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Preparation, characterization, and catalytic performance of high efficient CeO_2-MnO_x-Al_2O_3 catalysts for NO elimination 被引量:9
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作者 姚小江 李露露 +5 位作者 邹伟欣 虞硕涵 安继斌 李红丽 杨复沫 董林 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第8期1369-1380,共12页
A series of CeO2‐MnOx‐Al2O3 mixed oxide catalysts (Ce:Mn:Al mole ratio=6:4:x, x=0.25, 0.5, 1, 2) were prepared by a simple one‐step inverse co‐precipitation method to investigate the influence of the incorpo... A series of CeO2‐MnOx‐Al2O3 mixed oxide catalysts (Ce:Mn:Al mole ratio=6:4:x, x=0.25, 0.5, 1, 2) were prepared by a simple one‐step inverse co‐precipitation method to investigate the influence of the incorporation of Al3+ into CeO2‐MnOx mixed oxides. CeO2‐MnOx, CeO2‐Al2O3, and MnOx‐Al2O3 mixed oxides, and CeO2 were prepared by the same method for comparison. The samples were characterized by XRD, Raman, N2 physisorption, H2‐TPR, XPS, and in situ DRIFTS. The catalytic re‐duction of NO by CO was chosen as a model reaction to evaluate the catalytic performance. The incorporation of a small amount of Al3+into CeO2‐MnOx mixed oxides resulted in a decrease of crys‐tallite size, with the increase of the BET specific surface area and pore volume, as well as the in‐crease of Ce3+and Mn4+. The former benefits good contact between catalyst and reactants, and the latter promotes the adsorption of CO and the desorption, conversion and dissociation of adsorbed NO. All these enhanced the catalytic performance for the NO+CO model reaction. A reaction mecha‐nism was proposed to explain the excellent catalytic performance of CeO2‐MnOx‐Al2O3 catalysts for NO reduction by CO. 展开更多
关键词 Ceria-based mixed oxide Incorporation Electron interaction Adsorption property NO elimination
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国际建筑行业科学研究的六大趋势
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作者 陆伟成 《上海市建设职工大学学报(当代建设)》 1998年第2期46-47,共2页
本文对直接影响建筑研究管理的若干国际趋势作一番分析,是根据笔者任CIB秘书长的经历写就的向国际建筑研究与文献委员会(CIB)会议提交的一份报告。CIB作为一个协会,其目标是为了激励和促进国际建筑行业的研究、技术开发、文献交流等方... 本文对直接影响建筑研究管理的若干国际趋势作一番分析,是根据笔者任CIB秘书长的经历写就的向国际建筑研究与文献委员会(CIB)会议提交的一份报告。CIB作为一个协会,其目标是为了激励和促进国际建筑行业的研究、技术开发、文献交流等方面的合作与信息交流。CIB是世界范围研究部门、产业部门。 展开更多
关键词 国际建筑行业 科研机构 建筑市场 发展趋势 电子化合作
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Iron-based binary metal-organic framework nanorods as an efficient catalyst for the oxygen evolution reaction 被引量:2
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作者 Chuchu Wu Xiaoming Zhang +4 位作者 Huanqiao Li Zhangxun Xia Shansheng Yu Suli Wang Gongquan Sun 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第4期637-647,共11页
First-row transition metal compounds have been widely explored as oxygen evolution reaction(OER)electrocatalysts due to their impressive performance in this application.However,the activity trends of these electrocata... First-row transition metal compounds have been widely explored as oxygen evolution reaction(OER)electrocatalysts due to their impressive performance in this application.However,the activity trends of these electrocatalysts remain elusive due to the effect of inevitable iron impurities in alkaline electrolytes on the OER;the inhomogeneous structure of iron-based(oxy)hydroxides further complicates this situation.Bimetallic metal-organic frameworks(MOFs)have the advantages of well-defined and uniform atomic structures and the tunable coordination environments,allowing the structure-activity relationships of bimetallic sites to be precisely explored.Therefore,we prepared a series of iron-based bimetallic MOFs(denoted as Fe_(2)M-MIL-88B,M=Mn,Co,or Ni)and systematically compared their electrocatalytic performance in the OER in this work.All the bimetallic MOFs exhibited higher OER activity than their monometallic iron-based counterpart,with their activity following the order FeNi>FeCo>FeMn.In an alkaline electrolyte,Fe2Ni-MIL-88B showed the lowest overpotential to achieve a current density of 10 mA cm^(–2)(307 mV)and the smallest Tafel slope(38 mV dec^(–1)).The experimental and calculated results demonstrated that iron and nickel exhibited the strongest coupling effect in the series,leading to modification of the electronic structure,which is crucial for tuning the electrocatalytic activity. 展开更多
关键词 Oxygen evolution reaction Metal-organic frameworks ELECTROCATALYSIS Electronic coupling effect Water oxidation
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Synthesis and electrochemical properties of SnO_2-polyaniline composite 被引量:1
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作者 何则强 熊利芝 +3 位作者 刘文萍 吴显明 陈上 黄可龙 《Journal of Central South University of Technology》 2008年第2期214-217,共4页
The SnO2-polyaniline(SnO2-PAn) composite was prepared by microemulsion polymerization method using aniline,ammonium peroxodisulfate and SnO2 as starting materials.The SnO2-PAn composite was characterized by X-ray diff... The SnO2-polyaniline(SnO2-PAn) composite was prepared by microemulsion polymerization method using aniline,ammonium peroxodisulfate and SnO2 as starting materials.The SnO2-PAn composite was characterized by X-ray diffractometer,scanning electron microscope and electrochemical techniques.The results show that PAn in the composites is amorphous.PAn formed in the reaction is deposited preferentially on the SnO2 particles,giving a SnO2-PAn composite,in which SnO2 is coated with PAn.SnO2-PAn composite shows a reversible capacity of 657.6 mA·h/g and the capacity loss per cycle is only 0.092% after 80 cycles,suggesting that SnO2-PAn composite is a promising anode material for lithium ion batteries. 展开更多
