The photodissociation dynamics of acetaldehyde in the radical channel CH3＋HCO has been reinvestigated using time-sliced velocity map imaging technique in the photolysis wavelength range of 275-321 nm. The CH3 fragmen...The photodissociation dynamics of acetaldehyde in the radical channel CH3＋HCO has been reinvestigated using time-sliced velocity map imaging technique in the photolysis wavelength range of 275-321 nm. The CH3 fragments have been probed via （2＋1） resonance-enhanced multiphoton ionization. Images are measured for CH3 formed in the ground and excited states （v2=0 and 1） of the umbrella vibrational mode. For acetaldehyde dissociation on T1 state after intersystem crossing from S1 state, the products are formed with high translational energy release and low internal excitation. The rotational and vibrational energy of both fragments increases with increasing photodissociation energy. The triplet barrier height is estimated at 3.8814-0.006 eV above the ground state of acetaldehyde.展开更多
A design of coating on the entrance surface of the beam splitters with a transparent thin film of certain refractive index and thickness was presented.For this kind of beam splitters,it was possible to realize polariz...A design of coating on the entrance surface of the beam splitters with a transparent thin film of certain refractive index and thickness was presented.For this kind of beam splitters,it was possible to realize polarization-independent beam-splitting for chosen wavelength λ with incident angle .In addition,the simulation results using the coating designable software(Auto film) were consistent with the theoretical results,and the beam splitters are not sensitive to the small errors of film-thickness and film refractive-index over a broad spectra.展开更多
This work was synthesized CaAl2O4 （calcium aluminate） doped with trivalent praseodymium ions. CaAl2O4 with praseodymium 1.0% and 0.5% were synthesized. The powders of aluminates were characterized by scanning electr...This work was synthesized CaAl2O4 （calcium aluminate） doped with trivalent praseodymium ions. CaAl2O4 with praseodymium 1.0% and 0.5% were synthesized. The powders of aluminates were characterized by scanning electron microscopy and luminescence spectrofluorimetry.CaAl2O4, praseodymium ions, luminescence doped with praseodymium ion that showed less porosity in its grain structure and luminescent transitions that are dependent on the wavelengths of excitation and showing both types of transitions both 5d-4f and 4f-4f.展开更多
The ability to generate stable and coherent short wavelength radiation is a great promise of the externally seeded free-electron laser. However, the fre- quency up-conversion efficiency is limited to a small number in...The ability to generate stable and coherent short wavelength radiation is a great promise of the externally seeded free-electron laser. However, the fre- quency up-conversion efficiency is limited to a small number in a single stage setup. In this paper, we propose a new scheme to produce coherent hard X-ray FEL with two- beam based two-stage echo-enabled harmonic generation configuration. Electron beams with quite different proper- ties are separately used in each stage and a monochromator is adopted to purify the radiation from first stage for seeding the second stage. Three-dimensional start-to-end simulations have been performed with realistic parameters to show the feasibility of the proposed scheme.展开更多
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.21203186 and No.21073187）, the National Key Basic Research Program of China （No.2010CB923302）, 100 Talents Program of Chinese Academy of Sciences, and Knowledge Innovation Program of Chinese Academy of Sciences.
文摘The photodissociation dynamics of acetaldehyde in the radical channel CH3＋HCO has been reinvestigated using time-sliced velocity map imaging technique in the photolysis wavelength range of 275-321 nm. The CH3 fragments have been probed via （2＋1） resonance-enhanced multiphoton ionization. Images are measured for CH3 formed in the ground and excited states （v2=0 and 1） of the umbrella vibrational mode. For acetaldehyde dissociation on T1 state after intersystem crossing from S1 state, the products are formed with high translational energy release and low internal excitation. The rotational and vibrational energy of both fragments increases with increasing photodissociation energy. The triplet barrier height is estimated at 3.8814-0.006 eV above the ground state of acetaldehyde.
文摘A design of coating on the entrance surface of the beam splitters with a transparent thin film of certain refractive index and thickness was presented.For this kind of beam splitters,it was possible to realize polarization-independent beam-splitting for chosen wavelength λ with incident angle .In addition,the simulation results using the coating designable software(Auto film) were consistent with the theoretical results,and the beam splitters are not sensitive to the small errors of film-thickness and film refractive-index over a broad spectra.
文摘This work was synthesized CaAl2O4 （calcium aluminate） doped with trivalent praseodymium ions. CaAl2O4 with praseodymium 1.0% and 0.5% were synthesized. The powders of aluminates were characterized by scanning electron microscopy and luminescence spectrofluorimetry.CaAl2O4, praseodymium ions, luminescence doped with praseodymium ion that showed less porosity in its grain structure and luminescent transitions that are dependent on the wavelengths of excitation and showing both types of transitions both 5d-4f and 4f-4f.
基金supported by the National Development and Reform Commission([2013]2347)National Natural Science Foundation of China(11475250)the Shanghai Natural Science Foundation(13ZR1464700)
文摘The ability to generate stable and coherent short wavelength radiation is a great promise of the externally seeded free-electron laser. However, the fre- quency up-conversion efficiency is limited to a small number in a single stage setup. In this paper, we propose a new scheme to produce coherent hard X-ray FEL with two- beam based two-stage echo-enabled harmonic generation configuration. Electron beams with quite different proper- ties are separately used in each stage and a monochromator is adopted to purify the radiation from first stage for seeding the second stage. Three-dimensional start-to-end simulations have been performed with realistic parameters to show the feasibility of the proposed scheme.
