Solid-state lithium-metal-batteries(SSLMBs)using garnet Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)as the solid electrolyte are expected to conquer the safety concerns of high energy Li batteries with organic liquid e...Solid-state lithium-metal-batteries(SSLMBs)using garnet Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)as the solid electrolyte are expected to conquer the safety concerns of high energy Li batteries with organic liquid electrolytes owing to its nonflammable nature and good mechanical strength.However,the poor interfacial contact between the Li anode and LLZTO greatly restrains the practical applications of the electrolyte,because large polarization,dendritic Li formation and penetration can occur at the interfaces.Here,an effective method is proposed to improve the wettability of the LLZTO toward lithium and reduce the interfacial resistance by engineering universal lithiophilic interfacial layers.Thanks to the in-situ formed lithiophilic and ionic conductive Co/Li_(2)O interlayers,the symmetric Li/CoO-LLZTO/Li batteries present much smaller overpotential,ultra-low areal specific resistance(ASR,12.3 X cm^(2)),high critical current density(CCD,1.1 mA cm^(-2)),and outstanding cycling performance(1696 h at a current density of 0.3 mA cm^(-2))at 25℃.Besides,the solid-state Li/CoO-LLZTO/LFP cells deliver an excellent electrochemical performance with a high coulombic efficiency of~100%and a long cycling time over 185 times.Surprisingly,the high-voltage(4.6 V)solid state Li/CoO-LLZTO/Li_(1.4)Mn_(0.6)Ni_(0.2)Co_(0.2)O_(2.4)(LMNC622)batteries can also realize an ultra-high specific capacity(232.5 mAh g-1)under 0.1 C at 25℃.This work paves an effective way for practical applications of the dendrite-free SSLMBs.展开更多
The Co-S/x wt.% AB5 (x=0, 10, 20, 30) composite materials were prepared by simply mixing Co-S material fabricated by hy- drothermal method and AB5 alloy. The structure and morphology of the composite materials were ...The Co-S/x wt.% AB5 (x=0, 10, 20, 30) composite materials were prepared by simply mixing Co-S material fabricated by hy- drothermal method and AB5 alloy. The structure and morphology of the composite materials were characterized by XRD and SEM, respectively. The electrochemical properties of the composite electrodes were studied by the galvanostatic charge, dis- charge test and electrochemical impedance spectroscopy. The results showed that the Co-S/20 wt.% AB5 composite electrode showed the highest discharge capacity and the best cycling stability. The existence of the AB5 alloy improved the electro- chemical activity of composite electrodes, reduced the electrochemical polarization resistances and promoted the electrochem- ical conversion reaction between Co and Co(OH)2. In order to improve the utilization rate of active materials, 0.0! mol/L Na2S203 was added into the electrolyte. The electrochemical properties of the composite electrode were significantly enhanced. After fifty cycles, the discharge capacity of the composite electrode increased from 407 to 481.7 mAh/g and the capacity reten- tion increased from 79.7% to 91.2%.展开更多
This paper analyzes the fundamental frequency impedance presents a novel transmission line pilot protection scheme characteristic of a thyristor controlled series capacitor (TCSC) and based on fault component integr...This paper analyzes the fundamental frequency impedance presents a novel transmission line pilot protection scheme characteristic of a thyristor controlled series capacitor (TCSC) and based on fault component integrated impedance (FCII) calculated for a transmission line with TCSC and controllable shunt reactor (CSR). The FCII is defined as the ratio of the sum of the fault component voltage phasors of a transmission line with TCSC and CSR to the sum of the fault component current phasors where all the phasors are determined at both line's terminals. It can be used to distinguish internal faults occurring on the line from external ones. If the fault is an external one the FCII reflects the line's capacitive impedance and has large value. If the fault is an internal one on the line the FCII reflects the impedance of the equivalent system and the line and is relatively small. The new pilot protection scheme can be easily set and has the fault phase selection ability and also it is not affected by the capacitive current and the fault transition resistance. It is not sensitive to compensation level and dynamics of TCSC and CSR. The effectiveness of the new scheme is validated against data obtained in ATP simulations and Northwest China 750 kV Project.展开更多
0009894电容过程成像技术的进展〔刊〕/王化祥//仪器仪表学报.—2000,21(1).—4~7,11(E)本文详细介绍了电容过程成像技术的新进展,其中包括阵列式敏感电极结构设计,具有抗杂散电容影响的高灵敏 AC 桥电容检测线路以及 Landweber 迭代...0009894电容过程成像技术的进展〔刊〕/王化祥//仪器仪表学报.—2000,21(1).—4~7,11(E)本文详细介绍了电容过程成像技术的新进展,其中包括阵列式敏感电极结构设计,具有抗杂散电容影响的高灵敏 AC 桥电容检测线路以及 Landweber 迭代算法再构图像,从而使成像系统性能指标明显得到改善。展开更多
