CoO（100）表面高分辩电子能损失谱与量子化学的从头算

ＣｏＯ（１００）表面高分辩电子能损失谱与量子化学的从头算石守衡（大连轻工业学院基础部物理化学教研室，大连，１１６０３４）关键词ＣｏＯ（１００）表面，高分辩电子能损失谱，从头算Ａ．Ｆｒｅｉｔａｇ等［１］用高辩电子能损失谱研究了ＮｉＯ（１００）表面的电子...

Beryllium-distribution in metallic glass matrix composite containing beryllium

The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites （MGMCs） containing beryllium （Be） with the nominal composition of Tia7Zr19Cu5V12Be17 （mole fraction, %） were investigated using XRD, SEM, EBSD, TEM, EDS and three-dimensional reconstruction method. Moreover, visualized at the nanoscale, Be distribution is confirmed to be only present in the matrix using scanning transmission electron microscopy-electron energy loss spectroscopy （STEM-EELS）. Based on these findings, it has been obtained that the accurate chemical compositions are Wi28.3Zr19.7Cu8V6.4Be37.6 （mole fraction, %） for glass matrix and Wi62.nZr18.aCu2.6V16.6 （mole fraction, %） for the dendritic phases, and the volume fractions are 38.5% and 61.5%, respectively. It is believed that the results are of particular importance for the designing of Be-containing MGMCs.

Comparative Investigation of Mo（CO）6 Adsorption on Clean and OxidiZed Si（111） Surfaces

Mo（CO）6 adsorption on the clean, oxygen-precovered and deeply oxidized Si（lll） surfaces was comparatively investigated by high-resolution electron energy loss spectroscopy. The downward vibrational frequency shift of the C-O stretching mode in adsorbed Mo（CO）6 illustrates that different interactions of adsorbed Mo（CO）6 occur on clean Si（111） and SiO2/Si（111） surfaces, weak on the former and strong on the latter. The strong interaction on SiO2/Si（111） might lead to the partial dissociation of Mo（CO）6, consequently the formation of molybdenum subcarbonyls. Therefore, employing Mo（CO）6 as the precursor, metallic molybdenum could be successfully deposited on the SiO2/Si（111） surface but not on the clean Si（111） surface. A portion of the deposited metallic molybdenum is transformed into the MoOa on the SiO2/Si（111） surface upon heating, and the evolved MoO3 finally desorbs from the substrate upon annealing at elevated temperatures.

Direct View of Cr Atoms Doped in Anatase TiO2（001） Thin Film

Imaging the doping elements is doped TiO2 thin film. But it is critical for understanding the photocatalytic activity of still a challenge to characterize the interactions between the dopants and the TiO2 lattice at the atomic level. Here, we use high angle annular dark- field/annular bright-field scanning transmission electron microscope （HAADF/ABF-STEM） combined with electron energy loss spectroscopy （EELS） to directly image the individual Cr atoms doped in anatase TiO2（001） thin film from [100] direction. The Cr dopants, which are clearly imaged through the atomic-resolution EELS mappings while can not be seen by HADDF/ABF-STEM, occupy both the substitutional sites of Ti atoms and the interstitial sites of TiO2 matrix. Most of them preferentially locate at the substitutional sites of Ti atoms. These results provide the direct evidence for the doping structure of Cr-doped A- TiO2 thin film at the atomic level and also prove the EELS mapping is an excellent technique for characterizing the doped materials.

Simulation Study of Electron Beam Induced Surface Plasmon Excitation at Nanoparticles

Phenomenon of localized surface plasmon excitation at nanostructured materials has attracted much attention in recent decades for their wide applications in single molecule detection,surface-enhanced Raman spectroscopy and nano-plasmonics.In addition to the excitation by external light field,an electron beam can also induce the local surface plasmon excitation.Nowadays,electron energy loss spectroscopy(EELS)technique has been increasingly employed in experiment to investigate the surface excitation characteristics of metallic nanoparticles.However,a present theoretical analysis tool for electromagnetic analysis based on the discrete dipole approximation(DDA)method can only treat the case of excitation by light field.In this work we extend the DDA method for the calculation of EELS spectrum for arbitary nanostructured materials.We have simulated EELS spectra for different incident locations of an electron beam on a single silver nanoparticle,the simulated results agree with an experimental measurement very well.The present method then provides a computation tool for study of the local surface plasmon excitation of metallic nanoparticles induced by an electron beam.

