TiO2 films were formed on metallic titanium substrates by the anodic oxidation method in H2SO4 solution under the 80V D.C..Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning ...TiO2 films were formed on metallic titanium substrates by the anodic oxidation method in H2SO4 solution under the 80V D.C..Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions.Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves.The result showed that the TiO2 film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface.The average water contact angle of the film was 116.4? in dark, in contrast to an angle of 42.7? under the UV illumination for 2 hours, which demonstrates good hydrophobic property.The anti-corrosion behavior of the TiO2 film was declining with the extended immersion time.Under dark conditions, however, the hydrophobic TiO2 film retarded the water infiltrating into the substrate.The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight.All of those mentioned above indicate that the TiO2 film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.展开更多
This paper sets up a complete CO2 contact angle test system by a visualization autoclave, uses the hanging drop-method respectively getting the advancing angle and receding angle of CO2, on the shale surface under the...This paper sets up a complete CO2 contact angle test system by a visualization autoclave, uses the hanging drop-method respectively getting the advancing angle and receding angle of CO2, on the shale surface under the different temperature, and uses the Snake method measuring contact angle of droplet images, to make the wettability experimental study for CO2 on the shale surface. According to contact angle data, wettability of CO2 on the shale surface is preferable; the temperature is the higher, the wettability is better. At the same time, by analyzing correspondingly with scanning electron microscope images of shale sample, it is obtained that shale with different surface structures has affected wettability of CO2.展开更多
文摘TiO2 films were formed on metallic titanium substrates by the anodic oxidation method in H2SO4 solution under the 80V D.C..Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions.Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves.The result showed that the TiO2 film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface.The average water contact angle of the film was 116.4? in dark, in contrast to an angle of 42.7? under the UV illumination for 2 hours, which demonstrates good hydrophobic property.The anti-corrosion behavior of the TiO2 film was declining with the extended immersion time.Under dark conditions, however, the hydrophobic TiO2 film retarded the water infiltrating into the substrate.The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight.All of those mentioned above indicate that the TiO2 film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.
基金Fund project： This Paper is funded by the National Natural Science Foundation of China （NO. 51076170）.
文摘This paper sets up a complete CO2 contact angle test system by a visualization autoclave, uses the hanging drop-method respectively getting the advancing angle and receding angle of CO2, on the shale surface under the different temperature, and uses the Snake method measuring contact angle of droplet images, to make the wettability experimental study for CO2 on the shale surface. According to contact angle data, wettability of CO2 on the shale surface is preferable; the temperature is the higher, the wettability is better. At the same time, by analyzing correspondingly with scanning electron microscope images of shale sample, it is obtained that shale with different surface structures has affected wettability of CO2.
