通过极化曲线研究了3种不同溶液(阴极液、阳极液和完整镀液)的电化学行为,测定了主盐、还原剂浓度以及镀液p H和体系温度对化学镀镍沉积速率的影响.与直接在镁合金上化学镀镍并使用重量分析法得到的沉积速率相比较发现,完整镀液体系的...通过极化曲线研究了3种不同溶液(阴极液、阳极液和完整镀液)的电化学行为,测定了主盐、还原剂浓度以及镀液p H和体系温度对化学镀镍沉积速率的影响.与直接在镁合金上化学镀镍并使用重量分析法得到的沉积速率相比较发现,完整镀液体系的极化曲线才能真实地反映化学镀镍的沉积过程,其过程不能简单视为由彼此完全独立毫无关联的阴阳极半反应构成.根据Butler-Volmer公式,本化学镀液体系的化学镀镍过程属混合控制,其表观反应活化能为42.89 k J·mol-1.展开更多
This paper describes the foundation underlying the device physics and theory of the semiconductor field effect transistor which is applicable to any devices with two carrier species in an electric field. The importanc...This paper describes the foundation underlying the device physics and theory of the semiconductor field effect transistor which is applicable to any devices with two carrier species in an electric field. The importance of the boundary conditions on the device current-voltage characteristics is discussed. An illustration is given of the transfer DCIV characteristics computed for two boundary conditions,one on electrical potential,giving much higher drift-limited parabolic current through the intrinsic transistor, and the other on the electrochemical potentials, giving much lower injection-over-thebarrier diffusion-limited current with ideal 60mV per decade exponential subthreshold roll-off, simulating electron and hole contacts. The two-MOS-gates on thin pure-body silicon field-effect transistor is used as examples展开更多
The field-effect transistor is inherently bipolar, having simultaneously electron and hole surface and volume channels and currents. The channels and currents are controlled by one or more externally applied transvers...The field-effect transistor is inherently bipolar, having simultaneously electron and hole surface and volume channels and currents. The channels and currents are controlled by one or more externally applied transverse electric fields. It has been known as the unipolar field-effect transistor for 55-years since Shockley's 1952 invention,because the electron-current theory inevitably neglected the hole current from over-specified internal and boundary conditions, such as the electrical neutrality and the constant hole-electrochemical-potential, resulting in erroneous solutions of the internal and terminal electrical characteristics from the electron channel current alone, which are in gross error when the neglected hole current becomes comparable to the electron current, both in subthreshold and strong inversion. This report presents the general theory, that includes both electron and hole channels and currents. The rectangular ( x, y, z) parallelepiped transistors,uniform in the width direction (z-axis),with one or two MOS gates on thin and thick,and pure and impure base, are used to illustrate the two-dimensional effects and the correct internal and boundary conditions for the electric and the electron and hole electrochemical potentials. Complete analytical equations of the DC current-voltage characteristics of four common MOS transistor structures are derived without over-specification: the 1-gate on semi-infinite-thick impure-base (the traditional bulk transistor), the 1-gate on thin impure-silicon layer over oxide-insulated silicon bulk (SOI) ,the 1-gate on thin impure-silicon layer deposited on insulating glass (SOI TFT), and the 2-gates on thin pure-base (FinFETs).展开更多
The Weakest Bound Electron Potential Model theory is used to calculate transition probability-values and oscillator strength-values for individual lines of Sc(Ⅲ) and Y(Ⅲ). In this method, by solving the SchrSdin...The Weakest Bound Electron Potential Model theory is used to calculate transition probability-values and oscillator strength-values for individual lines of Sc(Ⅲ) and Y(Ⅲ). In this method, by solving the SchrSdinger equation of the weakest bound electron, the expressions of energy eigenvalue and the radial function can be obtained. And a coupled equation is used to determine the parameters which are needed in the calculations. The ob- tained results of Sc(III) from this work agree very well with the accepted values taken from the National Institute of Standards and Technoligy (NIST) data base, most deviations are within the accepted level. For Y(Ⅲ) there are no accepted values reported by the NIST data base. So we compared our results of Y(Ⅲ) with other theoretical results, good agreement is also obtained.展开更多
