces for the rapidly advancing quantum technology-orders of magnitude improvement has been accomplished on the detection sensitivity with atomic sensors,whereas such high-precision measurements for static electromagnetic forces have rarely been demonstrated.Here,based on quantum atomic matter waves confined by a two-dimensional optical lattice,we perform precision measurement of static electromagnetic forces by imaging coherent wave mechanics in the reciprocal space.The lattice confinement causes a decoupling between real-space and reciprocal dynamics,and provides a rigid coordinate frame for calibrating the wavevector accumulation of the matter wave.With that we achieve a stateof-the-art sensitivity of 2.30(8)×10^(-26) N/√Hz.Long-term stabilities on the order of 10^(-28) N are observed in the two spatial components of a force,which allows probing atomic Van der Waals forces at one millimeter distance.As a further illustrative application,we use our atomic sensor to calibrate the control precision of an alternating electromagnetic force applied in the experiment.Future developments of this method hold promise for delivering unprecedented atom-based quantum force sensing technologies.展开更多
Many experiments have proven that with increasing silt and gas(out-of-phase media)content in water,the cavitation characteristics change and the cavitation pressure increases.Currently,many large reservoirs in China a...Many experiments have proven that with increasing silt and gas(out-of-phase media)content in water,the cavitation characteristics change and the cavitation pressure increases.Currently,many large reservoirs in China are polluted by total phosphorus(TP)and other chemical contaminants because of the use of phosphate fertilizer runoff from agriculture.However,research regarding how chemical pollutants(in the form of out-of-phase media)affect the cavitation pressure characteristics of water is sparse.In this paper,the Goupitan Hydropower Station,the largest hydropower reservoir on the Wujiang River,which is heavily polluted by TP,is taken as an example to evaluate the effects of chemical pollution on water cavitation pressure characteristics.In this study,the cavitation pressure characteristics of polluted and clean water are compared.The results show that the cavitation pressure of water polluted by chemicals is larger than that of clean water.In a hydraulic power generation system,cavitation and cavitation erosion are likely to occur earlier in runners when the fluid is polluted.These results are of great importance to further studies of cavitation theory and can directly influence the arrangement of turbines in practical engineering.展开更多
Iron difluoride(FeF_(2))is considered a highcapacity cathode material for lithium-ion batteries.However,its specific capacity and stability are limited by the poor electrochemical kinetics of conversion reactions.Here...Iron difluoride(FeF_(2))is considered a highcapacity cathode material for lithium-ion batteries.However,its specific capacity and stability are limited by the poor electrochemical kinetics of conversion reactions.Herein,the conversion reaction is confined in a localized nanosized space by encapsulating FeF_(2) nanoparticles in polymer gelatin.The FeF_(2) nanocrystal-coated polyvinylidene fluoride-based layer(defined as Fe F_(2) @100%G-40%P)was synthesized by glucoseassisted in-situ gelatinization to construct an artificial cathode solid electrolyte interphase via a solvothermal process.Thanks to the improved kinetics of the localized conversion reaction,the obtained FeF_(2) @100%G-40%P electrodes show good cyclic stability(313mAhg^(-1) after 150 cycles at 100 mAg^(-1) ,corresponding to a retention of 80%)and a high rate performance(186.6 mAhg^(-1) at 500 mAg^(-1)).展开更多
We study a minimal extension of the standard model by introducing three right-handed neutrinos and a new scotogenic scalar doublet,in which the mass splittings between neutral and charged components are responsible fo...We study a minimal extension of the standard model by introducing three right-handed neutrinos and a new scotogenic scalar doublet,in which the mass splittings between neutral and charged components are responsible for the W-boson mass newly measured by the CDF Collaboration.This model can not only generate non-vanishing Majorana neutrino masses via the interaction of right-handed neutrinos and scotogenic scalars,but also explain the Universe’s missing matter in the form of FIMP dark matter.We also study the influence of the mass splitting on the first order electroweak phase transition,and find that it can further enhance the transition strength and thus induce gravitational waves during the phase transition,which may be detected in the forthcoming detectors such as U-DECIGO.展开更多
文摘The study results of the effects of temperature and ionic strength on the adsorption kineties of Pb ̄2+ and Cu ̄2+ bylatosol, red soil and kaolinte coated with Mn oxide showed that Pb ̄2+ and Cu ̄2+ adsorption by all samples, as awhole, increased with missing temperature. Temperature also increased both values of X_m (the amount of ionadsorbed at equilibrium) and k (kinetica constant) of Pb ̄2+ and Cu ̄2+. The activation energies of Pb ̄2+ adsorption werekaolin-Mn >red soil>goethite and those of Cu ̄2+ were latosol> red soil > kaolin-Mn >goethite. For a given singlesample the activation energy of Cu ̄2+ was greater than that of Pb ̄2+. Raising ionic strength decreased the adsorptionof Pb ̄2+ and Cu ̄2+ by latosol, red soil and kaolinite coated with Mn oxide but increased Pb ̄2+ and Cu ̄2+ adsorption bygoethite. The contrary results could be explained by the different changes in ion forms of Pb ̄2+ or Cu ̄2+ and in surfacecbarge characteristics of latosol, red soil, kaolin-Mn and goethite. Increasing supporting electrolyte concentration in-creased X_m and k in goethite systems but decreased X_m and k in kaolin-Mn systems. All the time-dependent data fit-ted the surface second-order equation very well.