Calculations of Energy-Loss Function for 26 Materials

We present a fitting calculation of energy-loss function for 26 bulk materials, including 18 pure elements （Ag, A1, Au, C, Co, Cs, Cu, Er, Fe, Ge, Mg, Mo, Nb, Ni, Pd, Pt, Si, Te） and 8 compounds （AgCl, Al2O3, AlAs, CdS, SiO2, ZnS, ZnSe, ZnTe） for application to surface electron spectroscopy analysis. The experimental energy-loss function, which is derived from measured optical data, is fitted into a finite sum of formula based on the Drude-Lindhard dielectric model. By checking the oscillator strength-sum and perfect- screening-sum rules, we have validated the high accuracy of the fitting results. Further-more, based on the fitted parameters, the simulated reflection electron energy-loss spec- troscopy （REELS） spectrum shows a good agreement with experiment. The calculated fitting parameters of energy loss function are stored in an open and online database at http：//micro.ustc.edu.cn/ELF/ELF.html.

Hard X-ray Photoelectron Spectroscopy Study of Electron Spectral Structure beyond the Known Signal Electron Peak

HAXPES （hard X-ray photoelectron spectroscopy） is a powerful emerging instrument in surface analysis. It extended the photoelectron energy range up to 15,000 eV and opened the possibility to study much thicker films, buried layers and bulk electronic properties. In order to study these features, data for the electron IMFP （inelastic mean free path） at these energies is needed. To date, only calculated IMFP are available at energies above 5,000 eV and therefore experimental validation of these calculations are essential. In this paper, a new approach for using the HAXPES spectra is presented. This approach, treats the attenuated part of the electron spectrum as a whole to calculating the average electron energy loss. This average electron energy loss is the result of inelastic collisions in the material and hence, carry with it information about the electron transport poses. Carbon layers with thicknesses between 20 and 75 nanometer deposited over copper substrate were used to test this approach at the Spanish beam-line （Spline） in the ESRF （European synchrotron radiation facility）. The measured results showed good agreement with the predictions of the multiple inelastic scattering theory. In addition, an algorithm for the experimental evaluation of electron IMFP, using the measured energy loss, is proposed.

Irradiation Damage of Nano-C2S Particles Studied by In-Situ Transmission Electron Microscopy

Development of a reactive nanocement is a new approach to improve the physical and chemical properties of construction materials. However, due to the decreased size of cement particles, beam damage during transmission electron microscope （TEM） observation becomes more severe than in conventional cement. In this work, irradiation damage to nano-C2S （dicalcium silicate） is observed and studied by in-situ evolution of diffraction patterns （DP）, high resolution TEM （HRTEM）, and electron energy-loss spectroscopy （EELS）. The results show that the damage to nano-C2S occurs through a decomposition reaction. Nano-C2S is first amorphized, and then re-crystallized into CaO nano-crystals with average size of 7 nm surrounded by an amorphous matrix of Si and SiO2. During this process, C2S particles exhibit volume shrinkage. The damage energy causing the reaction was analyzed and electron-electron inelastic scattering produced radiolysis and heat, leading to the observed phenomena.

Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

The inhibiting effect of ciprofloxacin,norfloxacin and ofloxacin on the corrosion of mild steel in 1 mol·L-1 HCl and the mechanism were studied at different temperatures using mass loss measurement,electrochemical method,and X-ray photoelectron spectroscopy(XPS) .Effective inhibition was shown by mass loss,potentiodynamic polarization and impedance spectroscopy measurement.The corrosion rate of the metal in the mass loss measurement,and the corrosion reaction on cathode and anode in the electrochemical measurement were accelerated when temperature was increased.XPS results showed that the inhibitors adsorbed effectively on the metal surface.

Hierarchical hollow Li4Ti5O12 urchin-like microspheres with ultra-high specific surface area for high rate lithium ion batteries

Large specific surface area is critical for Li4Ti5O12 to achieve good rate capacity and cycling stability, since it can increase the contact area between electrolyte/ electrode and shorten the transport paths for electrons and lithium ions. In this study, hierarchical hollow Li4Ti5O12 urchin-like microspheres with ultra-high specific surface area of over 140 m2·g^-1 and diameter more than 500 nm have been successfully synthesized by combining the versatile sol-gel process and a hydrothermal reaction, and exhibit excellent electrochemical performance with a high specific capacity of 120 mA-h.g-1 at 20 C and long cycling stability of 〈 2% decay after 100 cycles. Ex situ electron energy loss spectroscopy （EELS） analysis of Li4Ti5O12 microspheres at different charge-discharge stages indicates that only a fraction of the TP＊ ions are reduced to Ti3＋ and a phase transformation occurs whereby the spinel phase Li4TisO12 is converted into the rock-salt phase Li7Ti5O12. Even after 100 cycles, the oxidation-reduction reaction between Ti3＋ and Ti4＋ can be carried out much more effectively on the surface of Li4Ti5O12 nanosheets than on commercially available Li4Ti5O12 particles. All the results suggest that these Li4Ti5O12 microspheres may be attractive candidate anode materials for lithium ion batteries.

