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电化学双石英晶体阻抗分析新方法
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作者 谢青季 张友玉 +3 位作者 杨晓辉 李萌 何红梅 姚守拙 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2003年第10期1790-1792,共3页
A novel method for simultaneous impedance analyses of two resonating piezoelectric quartz crystals is proposed via the admittance measurements of two crystals in parallel and then nonlinear admittance fitting to an eq... A novel method for simultaneous impedance analyses of two resonating piezoelectric quartz crystals is proposed via the admittance measurements of two crystals in parallel and then nonlinear admittance fitting to an equivalent circuit of two Butterworth-Van Dyke circuits in parallel. Series of sucrose aqueous solutions and copper electro-deposition/stripping in a NH 3-(NH 4) 2SO 4 buffer were used to test this method, giving that the impedance parameters of each of the parallel crystals reflecting the solution density-viscosity effect or the mass effect were very close to those measured with each single crystal alone. Also, simultaneous impedance measurements at the working and counter electrodes were carried out and discussed. 展开更多
关键词 电化学 双石英晶体 电声阻抗分析 电流响应 化学分析
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