The microstructure and thermophysical properties of Mg-2 Zn-x Cu alloys(x=0.5, 1.0 and 1.5, at.%) were investigated through microstructural and thermophysical characterization, heat treatment, and first-principles cal...The microstructure and thermophysical properties of Mg-2 Zn-x Cu alloys(x=0.5, 1.0 and 1.5, at.%) were investigated through microstructural and thermophysical characterization, heat treatment, and first-principles calculations. It was found that the addition of Cu had influence on the microstructure and thermophysical properties of the alloy. As the Cu content increased, the content of the MgCuZn phase increased in the as-cast alloys along with the electrical and thermal conductivities. After solution treatment, the eutectic structure partially decomposed and Zn atoms dissolved into the matrix, leading to the decrease in both the electrical and thermal conductivities of the alloy. During the early stages of the aging treatment, solute atoms precipitated from the matrix, thus increasing the electrical conductivity of the alloy. After aging for 24 h, the thermal conductivity of Mg-2 Zn-1.5 Cu alloy reached the maximum of 147.1 W/(m·K). The thermostable MgCuZn phases were responsible for increasing the electrical and thermal conductivities. Smaller amounts of Zn atoms dissolved in the matrix resulted in smaller lattice distortion and higher conductivities. The first-principles calculations findings also proved that the MgCuZn phases had very high conductance.展开更多
Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of ca...Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate (CaCO3), which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal (calcite and aragonite) are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.展开更多
With the help of supercell method, the first-principle calculations were performed for the study of doping crystal Mg1-xAlxB2 and Mg(B1-yCy)2. Analyzing the variations of the charge distribution and the partial dens...With the help of supercell method, the first-principle calculations were performed for the study of doping crystal Mg1-xAlxB2 and Mg(B1-yCy)2. Analyzing the variations of the charge distribution and the partial densities of states, we found that the compounds with doping Al to MgB2 compound and/or replacing boron by carbon exhibit new covalent bond effects and unexpected electronic properties, related to superconductivity. The study of the density of states indicates that superconductivity decreases with the increase of Al fraction and carbon concentration. There exists a transition of superconductor to non-superconductor with the change of Al doping fraction. The substitution of boron by carbon results in the decrease of the transition temperature since the decrease of the electron concentration and the lattice constant. The theoretical predictions agree with experimental observations.展开更多
When a surface acoustic wave (SAW) propagates on the surface of a GaAs semiconductor, coupling between electrons in the two-dimensional electron gas beneath the interface and the elastic host crystal through piezoel...When a surface acoustic wave (SAW) propagates on the surface of a GaAs semiconductor, coupling between electrons in the two-dimensional electron gas beneath the interface and the elastic host crystal through piezoelectric interaction will attenuate the SAW. The coupling coemcient is ~alculated for the SAW propagating along an arbitrary direction. It is found that the coupling strength is strongly dependent on the propagating direction. When the SAW propagates along the [011] direction, the coupling becomes quite weak.展开更多
Dependence of conductance of corrugated graphene quantum dot(CGQD)on geometrical features includinglength,width,connection and edge is investigated by the first principles calculations.The results demonstrate that the...Dependence of conductance of corrugated graphene quantum dot(CGQD)on geometrical features includinglength,width,connection and edge is investigated by the first principles calculations.The results demonstrate that theconductance of CGQD with different geometrical features is different from each other.The positions and amplitudesof discrete levels in densities of states and transmission coefficients are sensitive to geometrical features.The I-Vcharacteristics of graphene are modified by size and edge,it is surprise the current does not change monotonously butoscillatory with length.And they are slight change for different connections.展开更多
Oxide heterointerface is a platform to create unprecedented two-dimensional electron gas, superconductivity and ferromagnetism, arising from a polar discontinuity at the interface. In particular, the ability to tune t...Oxide heterointerface is a platform to create unprecedented two-dimensional electron gas, superconductivity and ferromagnetism, arising from a polar discontinuity at the interface. In particular, the ability to tune these intriguing effects paves a way to elucidate their fundamental physics and to develop novel electronic/magnetic devices. In this work, we report for the first time that a ferroelectric polarization screening at SrTiO_(3)/PbTiO_(3) interface is able to drive an electronic construction of Ti atom, giving rise to room-temperature ferromagnetism. Surprisingly, such ferromagnetism can be switched to antiferromagnetism by applying a magnetic field, which is reversible. A coupling of itinerant electrons with local moments at interfacial Ti3d orbital was proposed to explain the magnetism. The localization of the itinerant electrons under a magnetic field is responsible for the suppression of magnetism. These findings provide new insights into interfacial magnetism and their control by magnetic field relevant interfacial electrons promising for device applications.展开更多
