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基于分层电化学热耦合模型的锂电池放电过程研究 被引量:1
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作者 时玮 韩甜 +1 位作者 赵杨梅 张雪楠 《电源学报》 CSCD 北大核心 2023年第4期138-147,共10页
软包锂离子电池由许多电池单元叠压形成,其中电池单元的电和热行为对电池的整体安全性有很大的影响。为了研究电池单元与单体之间的关系,采用多孔电极理论建立了大容量软包锂电池的分层多维模型,并考虑了瞬态温度变化与电化学反应间的... 软包锂离子电池由许多电池单元叠压形成,其中电池单元的电和热行为对电池的整体安全性有很大的影响。为了研究电池单元与单体之间的关系,采用多孔电极理论建立了大容量软包锂电池的分层多维模型,并考虑了瞬态温度变化与电化学反应间的相互作用关系。利用该分层模型研究不同温度下电池放电过程中的电化学和热特性,得到更为真实的电池温度场分布。此外,介绍了表征电池单体内不同电池单元荷电状态分布的均匀指数。仿真表明,电池单体内的温度梯度差异加剧了不同电池单元间的过电位不一致和电流密度不一致程度,有利于进一步研究单体电池的衰退演化轨迹。 展开更多
关键词 软包锂离子电池 电化学热耦合模型 电池单元 电化学特性分析 分析
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Formation of greigite under different climate conditions in the Yellow River delta 被引量:1
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作者 WANG YongHong ZHANG WeiGuo +2 位作者 LIU XiuJin LI GuangXue LIU Meng 《Science China Earth Sciences》 SCIE EI CAS CSCD 2015年第2期300-308,共9页
Formation and preservation of greigite can indicate the physicochemical characteristics of sedimentary environment. Presence of greigite can be diagnosed in the late Pleistocene fluvio-lacustrine sedimentary layers of... Formation and preservation of greigite can indicate the physicochemical characteristics of sedimentary environment. Presence of greigite can be diagnosed in the late Pleistocene fluvio-lacustrine sedimentary layers of 29.4–29.7 and 26.1–27.1 m in core ZK30 of the Yellow River delta, based on analysis of particle size, magnetic properties, scanning electron microscope(SEM) and X-ray diffraction(XRD) measurements. These layers are the transition zones from shallow marine facies to fluvio- lacustrine facies, and from fluvio-lacustrine facies to salt marsh facies in an ascending order, respectively. They are characterized by higher SIRM and SIRM/χ(>30 kA m-1) values than those of other layers, suggesting the possible existence of greigite. Both SEM and XRD analyses confirm its presence. However, sediment layer of 29.4–29.7 m are coarser, and greigite coexists with pyrite, but sediment layer of 26.1–27.1 m are finer and the occurrence of greigite is not accompanied by pyrite. The different occurrence of greigite in the two layers suggests that different climate condition and sedimentary environment control its formation and preservation. 展开更多
关键词 delta facies lacustrine sedimentary pyrite Yellow shallow preservation abundant finer
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