关键词 lithium ion battery SYNTHESIS electrochemical properties microemulsion polymerization method SNO2 POLYANILINE
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Comparative transcriptomic insights into the mechanisms of electron transfer in Geobacter co-cultures with activated carbon and magnetite 被引量:2
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作者 Shiling Zheng Fanghua Liu +2 位作者 Meng Li Leilei Xiao Oumei Wang 《Science China(Life Sciences)》 SCIE CAS CSCD 2018年第7期787-798,共12页
Both activated carbon and magnetite have been reported to promote the syntrophic growth of Geobacter metallireducens and Geobacter sulfurreducens co-cultures, the first model to show direct interspecies electron trans... Both activated carbon and magnetite have been reported to promote the syntrophic growth of Geobacter metallireducens and Geobacter sulfurreducens co-cultures, the first model to show direct interspecies electron transfer (DIET); however, differential transcriptomics of the promotion on co-cultures with these two conductive materials are unknown. Here, the comparative transcriptomic analysis of G. metallireducens and G. sulfurreducens co-cultures with granular activated carbon (GAC) and magnetite was reported. More than 2.6-fold reduced transcript abundances were determined for the uptake hydrogenase genes of G. sulfurreducens as well as other hydrogenases in those co-cultures to which conductive materials had been added. This is consistent with electron transfer in G. metallireducens-G. sulfurreducens co-cultures as evinced by direct interspecies electron transfer (DIET). Transcript abundance for the structural component of electrically conductive pili (e-pili), PilA, was 2.2-fold higher in G. metallireducens, and, in contrast, was 14.9-fold lower in G. sulfurreducens in co-cultures with GAC than in Geobacters co-cultures without GAC. However, it was 9.3-fold higher in G. sulfurreducens in co-cultures with magnetite than in Geobacters co-cultures. Mutation results showed that GAC can be substituted for the e-pili of both strains but magnetite can only compensate for that of G. sulfurreducens, indicating that the e-pili is a more important electron acceptor for the electron donor strain of G. metallireducens than for G. sulfurreducens. Transcript abundance for G. metallireducens c-type cytochrome gene GMET_RS14535, a homologue to c-type cytochrome gene omcE of G. sulfurreducens was 9.8-fold lower in co-cultures with GAC addition, while that for OmcS of G. sulfurreducens was 25.1-fold higher in co-cultures with magnetite, than in that without magnetite. Gene deletion studies showed that neither GAC nor magnetite can completely substitute the cytochrome (OmcE homologous) of G. metallireducens but compensate for the cytochrome (OmcS) of G. sulfurreducens. Moreover, some genes associated with central metabolism were up-regulated in the presence of both GAC and magnetite; however, tricarboxylic acid cycle gene transcripts in G. sulfurreducens were not highly-expressed in each of these amended co-cultures, suggesting that there was considerable redundancy in the pathways utilised by G. sulfurreducens for electron transfer to reduce fumarate with the amendment of GAC or magnetite. These results support the DIET model of G. metallireducens and G. sulfurreducens and suggest that e-pili and cytochromes of the electron donor strain are more important than that of the electron acceptor strain, indicating that comparative transcriptomics may be a promising route by which to reveal different responses of electron donor and acceptor during DIET in co-cultures. 展开更多
关键词 comparative transcriptomics GEOBACTER direct interspecies electron transfer(DIET) activated carbon MAGNETITE
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Optical and magnetic properties of transition-metal ions in tetrahedral and octahedral compounds 被引量:1
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作者 LI HuiFang WANG HuaiQian KUANG XiaoYu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第10期1796-1800,共5页
This paper presents the complete energy matrix of the 3d2system containing the electron-electron interaction, the ligand-fieldinteraction, the spin-orbit coupling interaction, and the Zeeman interaction, in which the ... This paper presents the complete energy matrix of the 3d2system containing the electron-electron interaction, the ligand-fieldinteraction, the spin-orbit coupling interaction, and the Zeeman interaction, in which the optical spectra and g-factor of V3+andTi2+ions in the series of tetrahedral AIIBVI(AII=Zn, Cd, BVI=S, Se, Te) semiconductor materials are determined. In the inves-tigation of the optical and magnetic properties of these transition-metal ions in the tetrahedral coordination complexes, wecompared the data obtained from the transition-metal ions in the tetrahedral coordination complexes with those obtained fromthe corresponding ions in the octahedral ones, and found that the tetrahedral complexes have weaker crystal-field strength, in-verse energy level ordering and stronger covalence effect. 展开更多
关键词 EPR and optical spectra complete energy matrix ligand-field theory tetrahedral coordination complexes octahedralcomplexes transition-metal ions
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