The oil solubility of synthetic oleic acid tris-(2-hydroxyethyl) isocyanurate phosphate ester(abbreviated as OHTP hereinafter) and its influence on the biodegradability and tribological performance of 400 SN mineral o...The oil solubility of synthetic oleic acid tris-(2-hydroxyethyl) isocyanurate phosphate ester(abbreviated as OHTP hereinafter) and its influence on the biodegradability and tribological performance of 400 SN mineral oil were investigated on a tester and a four-ball tribotester,respectively,for fast evaluating the biodegradability of lubricants.Furthermore,the morphologies and tribochemical species of the worn surfaces lubricated by OHTP-doped oil were studied by scanning electron microscope(SEM) and X-ray photoelectron spectroscope(XPS).The results indicated that OHTP possessed good oil solubility and could improve obviously the biodegradability,the extreme pressure properties,the anti-wear properties and friction-reducing properties of the 400 SN mineral oil.The analytical results of XPS spectra showed that the composite boundary lubrication films were mainly composed of absorbed films and tribochemical species such as FePO-4,Fe_3(PO_4)_2,Fe_2O_3 and Fe_3O_4,which contributed to improving the tribological performances.展开更多
To determine the ash characteristics during fluidized bed combustion and gasification purposes, the investigation of the impacts of chemical composition of Jincheng coal ash on the sintering temperature was conducted....To determine the ash characteristics during fluidized bed combustion and gasification purposes, the investigation of the impacts of chemical composition of Jincheng coal ash on the sintering temperature was conducted. A series of experiments on the sintering behavior at 0.5 MPa was performed using the pressurized pressure-drop technique in the combustion and gasification atmospheres. Meanwhile, the mineral transformations of sintered ash pellets were observed using X-ray diffractometer (XRD) analyzer to better understand the experimental results. In addition, quantitative XRD and field emission scanning electron microscope/energy dispersive X-ray spectrometer (FE-SEM/EDS) analyses of ash samples were used for clarifying the detailed ash melting mechanism. These results show that the addition of Fe203 can obviously reduce the sintering temperatures under gasification atmospheres, and only affect a little the sintering temperature under combustion atmosphere. This may be due to the presence of iron-bearing minerals, which will react with other ash compositions to produce low-melting-point eutectics. The FE-SEM/EDS analyses of ash samples with Fe203 additive show consistent results with the XRD measurements. The CaO and Na20 can reduce the sintering temperatures under both the combustion and gasification atmospheres. This can be also contributed to the formation of low-melting-point eutectics, decreasing the sintering temperature. Moreover, the fluxing minerals, such as magnetite, anhydrite, muscovite, albite and nepheline, contribute mostly to the reduction of the sintering temperature while the feldspar minerals, such as anorthite, gehlenite and sanidine, can react with other minerals to produce low-melting-point eutectics, and thereby reduce the sintering temperatures.展开更多
基金the financial support from the National Defense Science Technology Foundation (Project No.3604003)the National Natural Science Foundation of China (Project No.51375491)+1 种基金the Natural Science Foundation of Chongqing (Project No.CSTC,2014JCYJAA50021)the Natural Science Foundation of Chongqing (Project No.cstc2017jcyj AX0058)
文摘The oil solubility of synthetic oleic acid tris-(2-hydroxyethyl) isocyanurate phosphate ester(abbreviated as OHTP hereinafter) and its influence on the biodegradability and tribological performance of 400 SN mineral oil were investigated on a tester and a four-ball tribotester,respectively,for fast evaluating the biodegradability of lubricants.Furthermore,the morphologies and tribochemical species of the worn surfaces lubricated by OHTP-doped oil were studied by scanning electron microscope(SEM) and X-ray photoelectron spectroscope(XPS).The results indicated that OHTP possessed good oil solubility and could improve obviously the biodegradability,the extreme pressure properties,the anti-wear properties and friction-reducing properties of the 400 SN mineral oil.The analytical results of XPS spectra showed that the composite boundary lubrication films were mainly composed of absorbed films and tribochemical species such as FePO-4,Fe_3(PO_4)_2,Fe_2O_3 and Fe_3O_4,which contributed to improving the tribological performances.
基金Project (No. 2011DFA72730-202) supported by the Research Project of US-China Clean Energy Research Center
文摘To determine the ash characteristics during fluidized bed combustion and gasification purposes, the investigation of the impacts of chemical composition of Jincheng coal ash on the sintering temperature was conducted. A series of experiments on the sintering behavior at 0.5 MPa was performed using the pressurized pressure-drop technique in the combustion and gasification atmospheres. Meanwhile, the mineral transformations of sintered ash pellets were observed using X-ray diffractometer (XRD) analyzer to better understand the experimental results. In addition, quantitative XRD and field emission scanning electron microscope/energy dispersive X-ray spectrometer (FE-SEM/EDS) analyses of ash samples were used for clarifying the detailed ash melting mechanism. These results show that the addition of Fe203 can obviously reduce the sintering temperatures under gasification atmospheres, and only affect a little the sintering temperature under combustion atmosphere. This may be due to the presence of iron-bearing minerals, which will react with other ash compositions to produce low-melting-point eutectics. The FE-SEM/EDS analyses of ash samples with Fe203 additive show consistent results with the XRD measurements. The CaO and Na20 can reduce the sintering temperatures under both the combustion and gasification atmospheres. This can be also contributed to the formation of low-melting-point eutectics, decreasing the sintering temperature. Moreover, the fluxing minerals, such as magnetite, anhydrite, muscovite, albite and nepheline, contribute mostly to the reduction of the sintering temperature while the feldspar minerals, such as anorthite, gehlenite and sanidine, can react with other minerals to produce low-melting-point eutectics, and thereby reduce the sintering temperatures.