基金Project(51204020)supported by the National Natural Science Foundation of ChinaProject(BA2017044)supported by the Jiangsu Provincial Department of Science and Technology,China。
文摘The microstructure and thermophysical properties of Mg-2 Zn-x Cu alloys(x=0.5, 1.0 and 1.5, at.%) were investigated through microstructural and thermophysical characterization, heat treatment, and first-principles calculations. It was found that the addition of Cu had influence on the microstructure and thermophysical properties of the alloy. As the Cu content increased, the content of the MgCuZn phase increased in the as-cast alloys along with the electrical and thermal conductivities. After solution treatment, the eutectic structure partially decomposed and Zn atoms dissolved into the matrix, leading to the decrease in both the electrical and thermal conductivities of the alloy. During the early stages of the aging treatment, solute atoms precipitated from the matrix, thus increasing the electrical conductivity of the alloy. After aging for 24 h, the thermal conductivity of Mg-2 Zn-1.5 Cu alloy reached the maximum of 147.1 W/(m·K). The thermostable MgCuZn phases were responsible for increasing the electrical and thermal conductivities. Smaller amounts of Zn atoms dissolved in the matrix resulted in smaller lattice distortion and higher conductivities. The first-principles calculations findings also proved that the MgCuZn phases had very high conductance.
基金Supported by the Special Funds for Major State Basic Research Projects of China (G2000026304)
文摘Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate (CaCO3), which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal (calcite and aragonite) are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.
基金Natural Science Foundation of Hubei Province of China under Grant No.2007ABA035
文摘With the help of supercell method, the first-principle calculations were performed for the study of doping crystal Mg1-xAlxB2 and Mg(B1-yCy)2. Analyzing the variations of the charge distribution and the partial densities of states, we found that the compounds with doping Al to MgB2 compound and/or replacing boron by carbon exhibit new covalent bond effects and unexpected electronic properties, related to superconductivity. The study of the density of states indicates that superconductivity decreases with the increase of Al fraction and carbon concentration. There exists a transition of superconductor to non-superconductor with the change of Al doping fraction. The substitution of boron by carbon results in the decrease of the transition temperature since the decrease of the electron concentration and the lattice constant. The theoretical predictions agree with experimental observations.
基金the National Natural Science Foundation of China under
文摘When a surface acoustic wave (SAW) propagates on the surface of a GaAs semiconductor, coupling between electrons in the two-dimensional electron gas beneath the interface and the elastic host crystal through piezoelectric interaction will attenuate the SAW. The coupling coemcient is ~alculated for the SAW propagating along an arbitrary direction. It is found that the coupling strength is strongly dependent on the propagating direction. When the SAW propagates along the [011] direction, the coupling becomes quite weak.
文摘Dependence of conductance of corrugated graphene quantum dot(CGQD)on geometrical features includinglength,width,connection and edge is investigated by the first principles calculations.The results demonstrate that theconductance of CGQD with different geometrical features is different from each other.The positions and amplitudesof discrete levels in densities of states and transmission coefficients are sensitive to geometrical features.The I-Vcharacteristics of graphene are modified by size and edge,it is surprise the current does not change monotonously butoscillatory with length.And they are slight change for different connections.
基金supported by the National Natural Science Foundation of China (U1909212, U1809217, and 11474249)supported by the U.S. Department of Energy, Office of Basic Energy Science, Division of Materials Sciences and Engineering (Ames Laboratory is operated for the U.S. Department of Energy by Iowa State University under Contract No. DE-AC02-07CH11358)。
文摘Oxide heterointerface is a platform to create unprecedented two-dimensional electron gas, superconductivity and ferromagnetism, arising from a polar discontinuity at the interface. In particular, the ability to tune these intriguing effects paves a way to elucidate their fundamental physics and to develop novel electronic/magnetic devices. In this work, we report for the first time that a ferroelectric polarization screening at SrTiO_(3)/PbTiO_(3) interface is able to drive an electronic construction of Ti atom, giving rise to room-temperature ferromagnetism. Surprisingly, such ferromagnetism can be switched to antiferromagnetism by applying a magnetic field, which is reversible. A coupling of itinerant electrons with local moments at interfacial Ti3d orbital was proposed to explain the magnetism. The localization of the itinerant electrons under a magnetic field is responsible for the suppression of magnetism. These findings provide new insights into interfacial magnetism and their control by magnetic field relevant interfacial electrons promising for device applications.