Manipulation of surface phonon polaritons in Si C nanorods

Surface phonon polaritons(SPh Ps) are potentially very attractive for subwavelength control and manipulation of light at the infrared to terahertz wavelengths. Probing their propagation behavior in nanostructures is crucial to guide rational device design. Here, aided by monochromatic scanning transmission electron microscopy-electron energy loss spectroscopy technique, we measure the dispersion relation of SPh Ps in individual Si C nanorods and reveal the effects of size and shape. We find that the SPh Ps can be modulated by the geometric shape and size of Si C nanorods. The energy of SPh Ps shows redshift with decreasing radius and the surface optical phonon is mainly concentrated on the surface with large radius. Therefore, the fields can be precisely confined in specific positions by varying the size of the nanorod, allowing effective tuning at nanometer scale. The findings of this work are in agreement with dielectric response theory and numerical simulation, and provide novel strategies for manipulating light in polar dielectrics through shape and size control, enabling the design of novel nanoscale phononphotonic devices.

Dynamic observation of oxygen vacancies in hafnia layer by in situ transmission electron microscopy

The charge-trapping process, with HfO2 film as the charge-capturing layer, has been investigated by using in situ electron energy-loss spectroscopy and in situ energy-filter image under positive external bias. The results show that oxygen vacancies are non-uniformly distributed throughout the HfO2 trapping layer during the programming process. The distribution of the oxygen vacancies is not the same as that of the reported locations of the trapped electrons, implying that the trapping process is more complex. These bias-induced oxygen defects may affect the device performance characteristics such as the device lifetime. This phenomenon should be considered in the models of trapping processes.

E-beam-induced in situ structural transformation in one-dimensional nanomaterials

Electron beam （e-beam） irradiation is an inev- itable, but crucial issue for electron microscopy. Our investigation results show the e-beam-induced in situ structural transformations in silicon （Si） nanowires and zinc oxide （ZnO） nanowires （NWs）, respectively. Crystal to amorphous structure transition was revealed in Si NWs utilizing high resolution electron microscopy and electron energy loss spectroscopy. Reconstruction at the （1010） surface of ZnO NWs was also observed in the transmission electron microscope （TEM） using aberration-corrected electron microscopy. These e-beam-induced in situ struc- tural transformations prove that the electron beam irradi- ation effect is able to be used for the local modification of one-dimensional nanomaterials.

Uniform wurtzite MnSe nanocrystals with surface-dependent magnetic behavior

Manganese selenide （MnSe） possesses unique magnetic properties as an important magnetic semiconductor, but the synthesis and properties of MnSe nanocrystals are less developed compared to other semiconductor nanocrystals because of the inability to obtain high-quality MnSe, especially in the metastable wurtzite structure. Here, we have successfully fabricated wurtzite MnSe nanocrystals via a colloidal approach which affords uniform crystal sizes and tailored shapes. The selective binding strength of the amine surfactant is the determining factor in shape-control and shape-evolution. Bullet-shapes could be transformed into shuttle-shapes if part of the oleylamine in the reaction solution was replaced by trioctylamine, and tetrapod-shaped nanocrystals could be formed in trioctylamine systems. The three-dimensional （3D） structure of the bullet-shaped nanorods has been demonstrated by the advanced transmission electron microscope （TEM） 3D-tomography technology. High-resolution TEM （HRTEM） and electron energy-loss spectroscopy （EELS） show that planar-defect structures such as stacking faults and twinning along the [001] direction arise during the growth of bullet-shapes. On the basis of careful HRTEM observations, we propose a ＂quadra-twin core＂ growth mechanism for the formation of wurtzite MnSe nanotetrapods. Furthermore, the wurtzite MnSe nanocrystals show low- temperature surface spin-glass behavior due to their noncompensated surface spins and the blocking temperatures increase from 8.4 K to 18.5 K with increasing surface area/volume ratio of the nanocrystals. Our results provide a systematic study of wurtzite MnSe nanocrystals.