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NO_2分子在440~495nm范围内的激光诱导荧光激发谱 被引量:4
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作者 张贵银 张连水 +1 位作者 孙博 韩晓峰 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2005年第6期854-856,共3页
以Nd :YAG脉冲激光器泵浦的光学参量发生器 放大器作激发光源,获得了室温、低气压条件下,NO2 分子在4 4 0~4 95nm波长范围内的激光诱导荧光激发谱,将所得谱线峰归属为NO2 由基电子态X2 A1 态向第二电子激发态B2 B1 态的跃迁,利用实验... 以Nd :YAG脉冲激光器泵浦的光学参量发生器 放大器作激发光源,获得了室温、低气压条件下,NO2 分子在4 4 0~4 95nm波长范围内的激光诱导荧光激发谱,将所得谱线峰归属为NO2 由基电子态X2 A1 态向第二电子激发态B2 B1 态的跃迁,利用实验所得峰值波长计算了NO2 分子B2 B1 态的角振动频率ωe。通过对NO2 分子B2 B1 →X2 A1 跃迁的荧光时间分辨光谱进行实验研究,得到15Pa气压下B2 B1 (0 ,9,0 )振动态的能级寿命τ=4 9μs。测量了荧光寿命随气压的变化关系,利用曲线拟合得到NO2 B2 B1 (0 ,9,0 )振动态的自发辐射寿命τ0 ≈5 5 μs和无辐射跃迁弛豫速率常数。kq=1 2×10 - 9cm3molecule- 1 s- 1 。 展开更多
关键词 NO2分子 激光诱导荧光激发谱 电子振动态 自发辐射寿命
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New Way to Quantize Time-Dependent RLC Electric Circuit and Quantum Fluctuations
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作者 梁麦林 袁兵 赵林 《Transactions of Tianjin University》 EI CAS 2002年第1期8-11,共4页
According to the physical mechanism of the generation of the resistance or the electron phonon interaction, a new method is proposed to quantize the RLC electric circuit. Calculations show that the quantum fluctuatio... According to the physical mechanism of the generation of the resistance or the electron phonon interaction, a new method is proposed to quantize the RLC electric circuit. Calculations show that the quantum fluctuations under this new quantization are smaller than those by the traditional effective Hamiltonian method. And squeezed states can be generated if the inductance and capacity are time dependent. Meanwhile, the shortcoming of the traditional method that the electric charge and current will vanish in the long time limit is overcome. 展开更多
关键词 RLC electric circuit lattice oscillation quantum fluctuation squeezed state
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Two Schemes for Generation of Entanglement for Vibronic Collective States of Multiple Trapped Ions
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作者 YANG Wen-Xing LI Jia-Hua ZHNG An-Shou 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第3期421-426,共6页
We propose two schemes to prepare entanglement for the vibronic collective states of multiple trapped ions. The first scheme aims to generating multipartite entanglement for vibrational modes of trapped ions, which on... We propose two schemes to prepare entanglement for the vibronic collective states of multiple trapped ions. The first scheme aims to generating multipartite entanglement for vibrational modes of trapped ions, which only requires a single laser beam tuned to the ionic carrier frequency. Our scheme works in the mediated excitation regime, in which the corresponding Rabi frequency is equal to the trap frequency. Beyond their fundamental importance, these states may be of interest for experimental studies on decoherence since the present scheme operates in a fast way. The second scheme aims to preparing the continuous variable multimode maximal1y Greenberger-Horne-Zeilinger state. The distinct advantage is that the operation time is only limited by the available laser intensity, not by the inherent mechanisms such as off-resonant excitations. This makes it promising to obtain entanglernent of multiple coherent and squeezing states with desired amplitudes in a reasonable time. 展开更多
关键词 multipartite entanglement GHZ state trapped ions
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Structural, Spectroscopic and Vibrational Properties for Low-Lying Electronic States of LiCl
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作者 曹耀峰 高玉峰 高涛 《Communications in Theoretical Physics》 SCIE CAS CSCD 2013年第11期593-600,共8页
A multireference configuration interaction (MRCI) study has been carried out on the LiCl molecule. The potential energy has been calculated over a wide range of internuclear separation for the 21 low-lying electroni... A multireference configuration interaction (MRCI) study has been carried out on the LiCl molecule. The potential energy has been calculated over a wide range of internuclear separation for the 21 low-lying electronic states of the LiCl molecule dissociating into Li (^2S, ^2p, ^3S)+Cl (^2p). The (4)^1∑^+, (3)∏, 1-3^3∑^+, 1-3^3∏, 1,3Δ, ^1,3∑^-, (5)^1∑^+,(4)^3∑^+, (4)^3∏, (4)^3∏ excited states are studied for the first time in theory. Molecular spectroscopic constants .(Re, De,ωe, ωeΧe,Be and αe) have been derived for the 9 bound states (X^1∑^+, (3)^1∑^+, (2)^3∑^+, ^1,3Δ, ^1,3∑^-, (4)^∏, (4)^3∏) with a regular shape, and the spectroscopic constants of ground states X^1 ∑^+ are in good agreement with available experimental and theoretical values. The relative differences between experimental values and our values for Re, De, ωe, ωeΧe, Be and α3 are 1.02%, 0.60%, 1.72%, 9.46%, 2.0%, and 0.75%, respectively. Moreover, vibrational levels of 9 bound states, which have not been investigated experimentally, are computed. 展开更多
关键词 multireference configuration interaction (MRCI) low-lying excited states LiCl molecule molecular Constant vibrational level
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Coupling Distant Spins of Surface-State Electrons by Manipulating Their Collective Vibrations 被引量:1
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作者 曾勇 张淼 韦联福 《Communications in Theoretical Physics》 SCIE CAS CSCD 2014年第1期131-134,共4页
The system of electrons on liquid helium is an interesting candidate to implement quantum computation, due to the long coherence times of the qubits encoded by the electronic spins. In order to implement the quantum l... The system of electrons on liquid helium is an interesting candidate to implement quantum computation, due to the long coherence times of the qubits encoded by the electronic spins. In order to implement the quantum logic operations between the spins, we propose here a configuration, similarly to the cooled ions in a trap, to couple the distant electrons via manipulating their center of mass (CM) vibrations. First, we show that the electrons could be confined in a common harmonic oscillator potential by using an electrostatic field. Then, with a single current pulse (applied on the micro-electrode below the liquid helium) the distant electronic spins can be coupled simultaneously to the CM mode. Finally, by adiabatically eliminating the CM mode, effective interaction between the distant spins is induced for implementing the desired quantum computing. 展开更多
关键词 electrons on liquid helium spin-orbit coupling collective vibrations
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