Electrocatalytic ammonia synthesis under mild conditions is an attractive and challenging process in the earth’s nitrogen cycle,which requires efficient and stable catalysts to reduce the overpotential.The N2 activat...Electrocatalytic ammonia synthesis under mild conditions is an attractive and challenging process in the earth’s nitrogen cycle,which requires efficient and stable catalysts to reduce the overpotential.The N2 activation and reduction overpotential of different Ti3C2O2-supported transition metal(TM)(Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Mo,Ru,Rh,Pd,Ag,Cd,and Au)single-atom catalysts have been analyzed in terms of the Gibbs free energies calculated using the density functional theory(DFT).The end-on N2 adsorption was more energetically favorable,and the negative free energies represented good N2 activation performance,especially in the presence Fe/Ti3C2O2(﹣0.75 eV).The overpotentials of Fe/Ti3C2O2,Co/Ti3C2O2,Ru/Ti3C2O2,and Rh/Ti3C2O2 were 0.92,0.89,1.16,and 0.84 eV,respectively.The potential required for ammonia synthesis was different for different TMs and ranged from 0.68 to 2.33 eV.Two possible potential-limiting steps may be involved in the process:(i)hydrogenation of N2 to*NNH and(ii)hydrogenation of*NH2 to ammonia.These catalysts can change the reaction pathway and avoid the traditional N–N bond-breaking barrier.It also simplifies the understanding of the relationship between the Gibbs free energy and overpotential,which is a significant factor in the rational designing and large-scale screening of catalysts for the electrocatalytic ammonia synthesis.展开更多
Using density function theory (DFT), the Cu-doped Aln (n=1-15) clusters have been stud- ied. The electron affinity, ionization potential, Mulliken population analysis of Cu, mean polarizability, polarizability ani...Using density function theory (DFT), the Cu-doped Aln (n=1-15) clusters have been stud- ied. The electron affinity, ionization potential, Mulliken population analysis of Cu, mean polarizability, polarizability anisotropy, dipole moments and HOMO-LUMO gaps have also been calculated on the basis of optimized geometries. The results indicate that there is magic numbers in copper-doped aluminum clusters and electronic characteristic depended on the size of clusters. As n=13, the electron affinity and ionization potential of cluster changed more than 0.3 and 0.6 eV respectively, compared with neighborhood clusters.展开更多
From the perturbation around the background spacetimes in the Gauss Bonnet gravity, we find the physical evidence that Ricci fiat AdS black holes and AdS solitons are different physical configurations and stay in diff...From the perturbation around the background spacetimes in the Gauss Bonnet gravity, we find the physical evidence that Ricci fiat AdS black holes and AdS solitons are different physical configurations and stay in different phases, this serves as a strong support to the previous mathematical and thermodynamieal arguments.展开更多
The interaction potentials between electron and atom play an important role in electron- atom scattering. Using three potential models, the absolute differential cross section has been calculated by the second Born ap...The interaction potentials between electron and atom play an important role in electron- atom scattering. Using three potential models, the absolute differential cross section has been calculated by the second Born approximation theory. Results show that these model potentials are successful in the laser-assisted e-Ar scattering system. The influence of static potential, exchange potential and polarization potential on the absolute differential cross section is also analyzed and discussed.展开更多
The formation mechanism of porous anodic oxides remains unclear till now.The classical field-assisted dissolution(FAD)theory cannot explain the relationship between the current curve and FAD reaction,and the influence...The formation mechanism of porous anodic oxides remains unclear till now.The classical field-assisted dissolution(FAD)theory cannot explain the relationship between the current curve and FAD reaction,and the influence of the electrode potential on anodization is rarely reported.The electrode potential theory,oxygen bubble model and the ionic current and electronic current theories were introduced to explain the growth of porous anodic oxides of three metals(Ti,Zr and Fe).Taking the anodization of Ti in aqueous solution containing 0.5wt% NH_(4)F as an example,the electrode potential was calculated,and the morphology of porous anodic oxides was investigated at low voltages.Results show that the growth of porous anodic oxides is determined by the ratio of the ionic current to the electronic current.During the anodization,metals are classified into two groups:one is easy to form the compact oxide layer,and the other is easy to induce oxygen releasing,thus forming oxygen bubbles.The electrolyte is also classified into two groups correspondingly:compact oxide layer-assisted electrolyte and releasing oxygen-assisted electrolyte.展开更多
