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自适应卡尔曼滤波分辨电化学重叠信号的研究 被引量:1
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作者 杨孙楷 陈庆绸 曾子建 《分析仪器》 CAS 1990年第4期14-18,共5页
卡尔曼滤波器依赖于由两个方程组成的线性模型,在多组份分析时测量模型会存在误差,自适应卡尔曼滤波技术实时估计协方差R以补偿这种误差。本文在脉冲极谱分析法领域研究自适应卡尔曼滤波技术的应用.常规脉冲极谱和差分脉冲极谱的拟合数... 卡尔曼滤波器依赖于由两个方程组成的线性模型,在多组份分析时测量模型会存在误差,自适应卡尔曼滤波技术实时估计协方差R以补偿这种误差。本文在脉冲极谱分析法领域研究自适应卡尔曼滤波技术的应用.常规脉冲极谱和差分脉冲极谱的拟合数据试验表明,应用这种技术时,数据序列的初始几个数据不能是零;自适应滤波的估计误差远小于普通滤波的估计误差。用自适应卡尔曼滤波器分辨Cd(Ⅱ)/In(Ⅲ)重叠响应信号,新息序列表明,测量模型误差存在于Cd(Ⅱ)开始起波至峰值范围内. 展开更多
关键词 卡尔曼滤波器 电化信号 脉冲极谱
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双信号电化学法检测金雀异黄素对MCF-7细胞的抑制作用 被引量:3
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作者 曹海鹏 蔺润先 +2 位作者 段春雷 武冬梅 李锦莲 《黑龙江医药科学》 2014年第1期88-89,共2页
目的:电化学法研究金雀异黄素对MCF-7的抑制作用.方法:采用双信号电化学法.结果:在10×10-6~120×10-6μM的剂量范围内,随着金雀异黄素剂量的增加,MCF-7的两个电化学信号呈现下降趋势.结论:MCF-7的两个电化学信号均具有金... 目的:电化学法研究金雀异黄素对MCF-7的抑制作用.方法:采用双信号电化学法.结果:在10×10-6~120×10-6μM的剂量范围内,随着金雀异黄素剂量的增加,MCF-7的两个电化学信号呈现下降趋势.结论:MCF-7的两个电化学信号均具有金雀异黄素剂量依赖性,说明采用双信号电化学法可以很好地反映金雀异黄素对MCF-7细胞的抑制. 展开更多
关键词 信号电化学法 雀异黄素 MCF-7
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自动量程控制在DNA电化学信号采集仪中的应用
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作者 沈东海 杜民 陈旭海 《现代电子技术》 2010年第3期167-170,共4页
介绍一种基于电化学分析技术,用于疾病早期诊断的DNA电化学信号采集仪。详细阐述了仪器中的自动量程控制系统如何实现自动调整采样灵敏度。在此系统中,DSP处理器根据采集到的电流信号值控制两片数字电位器,从而调整I/V转换的灵敏度,实... 介绍一种基于电化学分析技术,用于疾病早期诊断的DNA电化学信号采集仪。详细阐述了仪器中的自动量程控制系统如何实现自动调整采样灵敏度。在此系统中,DSP处理器根据采集到的电流信号值控制两片数字电位器,从而调整I/V转换的灵敏度,实现自动量程控制的功能,这样就避免了手动设置灵敏度,提高了采样的灵活性和准确性。 展开更多
关键词 DNA电化信号采集仪 自动量程控制 数字电位器 I/V转换
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大米食味因子与电化学信号的相关性研究
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作者 杨柳 许甫生 +1 位作者 苏忠军 吴淑清 《粮食与油脂》 北大核心 2019年第10期18-24,共7页
采用基于方波伏安法的装置采集大米电化学信号,对电化学信号进行小波去噪后,对电化学信号和大米食味因子进行相关性分析。结果显示:Au、Pd、Cu、Pb、Cd、In、Ni、Fe、W、Ti的电化学信号均同大米直链淀粉含量负相关,同支链淀粉含量和支... 采用基于方波伏安法的装置采集大米电化学信号,对电化学信号进行小波去噪后,对电化学信号和大米食味因子进行相关性分析。结果显示:Au、Pd、Cu、Pb、Cd、In、Ni、Fe、W、Ti的电化学信号均同大米直链淀粉含量负相关,同支链淀粉含量和支直比正相关;而Al电极在某些电位点处同直链淀粉含量正相关,某些电位点处呈负相关,对支链淀粉和支直比情况类似。 展开更多
关键词 大米食味因子 电化信号 直链淀粉 支链淀粉
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皂土修饰碳糊电极的电化学发光特性研究及其分析应用 被引量:10
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作者 郑行望 章竹君 王琦 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2003年第8期1385-1389,共5页
基于皂土修饰碳糊电极对鲁米诺背景电化学发光信号的降低作用和对异烟肼的富集分离作用 ,建立了一种灵敏度高、选择性好的测定异烟肼的电化学发光新方法 .在最佳的实验条件下 ,相对电化学发光强度与异烟肼的浓度在 5 .0× 1 0 - 9~... 基于皂土修饰碳糊电极对鲁米诺背景电化学发光信号的降低作用和对异烟肼的富集分离作用 ,建立了一种灵敏度高、选择性好的测定异烟肼的电化学发光新方法 .在最佳的实验条件下 ,相对电化学发光强度与异烟肼的浓度在 5 .0× 1 0 - 9~ 8.0× 1 0 - 7mol/L范围内呈线性关系 ,方法的检出限为 1 .8× 1 0 - 9mol/L,相关系数为 0 .9984 . 展开更多
关键词 皂土修饰碳糊电极 电化学发光分析 电化学发光信号 异烟肼 测定 富集分离 鲁米诺
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基于磁性纳米颗粒和金纳米粒子构建DNA电化学生物传感技术 被引量:3
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作者 王小兰 郑静 +3 位作者 陈琛 汤亚泥 张帆 何品刚 《分析科学学报》 CAS CSCD 北大核心 2014年第4期477-480,共4页
本文构建了一种基于纳米粒子、茎环DNA和丝网印刷电极(SPCE)的电化学生物传感技术用于乳腺癌基因的快速、灵敏检测。该传感技术中,探针DNA的两端分别标记了巯基和生物素,巯基用于与金纳米粒子(AuNPs)作用,生物素用于与磁性纳米颗粒(MNPs... 本文构建了一种基于纳米粒子、茎环DNA和丝网印刷电极(SPCE)的电化学生物传感技术用于乳腺癌基因的快速、灵敏检测。该传感技术中,探针DNA的两端分别标记了巯基和生物素,巯基用于与金纳米粒子(AuNPs)作用,生物素用于与磁性纳米颗粒(MNPs)表面修饰的链酶亲和素作用以达到富集的目的,之后利用SPCE进行电化学检测。无目标DNA存在时,双标记DNA保持茎环结构,使得生物素分子很难和MNPs上的亲和素接触。一旦加入目标DNA,茎环结构打开,生物素得以与MNPs上的链霉亲和素发生特异性结合,形成的复合物(MNPs-DNA-AuNPs)通过磁性富集到SPCE表面,从而获得AuNPs的电化学信号。该DNA电化学生物传感对单碱基错配有良好的分辨能力,完全互补DNA的检出限为8.0×10-13 mol/L。 展开更多