文摘Interaction between beta-lactum antibiotic drug ciprofloxacin hydrochloride(CFH)and cationic surfactant cetyltrimethylammonium bromide(CTAB)was performed conductometrically in aqueous as well as in the occurrence of different salts(NaCl,KCl as well as NH_4Cl)over the temperature range of 298.15–323.15 K at the regular interval of 5 K.CFH drug has been suggested for the treatment of bacterial infections such as urinary tract infections and acute sinusitis.A clear critical micelle concentration(CMC)was obtained for pure CTAB as well as(CFH+CTAB)mixed systems.The decrease in CMC values of CTAB caused by the addition of CFH reveals the existence of the interaction between the components and therefore it is the indication of micelle formation at lower concentration of CTAB and their CMC values further decrease in attendance of salts.A nonlinear behavior in the CMC versus T plot was observed in all the cases.The ΔG_m^0 values are found to be negative in present study systems demonstrated the stability of the solution.The values of ΔH_m^0 and ΔS_m^0 reveal the existence of hydrophobic and electrostatic interactions between CFH and CTAB.The thermodynamic properties of transfer for the micellization were also evaluated and discussed in detail.Molecular dynamic simulation disclosed that environment of water and salts have impact on the hydrophobic interaction between CFH and CTAB.In water and salts,CTAB adopts spherical micelle in which charged hydrophilic groups are interacted with waters whereas hydrophobic tails form the core of the micelle.This hydrophobic core region is highly conserved and protected.In addition,micelle formation is more favorable in aqueous Na Cl solution than other solutions.
文摘Electrical power supply to communities isolated from urban areas is typically complex and expensive. Their geographical situation and the lack of infrastructure and qualified workforce impede the provision of electricity. Many are the sources of energy available, but few are appropriate or sustainable. Combustion of diesel fuel is a good technical solution; however, it is neither economic nor environmentally tenable. This paper presents the advantages of using biomass as an energy source, along with its potential increase in efficiency when steam is generated in specific circumstances of temperature and pressure.
文摘Decrease or enlargement of the number of pairinos in nuclei and as free nucleons, pairinos, electrinos, positpinos is a factor of destabilization in the matter and or environment. For the benefit of a electronic-positron structure the representations about an annihilation of the electronic-positron pairs, formation in substance electronic-positron of pairs under activity action of a gamma radiation, electronic and positron character of a beta radiation in nuclei are worked. Terminology: positrino, electrino, pairino. The new mechanism of a physical phenomenon, well explored to the present moment, with the conventional interpretation - mechanism of an annihilation of a free positron on electrons of substance is offered. That is the conventional point of view is those, that during annihilation the electron bums down, disappears or is transmuted into a gamma-quantum. In opinion of the author any facts or the proofs of such interpretation do not exist. The following mechanism therefore is offered: an electron and positron at coming together are discharged by two gamma-quantum and form pairino (unloaded electron - positron state with gravitational mass "m" about 2 eV, with compensation by electric charge, about an electrino by positrino interaction); that is the mechanism "cold" (low, is less than 10 KeV, energies) synthesis of pairino. The given mechanism of phenomenon of annihilation is more realistic.
文摘Early and accurate fault detection and diagnosis for renewable energy systems can increase their safety and ensure the continuity of their service. This paper presents a comprehensive review of different fault detection and diagnosis methods for hybrid renewable energy systems consisting of a wind turbine power generator, a PV (photovoltaic) array, a PEM (polymer electrolyte membrane) fuel cell and a battery storage system. The need of batteries to store the generated power from the solar panel, wind turbine or PEM fuel cell is also emphasized. Finally, an overview of the current methods used in the diagnosing of the lead-acid battery degradation is given.
文摘In this study, a novel design concept for PEMFC (polymer electrolyte membrane fuel cell) stacks is presented with single cells inserted in pockets surrounded by a hydraulic medium. The hydraulic pressure introduces necessary compression forces to the membrane electrode assembly of each cell within a stack. Moreover, homogeneous cell cooling is achieved by this medium. First, prototypes presented in this work indicate that, upscaling of cells for the novel stack design is possible without significant performance losses. Due to its modularity and scalability, this stack design meets the requirements for large PEMFC units.
基金National Key Fundamental Research and Development Program (No.2005cb623701)
文摘The conventional collector for diaspore mineral is oleic acid,which is highly insoluble and must be used in high dosage in bauxite flotation,that is the great drawback of oleic acid in use.Octylic hydroxamic acid was synthesized,and its collecting ability to certain minerals in bauxite:diaspore and kaolinite were studied.The collecting power of various reagents to diaspore in an incremental sequence was shown as follows:oleic acid<octylic hydroxamic acid,while the incremental sequence of the collecting power to kaolinite was like this:octylic hydroxamic acid < oleic acid.It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity,and octylic hydroxamic acid was chosen to use in the following experiments.Reduced zeta potential showed the adsorption of the anionic collector on the mineral.By the adsorptive capability and IR(infrared ray)tests,the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption,which was greater than that of oleic acid,as it was absorption by hydrogen bond.