Aiming at the air-gap magnetic field excited by wall armatures,Laplace’s partial differential equation of air-gap magnetic potential is achieved by means of the electromagnetic field theory.According to the magnetic ...Aiming at the air-gap magnetic field excited by wall armatures,Laplace’s partial differential equation of air-gap magnetic potential is achieved by means of the electromagnetic field theory.According to the magnetic boundary conditions and the method of separation of variables,the magnetic potential of the air-gap magnetic field is obtained.Based on the magnetization force model and Lorentz force of ferromagnetic thin-walled structures,and introducing the electromagnetic constitutive relations and boundary conditions,the calculation model of electromagnetic force of the soft ferromagnetic thin plate moving in air-gap magnetic field is established.Considering geometric nonlinearity,expressions of strain energy and kinetic energy of the elastic thin plate and the work of forces are given,respectively.The magnetic-structure coupling nonlinear vibration equations of ferromagnetic thin plate parallel moving in the air-gap magnetic field excited by armatures are obtained by using the Hamilton principle,which can be of the characterization of the system dynamics model with electro-magneto-velocity-mechanical interaction.Through numerical examples,primary resonance characteristics of the strip thin plate under the action of air-gap magnetic force are obtained.The results show that the two stable amplitude values will increase as amplitude of magnetic potential increases and thickness of air-gap decreases,and the amplitude’s multi-valued region will change due to the varieties of magnetic potential,air-gap and velocity.The model established in this paper is a theoretical reference for investigation on the multi-field coupling dynamic behaviors of structures moving in complex electromagnetic fields.展开更多
We investigate the Hawking radiation of a GMGHS charged black hole from the heterotic string scenario by the massive particles turmeling method. We consider the spacetime background to be dynamical, incorporate the se...We investigate the Hawking radiation of a GMGHS charged black hole from the heterotic string scenario by the massive particles turmeling method. We consider the spacetime background to be dynamical, incorporate the self-gravitation effect of the emitted particles and show that the tunneling rate is related to the change of Bekenstein- Hawking entropy and the derived emission spectrum does not deviate from the pure thermal spectrum of Schwrzschild's black hole.展开更多
The equilibrium geometries, relative stabilities, and electronic properties of Ca2Sin (n = 1-11) clusters have been systematically investigated by using the density function theory at the 6-311G (d) level The opti...The equilibrium geometries, relative stabilities, and electronic properties of Ca2Sin (n = 1-11) clusters have been systematically investigated by using the density function theory at the 6-311G (d) level The optimized geometries indicate that the most stable isomers have three-dimensional structures for n = 3-11. The electronic properties of Ca2 Sin (n = 1-11) dusters axe obtained through the analysis of the natural charge population, natural electron configuration, vertical ionization potential, and vertical electron affinity. The results show that the charges in corresponding Ca2Sin clusters transfer from the Ca atoms to the Sin host. Based on the obtained lowest-energy geometries, the size dependence of cluster properties, such as averaged binding energies, fragmentation energies, second-order energy differences, HOMO- LUMO gaps and chemical hardness, are deeply discussed.展开更多
文摘通过极化曲线研究了3种不同溶液(阴极液、阳极液和完整镀液)的电化学行为,测定了主盐、还原剂浓度以及镀液p H和体系温度对化学镀镍沉积速率的影响.与直接在镁合金上化学镀镍并使用重量分析法得到的沉积速率相比较发现,完整镀液体系的极化曲线才能真实地反映化学镀镍的沉积过程,其过程不能简单视为由彼此完全独立毫无关联的阴阳极半反应构成.根据Butler-Volmer公式,本化学镀液体系的化学镀镍过程属混合控制,其表观反应活化能为42.89 k J·mol-1.