关键词 本文构建了一种基于纳米粒子、茎环DNA和丝网印刷电极(SPCE)的电化学生物传感技术用于乳腺癌基因的快速、灵敏检测.该传感技术中 探针DNA的两端分别标记了巯基和生物素 巯基用于与金纳米粒子(AuNPs)作用 生物素用于与磁性纳米颗粒(MNPs)表面修饰的链酶亲和素作用以达到富集的目的 之后利用SPCE进行电化学检测.无目标DNA存在时 双标记DNA保持茎环结构 使得生物素分子很难和MNPs上的亲和素接触.一旦加入目标DNA 茎环结构打开 生物素得以与MNPs上的链霉亲和素发生特异性结合 形成的复合物(MNPs-DNA-AuNPs)通过磁性富集到SPCE表面 从而获得AuNPs的电化信号.该DNA电化学生物传感对单碱基错配有良好的分辨能力 完全互补DNA的检出限为8 0×10-13 mol L.本文构建了一种基于纳米粒子、茎环DNA和丝网印刷电极(SPCE)的电化学生物传感技术用于乳腺癌基因的快速、灵敏检测.该传感技术中 探针DNA的两端分别标记了巯基和生物素 巯基用于与金纳米粒子(AuNPs)作用 生物素用于与磁性纳米颗粒(MNPs)表面修饰的链酶亲和素作用以达到富集的目的 之后利用SPCE进行电化学检测.无目标DNA存在时 双标记DNA保持茎环结构 使得生物素分子很难和MNPs上的亲和素接触.一旦加入目标DNA 茎环结构打开 生物素得以与MNPs上的链霉亲和素发生特异性结合 形成的复合物(MNPs-DNA-AuNPs)通过磁性富集到SPCE表面 从而获得AuNPs的电化信号.该DNA电化学生物传感对单碱基错配有良好的分辨能力 完全互补DNA的检出限为8 0×10-13 mol L.磁性纳米颗粒 金纳米粒子 DNA 丝网印刷电极
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数字电视及其发展 被引量:4
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作者 姜艳芳 《中国电化教育》 CSSCI 北大核心 2000年第2期63-65,共3页
关键词 电化教学 数字电视 电化信号 图像质量
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单纯形法在伏安数据去噪中的应用
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作者 卢小泉 刘红德 +2 位作者 张敏 王小强 杨声 《天水师范学院学报》 2002年第5期16-18,共3页
提出了利用单纯形法对含噪音的数据的处理,讨论了原理,给出了算法,通过对多组数据的拟合,证明了单纯形调优法的可行性和优越性.
关键词 单纯形法 伏安数据 数据拟合 噪声 电化信号 电分析仪器
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A Signal-Flow Driven Automatic Physical Synthesis Methodology for Analog Circuits
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作者 龙迪 洪先龙 董社勤 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第4期689-696,共8页
This paper introduces a novel automatic physical synthesis methodology for analog circuits based on the signal-flow analysis.Circuit analysis sub-system adopts the newly advanced methodology,circuit topology analysis,... This paper introduces a novel automatic physical synthesis methodology for analog circuits based on the signal-flow analysis.Circuit analysis sub-system adopts the newly advanced methodology,circuit topology analysis,and circuit sensitivity analysis to generate layout constraints and control performance degradations.Considering the heuristic information about signal-flow,complexity of the methodology is less than the pure performance-driven methodology.And then these constraints are implemented in device generation,placement,and routing sub-systems separately,which makes the different constraints be satisfied at most easily implemented stages.Excellent circuit performance obtained by the methodology is demonstrated by practical circuit examples. 展开更多
关键词 analog layout automation signal-flow circuit analysis device generation PLACEMENT ROUTING
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基于微间隙生物芯片检测单核细胞增生李斯特菌 被引量:1
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作者 邱华丽 蒋成 +3 位作者 徐睿鑫 宋涛平 邱志鹏 杨丽霞 《食品与药品》 CAS 2017年第6期391-394,共4页
目的建立一种可快速检测食品中单核细胞增生李斯特菌的方法。方法以微间隙生物芯片阵列电极为基础电极,采用双抗夹心酶联免疫反应,结合酶的生物催化银沉淀反应,放大电化学分析信号,用于单核细胞增生李斯特菌的检测。结果该方法特异性好... 目的建立一种可快速检测食品中单核细胞增生李斯特菌的方法。方法以微间隙生物芯片阵列电极为基础电极,采用双抗夹心酶联免疫反应,结合酶的生物催化银沉淀反应,放大电化学分析信号,用于单核细胞增生李斯特菌的检测。结果该方法特异性好,对其他菌株无交叉反应。单核细胞增生李斯特菌在10~5~10~8 CFU/m L浓度范围内变化时,电导与菌浓度成线性关系(R^2=0.993),最低检出限为105 CFU/mL。结论该方法具有灵敏度高、检测时间短、特异性好等优点,在食品检测中有较好的应用价值。 展开更多
关键词 微间隙生物芯片 电化信号 银沉淀 双抗夹心
