基于静电场固溶处理制坯为铝合金时效成形提供了一种新的方法。为评价该工艺的可行性,研究了不同电场强度对2A12铝合金时效成形的影响,探索了在不同固溶电场强度下的时效成形性与普通固溶处理后时效成形的差异,对处理后的2A12铝合金试...基于静电场固溶处理制坯为铝合金时效成形提供了一种新的方法。为评价该工艺的可行性,研究了不同电场强度对2A12铝合金时效成形的影响,探索了在不同固溶电场强度下的时效成形性与普通固溶处理后时效成形的差异,对处理后的2A12铝合金试件进行力学性能测试与显微组织分析。结果表明:电场固溶处理+时效成形对2A12铝合金的组织和性能有一定的影响,较普通固溶处理+时效成形表现出良好的成形性和伸长率;随着电场强度的增加回弹率逐渐降低,韧窝数量增加且尺寸增大;在固溶时施加5.2 k V·cm-1的电场强度可以促进第二相的溶解,导致Cu Al2析出相的比重增大。展开更多
Constructing bismuth oxyhalide solid solutions with a single homogeneous phase have intrigued the research community;however,a deeper understanding of the intrinsic origin for improved bulk-charge separation is still ...Constructing bismuth oxyhalide solid solutions with a single homogeneous phase have intrigued the research community;however,a deeper understanding of the intrinsic origin for improved bulk-charge separation is still unclear.Herein,a series of Bi_(24)O_(31)Cl_(x)Br_(10-x) solid solutions with the same structural characteristics were synthesized by crystal structure regulation.Combining density functional theory calculation,Kelvin probe force microscopy,and zeta potential testing results,an enhanced internal electric field(IEF)intensity between[Bi_(24)O_(31)]and[X]layers was achieved by changing halogen types and ratios.This greatly facilitated bulk-charge separation and transfer efficiency,which is significant for the degradation of phenolic organic pollutants.Owing to the enhanced IEF intensity,the charge carrier density of Bi_(24)O_(31)Cl_(4)Br_(6) was 33.1 and 4.7 times stronger than that of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Therefore,Bi24O31Cl4Br6 had an optimal photoactivity for the degradation of bisphenol A,which was 6.21 and 2.71 times higher than those of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Thus,this study revealed the intrinsic mechanism of the solid solution strategy for photocatalytic performance enhancement with respect to an IEF.展开更多
文摘基于静电场固溶处理制坯为铝合金时效成形提供了一种新的方法。为评价该工艺的可行性,研究了不同电场强度对2A12铝合金时效成形的影响,探索了在不同固溶电场强度下的时效成形性与普通固溶处理后时效成形的差异,对处理后的2A12铝合金试件进行力学性能测试与显微组织分析。结果表明:电场固溶处理+时效成形对2A12铝合金的组织和性能有一定的影响,较普通固溶处理+时效成形表现出良好的成形性和伸长率;随着电场强度的增加回弹率逐渐降低,韧窝数量增加且尺寸增大;在固溶时施加5.2 k V·cm-1的电场强度可以促进第二相的溶解,导致Cu Al2析出相的比重增大。
文摘Constructing bismuth oxyhalide solid solutions with a single homogeneous phase have intrigued the research community;however,a deeper understanding of the intrinsic origin for improved bulk-charge separation is still unclear.Herein,a series of Bi_(24)O_(31)Cl_(x)Br_(10-x) solid solutions with the same structural characteristics were synthesized by crystal structure regulation.Combining density functional theory calculation,Kelvin probe force microscopy,and zeta potential testing results,an enhanced internal electric field(IEF)intensity between[Bi_(24)O_(31)]and[X]layers was achieved by changing halogen types and ratios.This greatly facilitated bulk-charge separation and transfer efficiency,which is significant for the degradation of phenolic organic pollutants.Owing to the enhanced IEF intensity,the charge carrier density of Bi_(24)O_(31)Cl_(4)Br_(6) was 33.1 and 4.7 times stronger than that of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Therefore,Bi24O31Cl4Br6 had an optimal photoactivity for the degradation of bisphenol A,which was 6.21 and 2.71 times higher than those of Bi_(24)O_(31)Cl_(10) and Bi_(24)O_(31)Br_(10),respectively.Thus,this study revealed the intrinsic mechanism of the solid solution strategy for photocatalytic performance enhancement with respect to an IEF.