文摘This paper describes the foundation underlying the device physics and theory of the semiconductor field effect transistor which is applicable to any devices with two carrier species in an electric field. The importance of the boundary conditions on the device current-voltage characteristics is discussed. An illustration is given of the transfer DCIV characteristics computed for two boundary conditions,one on electrical potential,giving much higher drift-limited parabolic current through the intrinsic transistor, and the other on the electrochemical potentials, giving much lower injection-over-thebarrier diffusion-limited current with ideal 60mV per decade exponential subthreshold roll-off, simulating electron and hole contacts. The two-MOS-gates on thin pure-body silicon field-effect transistor is used as examples
文摘The field-effect transistor is inherently bipolar, having simultaneously electron and hole surface and volume channels and currents. The channels and currents are controlled by one or more externally applied transverse electric fields. It has been known as the unipolar field-effect transistor for 55-years since Shockley's 1952 invention,because the electron-current theory inevitably neglected the hole current from over-specified internal and boundary conditions, such as the electrical neutrality and the constant hole-electrochemical-potential, resulting in erroneous solutions of the internal and terminal electrical characteristics from the electron channel current alone, which are in gross error when the neglected hole current becomes comparable to the electron current, both in subthreshold and strong inversion. This report presents the general theory, that includes both electron and hole channels and currents. The rectangular ( x, y, z) parallelepiped transistors,uniform in the width direction (z-axis),with one or two MOS gates on thin and thick,and pure and impure base, are used to illustrate the two-dimensional effects and the correct internal and boundary conditions for the electric and the electron and hole electrochemical potentials. Complete analytical equations of the DC current-voltage characteristics of four common MOS transistor structures are derived without over-specification: the 1-gate on semi-infinite-thick impure-base (the traditional bulk transistor), the 1-gate on thin impure-silicon layer over oxide-insulated silicon bulk (SOI) ,the 1-gate on thin impure-silicon layer deposited on insulating glass (SOI TFT), and the 2-gates on thin pure-base (FinFETs).
文摘The Weakest Bound Electron Potential Model theory is used to calculate transition probability-values and oscillator strength-values for individual lines of Sc(Ⅲ) and Y(Ⅲ). In this method, by solving the SchrSdinger equation of the weakest bound electron, the expressions of energy eigenvalue and the radial function can be obtained. And a coupled equation is used to determine the parameters which are needed in the calculations. The ob- tained results of Sc(III) from this work agree very well with the accepted values taken from the National Institute of Standards and Technoligy (NIST) data base, most deviations are within the accepted level. For Y(Ⅲ) there are no accepted values reported by the NIST data base. So we compared our results of Y(Ⅲ) with other theoretical results, good agreement is also obtained.
基金financially supported by the National Natural Science Foundation of China(21625604,21776251,21671172,21706229,21878272)~~
文摘Electrocatalytic ammonia synthesis under mild conditions is an attractive and challenging process in the earth’s nitrogen cycle,which requires efficient and stable catalysts to reduce the overpotential.The N2 activation and reduction overpotential of different Ti3C2O2-supported transition metal(TM)(Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Mo,Ru,Rh,Pd,Ag,Cd,and Au)single-atom catalysts have been analyzed in terms of the Gibbs free energies calculated using the density functional theory(DFT).The end-on N2 adsorption was more energetically favorable,and the negative free energies represented good N2 activation performance,especially in the presence Fe/Ti3C2O2(﹣0.75 eV).The overpotentials of Fe/Ti3C2O2,Co/Ti3C2O2,Ru/Ti3C2O2,and Rh/Ti3C2O2 were 0.92,0.89,1.16,and 0.84 eV,respectively.The potential required for ammonia synthesis was different for different TMs and ranged from 0.68 to 2.33 eV.Two possible potential-limiting steps may be involved in the process:(i)hydrogenation of N2 to*NNH and(ii)hydrogenation of*NH2 to ammonia.These catalysts can change the reaction pathway and avoid the traditional N–N bond-breaking barrier.It also simplifies the understanding of the relationship between the Gibbs free energy and overpotential,which is a significant factor in the rational designing and large-scale screening of catalysts for the electrocatalytic ammonia synthesis.
基金The work was supported by the National Natural Science Foundation of China (No.10374036 and No. 10374037) and the Chinese Academic of Engineering Physics (No.51480030105JW1301).
文摘Using density function theory (DFT), the Cu-doped Aln (n=1-15) clusters have been stud- ied. The electron affinity, ionization potential, Mulliken population analysis of Cu, mean polarizability, polarizability anisotropy, dipole moments and HOMO-LUMO gaps have also been calculated on the basis of optimized geometries. The results indicate that there is magic numbers in copper-doped aluminum clusters and electronic characteristic depended on the size of clusters. As n=13, the electron affinity and ionization potential of cluster changed more than 0.3 and 0.6 eV respectively, compared with neighborhood clusters.
文摘From the perturbation around the background spacetimes in the Gauss Bonnet gravity, we find the physical evidence that Ricci fiat AdS black holes and AdS solitons are different physical configurations and stay in different phases, this serves as a strong support to the previous mathematical and thermodynamieal arguments.