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Digital Filter Algorithm Based on Morphological Lifting Scheme and Median Filter 被引量:2
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作者 Lan Zhang 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2018年第5期1007-1011,共5页
Abstract--When the circuits in which electronic products are fitted are disturbed by various interrupting signals, wave distortions occur to the normal voltage signals of these circuits. These wave distortions influen... Abstract--When the circuits in which electronic products are fitted are disturbed by various interrupting signals, wave distortions occur to the normal voltage signals of these circuits. These wave distortions influence the normal operation and life cycle of electronic products. To eliminate the harmful effects of interrupting signals on electronic products, in this paper, a digital filter algorithm based on morphological lifting scheme and median filter (MLS-MF), which will be used to filter various interrupting signals existing in the circuits in which electronic products are fitted, is proposed. A variety of interrupting sig- nals have been included in simulation studies, and simulation results have demonstrated the effectiveness and feasibility of the proposed digital filter algorithm in high frequency continuous interference, random background noise and damped oscillatory transient interference filter. Index Terms--Digital filter, lifting scheme, median filter, mor- phology. 展开更多
关键词 Digital filter lifting scheme median filter MORPHOLOGY
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Individualization of Data-Segment-Related Parameters for Improvement of EEG Signal Classification in Brain-Computer Interface 被引量:1
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作者 曹红宝 BESIO Walter G +1 位作者 JONES Steven 周鹏 《Transactions of Tianjin University》 EI CAS 2010年第3期235-238,共4页
In electroencephalogram (EEG) modeling techniques, data segment selection is the first and still an important step. The influence of a set of data-segment-related parameters on feature extraction and classification in... In electroencephalogram (EEG) modeling techniques, data segment selection is the first and still an important step. The influence of a set of data-segment-related parameters on feature extraction and classification in an EEG-based brain-computer interface (BCI) was studied. An auto search algorithm was developed to study four datasegment-related parameters in each trial of 12 subjects’ EEG. The length of data segment (LDS), the start position of data (SPD) segment, AR order, and number of trials (NT) were used to build the model. The study showed that, compared with the classification ratio (CR) without parameter selection, the CR was increased by 20% to 30% with proper selection of these data-segment-related parameters, and the optimum parameter values were subject-dependent. This suggests that the data-segment-related parameters should be individualized when building models for BCI. 展开更多
关键词 data segment parameter selection EEG classification brain-computer interface (BCI)
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Application of Holter ECG Signal Analysis Based on Wavelet and Data Mining Technique
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作者 余辉 谢远国 +1 位作者 周仲兴 吕扬生 《Transactions of Tianjin University》 EI CAS 2004年第2期126-129,共4页