基金supported by the National Natural Science Foundation of China (21603019 and 201503025)Program for the Hundred Talents Program of Chongqing University。
文摘Solid-state lithium-metal-batteries(SSLMBs)using garnet Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)as the solid electrolyte are expected to conquer the safety concerns of high energy Li batteries with organic liquid electrolytes owing to its nonflammable nature and good mechanical strength.However,the poor interfacial contact between the Li anode and LLZTO greatly restrains the practical applications of the electrolyte,because large polarization,dendritic Li formation and penetration can occur at the interfaces.Here,an effective method is proposed to improve the wettability of the LLZTO toward lithium and reduce the interfacial resistance by engineering universal lithiophilic interfacial layers.Thanks to the in-situ formed lithiophilic and ionic conductive Co/Li_(2)O interlayers,the symmetric Li/CoO-LLZTO/Li batteries present much smaller overpotential,ultra-low areal specific resistance(ASR,12.3 X cm^(2)),high critical current density(CCD,1.1 mA cm^(-2)),and outstanding cycling performance(1696 h at a current density of 0.3 mA cm^(-2))at 25℃.Besides,the solid-state Li/CoO-LLZTO/LFP cells deliver an excellent electrochemical performance with a high coulombic efficiency of~100%and a long cycling time over 185 times.Surprisingly,the high-voltage(4.6 V)solid state Li/CoO-LLZTO/Li_(1.4)Mn_(0.6)Ni_(0.2)Co_(0.2)O_(2.4)(LMNC622)batteries can also realize an ultra-high specific capacity(232.5 mAh g-1)under 0.1 C at 25℃.This work paves an effective way for practical applications of the dendrite-free SSLMBs.
基金supported by the National Natural Science Foundation of China(Grant No.51201089)the Priority Academic Program Development of Jiangsu Higher Education Institutions of China(PAPD)Specialized Research Fund for the Doctoral Program of Higher Education(Grant No.20133221110009)
文摘The Co-S/x wt.% AB5 (x=0, 10, 20, 30) composite materials were prepared by simply mixing Co-S material fabricated by hy- drothermal method and AB5 alloy. The structure and morphology of the composite materials were characterized by XRD and SEM, respectively. The electrochemical properties of the composite electrodes were studied by the galvanostatic charge, dis- charge test and electrochemical impedance spectroscopy. The results showed that the Co-S/20 wt.% AB5 composite electrode showed the highest discharge capacity and the best cycling stability. The existence of the AB5 alloy improved the electro- chemical activity of composite electrodes, reduced the electrochemical polarization resistances and promoted the electrochem- ical conversion reaction between Co and Co(OH)2. In order to improve the utilization rate of active materials, 0.0! mol/L Na2S203 was added into the electrolyte. The electrochemical properties of the composite electrode were significantly enhanced. After fifty cycles, the discharge capacity of the composite electrode increased from 407 to 481.7 mAh/g and the capacity reten- tion increased from 79.7% to 91.2%.
基金supported by the National Natural Science Foundation of China (Grant Nos.50877061 and 51037005)
文摘This paper analyzes the fundamental frequency impedance presents a novel transmission line pilot protection scheme characteristic of a thyristor controlled series capacitor (TCSC) and based on fault component integrated impedance (FCII) calculated for a transmission line with TCSC and controllable shunt reactor (CSR). The FCII is defined as the ratio of the sum of the fault component voltage phasors of a transmission line with TCSC and CSR to the sum of the fault component current phasors where all the phasors are determined at both line's terminals. It can be used to distinguish internal faults occurring on the line from external ones. If the fault is an external one the FCII reflects the line's capacitive impedance and has large value. If the fault is an internal one on the line the FCII reflects the impedance of the equivalent system and the line and is relatively small. The new pilot protection scheme can be easily set and has the fault phase selection ability and also it is not affected by the capacitive current and the fault transition resistance. It is not sensitive to compensation level and dynamics of TCSC and CSR. The effectiveness of the new scheme is validated against data obtained in ATP simulations and Northwest China 750 kV Project.
文摘0009894电容过程成像技术的进展〔刊〕/王化祥//仪器仪表学报.—2000,21(1).—4~7,11(E)本文详细介绍了电容过程成像技术的新进展,其中包括阵列式敏感电极结构设计,具有抗杂散电容影响的高灵敏 AC 桥电容检测线路以及 Landweber 迭代算法再构图像,从而使成像系统性能指标明显得到改善。