文摘The interaction potentials between electron and atom play an important role in electron- atom scattering. Using three potential models, the absolute differential cross section has been calculated by the second Born approximation theory. Results show that these model potentials are successful in the laser-assisted e-Ar scattering system. The influence of static potential, exchange potential and polarization potential on the absolute differential cross section is also analyzed and discussed.
基金National Natural Science Foundation of China(51577093,51777097)Natural Science Foundation of Jiangsu Higher Education Institutions(20KJB430040)+1 种基金Changzhou Science&Technology Program(CJ20200026)Qing Lan Project in Colleges and Universities of Jiangsu Province。
文摘The formation mechanism of porous anodic oxides remains unclear till now.The classical field-assisted dissolution(FAD)theory cannot explain the relationship between the current curve and FAD reaction,and the influence of the electrode potential on anodization is rarely reported.The electrode potential theory,oxygen bubble model and the ionic current and electronic current theories were introduced to explain the growth of porous anodic oxides of three metals(Ti,Zr and Fe).Taking the anodization of Ti in aqueous solution containing 0.5wt% NH_(4)F as an example,the electrode potential was calculated,and the morphology of porous anodic oxides was investigated at low voltages.Results show that the growth of porous anodic oxides is determined by the ratio of the ionic current to the electronic current.During the anodization,metals are classified into two groups:one is easy to form the compact oxide layer,and the other is easy to induce oxygen releasing,thus forming oxygen bubbles.The electrolyte is also classified into two groups correspondingly:compact oxide layer-assisted electrolyte and releasing oxygen-assisted electrolyte.
基金the National Natural Science Foundation of China(Grant Nos.12172321 and 11472239)the Hebei Provincial Natural Science Foundation of China(Grant No.A2020203007).
文摘Aiming at the air-gap magnetic field excited by wall armatures,Laplace’s partial differential equation of air-gap magnetic potential is achieved by means of the electromagnetic field theory.According to the magnetic boundary conditions and the method of separation of variables,the magnetic potential of the air-gap magnetic field is obtained.Based on the magnetization force model and Lorentz force of ferromagnetic thin-walled structures,and introducing the electromagnetic constitutive relations and boundary conditions,the calculation model of electromagnetic force of the soft ferromagnetic thin plate moving in air-gap magnetic field is established.Considering geometric nonlinearity,expressions of strain energy and kinetic energy of the elastic thin plate and the work of forces are given,respectively.The magnetic-structure coupling nonlinear vibration equations of ferromagnetic thin plate parallel moving in the air-gap magnetic field excited by armatures are obtained by using the Hamilton principle,which can be of the characterization of the system dynamics model with electro-magneto-velocity-mechanical interaction.Through numerical examples,primary resonance characteristics of the strip thin plate under the action of air-gap magnetic force are obtained.The results show that the two stable amplitude values will increase as amplitude of magnetic potential increases and thickness of air-gap decreases,and the amplitude’s multi-valued region will change due to the varieties of magnetic potential,air-gap and velocity.The model established in this paper is a theoretical reference for investigation on the multi-field coupling dynamic behaviors of structures moving in complex electromagnetic fields.
基金Supported by the Universidad Nacional de Colombia.Hermes Project Code 17318
文摘We investigate the Hawking radiation of a GMGHS charged black hole from the heterotic string scenario by the massive particles turmeling method. We consider the spacetime background to be dynamical, incorporate the self-gravitation effect of the emitted particles and show that the tunneling rate is related to the change of Bekenstein- Hawking entropy and the derived emission spectrum does not deviate from the pure thermal spectrum of Schwrzschild's black hole.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11304167 and 51374132Postdoctoral Science Foundation of China under Grant No.20110491317Natural Science Foundation of Henan Province under Grant Nos.2011B140015,132300410209,and 132300410290
文摘The equilibrium geometries, relative stabilities, and electronic properties of Ca2Sin (n = 1-11) clusters have been systematically investigated by using the density function theory at the 6-311G (d) level The optimized geometries indicate that the most stable isomers have three-dimensional structures for n = 3-11. The electronic properties of Ca2 Sin (n = 1-11) dusters axe obtained through the analysis of the natural charge population, natural electron configuration, vertical ionization potential, and vertical electron affinity. The results show that the charges in corresponding Ca2Sin clusters transfer from the Ca atoms to the Sin host. Based on the obtained lowest-energy geometries, the size dependence of cluster properties, such as averaged binding energies, fragmentation energies, second-order energy differences, HOMO- LUMO gaps and chemical hardness, are deeply discussed.