A new model based on dyadic differential wavelet was developed for detecting the R peak in Holter ECG signal according to the design of data mining. The Mallat recursive filter algorithm was introduced to calculate wa... A new model based on dyadic differential wavelet was developed for detecting the R peak in Holter ECG signal according to the design of data mining. The Mallat recursive filter algorithm was introduced to calculate wavelet and optimize the detection algorithm which is based on the equivalent filter technique. The detection algorithm has been verified by MIT arrhythmia database with a high efficiency of 99%. After optimization, the algorithm was put into clinical experiment and tested in the Air Force Hospital in Tianjin for about two months. After about 108 hearts beating test of more than 100 patients, the total efficient detection rate has reached 97%. Now this algorithm module has been applied in business software and shows perfect performance under the complex conditions such as the inversion of heart beating, the falling off of the electrodes, the excursion of base line and so on. 展开更多
关键词 WAVELET data mining signal detection ELECTROCARDIOGRAM dyadic wavelet R peak detection
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The Study of the Impact of Mercury Sample Magnetization Prior to Detection by Emission Spectroscopy 被引量:1
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作者 Wameath S. Abdul-Majeed William B. Zimmerman 《Journal of Environmental Science and Engineering(A)》 2012年第3期380-387,共8页
Experimental investigations were conducted in this study to explore the effect of magnetization on water sample properties and to envisage whether the effect is beneficial for mercury detection in a sample of water or... Experimental investigations were conducted in this study to explore the effect of magnetization on water sample properties and to envisage whether the effect is beneficial for mercury detection in a sample of water or not. Subjecting the water sample to 0.3 Tesla magnetic field for 14 hours led to instantaneous effects on the examined water properties, where a reduction in the values of pH (7%) and interfacial tension (0.2%) was observed, whereas an increase (8%) in water electrical conductivity was recorded. Similar behaviours with slight changes in trend were observed after storing the samples for six days, which indicates a creation of permanent effects. Other experiments were conducted to explore the impact of magnetizing water sample containing inorganic mercury prior to detection by emission spectroscopy. Samples were prepared with different mercury concentrations and derivatized by using tin chloride (SnCI2). The generated mercury vapour species were transported with aid of carrier gas into a dielectric barrier discharge plasma atomizer, in which the mercury signal at 253.65 nm was recorded. The results have shown 3.5%-7.5% increase in the signal intensities recorded for the magnetized samples, mostly attributed to a reduction in the sample surface tension and other reasons, which facilitates analyte derivatization. 展开更多
关键词 Water magnetization DBD plasma atomic emission spectroscopy heavy metals.