基金supported by the National Program on Key Basic Research Project of China (2018YFA0305601, 2021YFA07183012021YFA1400900)+4 种基金the National Natural Science Foundation of China (61727819, 11934002, and 11874073)Shanghai Municipal Science and Technology Major Project (2019SHZDZCX01)the Chinese Academy of Sciences Priority Research Program(XDB35020100)the Science and Technology Major Project of Shanxi (202101030201022)the Space Application System of China Manned Space Program
文摘High-precision sensing of vectorial forces has broad impact on both fundamental research and technological applications such as the examination of vacuum fluctuations and the detection of surface roughness of nanostructures.Recent years have witnessed much progress on sensing alternating electromagnetic forces for the rapidly advancing quantum technology-orders of magnitude improvement has been accomplished on the detection sensitivity with atomic sensors,whereas such high-precision measurements for static electromagnetic forces have rarely been demonstrated.Here,based on quantum atomic matter waves confined by a two-dimensional optical lattice,we perform precision measurement of static electromagnetic forces by imaging coherent wave mechanics in the reciprocal space.The lattice confinement causes a decoupling between real-space and reciprocal dynamics,and provides a rigid coordinate frame for calibrating the wavevector accumulation of the matter wave.With that we achieve a stateof-the-art sensitivity of 2.30(8)×10^(-26) N/√Hz.Long-term stabilities on the order of 10^(-28) N are observed in the two spatial components of a force,which allows probing atomic Van der Waals forces at one millimeter distance.As a further illustrative application,we use our atomic sensor to calibrate the control precision of an alternating electromagnetic force applied in the experiment.Future developments of this method hold promise for delivering unprecedented atom-based quantum force sensing technologies.
基金supported by the National Natural Science Foundation of China(Grant No.50976124)
文摘Many experiments have proven that with increasing silt and gas(out-of-phase media)content in water,the cavitation characteristics change and the cavitation pressure increases.Currently,many large reservoirs in China are polluted by total phosphorus(TP)and other chemical contaminants because of the use of phosphate fertilizer runoff from agriculture.However,research regarding how chemical pollutants(in the form of out-of-phase media)affect the cavitation pressure characteristics of water is sparse.In this paper,the Goupitan Hydropower Station,the largest hydropower reservoir on the Wujiang River,which is heavily polluted by TP,is taken as an example to evaluate the effects of chemical pollution on water cavitation pressure characteristics.In this study,the cavitation pressure characteristics of polluted and clean water are compared.The results show that the cavitation pressure of water polluted by chemicals is larger than that of clean water.In a hydraulic power generation system,cavitation and cavitation erosion are likely to occur earlier in runners when the fluid is polluted.These results are of great importance to further studies of cavitation theory and can directly influence the arrangement of turbines in practical engineering.
基金supported by the Science and Technology Commission of Shanghai Municipality(20520710400,19JC1412600 and 18230743400)the National Natural Science Foundation of China(21771124 and 21901156)+1 种基金the Oceanic Interdisciplinary Program(SL2020MS020)the SJTU-Warwick Joint Seed Fund(2019/20)of Shanghai Jiao Tong University。
文摘Iron difluoride(FeF_(2))is considered a highcapacity cathode material for lithium-ion batteries.However,its specific capacity and stability are limited by the poor electrochemical kinetics of conversion reactions.Herein,the conversion reaction is confined in a localized nanosized space by encapsulating FeF_(2) nanoparticles in polymer gelatin.The FeF_(2) nanocrystal-coated polyvinylidene fluoride-based layer(defined as Fe F_(2) @100%G-40%P)was synthesized by glucoseassisted in-situ gelatinization to construct an artificial cathode solid electrolyte interphase via a solvothermal process.Thanks to the improved kinetics of the localized conversion reaction,the obtained FeF_(2) @100%G-40%P electrodes show good cyclic stability(313mAhg^(-1) after 150 cycles at 100 mAg^(-1) ,corresponding to a retention of 80%)and a high rate performance(186.6 mAhg^(-1) at 500 mAg^(-1)).
基金supported by the National Natural Science Foundation of China(11805161,12005180,and 11975195)the Natural Science Foundation of Shandong Province(ZR2020QA083 and ZR2019JQ04)the Project of Shandong Province Higher Educational Science and Technology Program(2019KJJ007)。
文摘We study a minimal extension of the standard model by introducing three right-handed neutrinos and a new scotogenic scalar doublet,in which the mass splittings between neutral and charged components are responsible for the W-boson mass newly measured by the CDF Collaboration.This model can not only generate non-vanishing Majorana neutrino masses via the interaction of right-handed neutrinos and scotogenic scalars,but also explain the Universe’s missing matter in the form of FIMP dark matter.We also study the influence of the mass splitting on the first order electroweak phase transition,and find that it can further enhance the transition strength and thus induce gravitational waves during the phase transition,which may be detected in the forthcoming detectors such as U-DECIGO.