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Nickel Sulfide/Graphene/Carbon Nanotube Composites as Electrode Material for the Supercapacitor Application in the Sea Flashing Signal System
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作者 Hailong Chen Ji Li +4 位作者 Conglai Long Tong Wei Guoqing Ning Jun Yan Zhuangjun Fan 《Journal of Marine Science and Application》 2014年第4期462-466,共5页
This work presents NiS/graphene/carbon nanotube (NiS/GNS/CNT) composites as electrode material for the supercapacitor application in sea flashing signal systems. NiS nanosheets were closely anchored on the conductiv... This work presents NiS/graphene/carbon nanotube (NiS/GNS/CNT) composites as electrode material for the supercapacitor application in sea flashing signal systems. NiS nanosheets were closely anchored on the conductive GNS-CNT networks. As a result, the NiS/GNS/CNT electrode showed a high specific capacitance of 2 377 F.g^-1 at 2 mV.s^-1 and good cycling stability compared with the pure NiS (1 599F.g^-1). The enhanced electrochemical performances are attributed to the synergetic effect between the conductive carbon and the pseudo-capacitive NiS. The high performance supercapacitor may provide application in the sea flashing signal system. 展开更多
关键词 flashing signal system electrochemical performances NiS/graphene/carbon nanotube composites SUPERCAPACITOR
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Feature extraction of induction motor stator fault based on particle swarm optimization and wavelet packet
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作者 WANG Pan-pan SHI Li-ping +1 位作者 HU Yong-jun MIAO Chang-xin 《Journal of Coal Science & Engineering(China)》 2012年第4期432-437,共6页
To effectively extract the interturn short circuit fault features of induction motor from stator current signal, a novel feature extraction method based on the bare-bones particle swarm optimization (BBPSO) algorith... To effectively extract the interturn short circuit fault features of induction motor from stator current signal, a novel feature extraction method based on the bare-bones particle swarm optimization (BBPSO) algorithm and wavelet packet was proposed. First, according to the maximum inner product between the current signal and the cosine basis functions, this method could precisely estimate the waveform parameters of the fundamental component using the powerful global search capability of the BBPSO, which can eliminate the fundamental component and not affect other harmonic components. Then, the harmonic components of residual current signal were decomposed to a series of frequency bands by wavelet packet to extract the interturn circuit fault features of the induction motor. Finally, the results of simulation and laboratory tests demonstrated the effectiveness of the proposed method. 展开更多
关键词 induction machine stator winding intertum short circuit bare-bones particle swarm optimization feature extraction wavelet packet fault diagnosis
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Seasonal Effect on Atmospheric Refractivity in Diverse Terrains
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作者 Y.O. Olasoji M.O. Kolawole 《Journal of Environmental Science and Engineering》 2011年第11期1537-1541,共5页
Air masses in the atmosphere have contrasting temperature, humidity and moisture, which influence radio signals traversing the atmosphere. The influence of the atmosphere on refractivity is strongly determined by its ... Air masses in the atmosphere have contrasting temperature, humidity and moisture, which influence radio signals traversing the atmosphere. The influence of the atmosphere on refractivity is strongly determined by its temporal and spatial variability. This paper uses meteorological measurements to investigate the impact of meteorological structures on diverse environments evident in Nigeria. The study hypothesises that refractivity measures could serve as indicators of diurnal radio wave degradation traversing the atmosphere. 展开更多
关键词 RADIOSONDE REFRACTIVITY radio signal hydrostatic component Longley-Rice model
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System design of a dexterous lightweight robot arm with remote control
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作者 Li Tian Sun Kui Jiang Zainan Xie Zongwu Liu Hong 《High Technology Letters》 EI CAS 2012年第3期248-255,共8页
This paper presents a novel remote controlled dexterous robot arm with 6 degrees of freedom (DOF). As a highly integrated mechatronics system, sensors and their signal processing system are integrated inside each jo... This paper presents a novel remote controlled dexterous robot arm with 6 degrees of freedom (DOF). As a highly integrated mechatronics system, sensors and their signal processing system are integrated inside each joint. To lighten the weight, almost all mechanical parts are made of aluminum and the robot control system is placed outside. The modular concept is adopted during the robot design process for time and cost saving. Considering the much greater torque acted on the two shoulder joints, the joint shells are strengthened in the design to increase joint stiffness and suppress system vibration. Meanwhile, to simplify the maintenance, a new spring pins electronic connector is designed to disassemble every joint, connector and link independently without cutting any cables. The teleoperation technology enables the robot to offer more convenient service definitely for people' s daily life. Virtual reality technology is used to solve the time delay problem during teleoperation. Finally, two typical daily chore experiments are implemented to prove the manipulation ability of the dexterous robot arm. 展开更多
关键词 dexterous robot arm LIGHTWEIGHT modular joint virtual reality l multisensory ca-pability
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Signal Processing Circuit Design of Infrared Detection System with SO2 Concentration Based on Correlation Filter Technology
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作者 赵雁雨 姚娜 《Journal of Measurement Science and Instrumentation》 CAS 2011年第4期394-397,共4页
Signals from infrared detector are very weak in SO2 concentration measuring system.In order to improve the sensitivity of detection,combining with filter correlation technology and infrared absorption principle,the we... Signals from infrared detector are very weak in SO2 concentration measuring system.In order to improve the sensitivity of detection,combining with filter correlation technology and infrared absorption principle,the weak signal processing circuit is designed according to correlation detection technology.Under laboratory conditions,system performance of SO2 concentration is tested,and the experimental data are analyzed and processed.Then relationship of SO2 concentration and the measuring voltage is provided to prove that the design improves measuring sensitivity of the system. 展开更多
关键词 SO2 infrared absorption correlation detecting and filtering technology weak signal processing
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基于酶催化沉积放大电化学阻抗传感器对三磷酸腺苷的检测 被引量:1
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作者 杨雅妮 刘冰倩 +2 位作者 蔡杰 石维平 曾丹丹 《分析试验室》 CAS CSCD 北大核心 2020年第7期766-771,共6页
基于适配体(t DNA)与目标物的特异性识别,以辣根过氧化物酶(HRP)和单链DNA (ss DNA)修饰的金纳米颗粒(HRP-AuNPs-ssDNA)为电化学信号转导标签,利用酪胺信号放大(TSA)技术构建一种多级信号放大的灵敏检测方法。在优化条件下,三磷酸腺苷(A... 基于适配体(t DNA)与目标物的特异性识别,以辣根过氧化物酶(HRP)和单链DNA (ss DNA)修饰的金纳米颗粒(HRP-AuNPs-ssDNA)为电化学信号转导标签,利用酪胺信号放大(TSA)技术构建一种多级信号放大的灵敏检测方法。在优化条件下,三磷酸腺苷(ATP)浓度在10~50μmol/L范围内,电化学响应与目标物浓度呈良好线性,检出限为1.3μmol/L (3σ)。 展开更多
关键词 适配体 电化信号转导源 三磷酸腺苷 酪胺信号放大
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