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不同尺寸球形纳米金粒子修饰电极在高浓度抗坏血酸共存下选择性测定多巴胺 被引量:3
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作者 王婷婷 杨莉莉 +3 位作者 李元 鲍昌昊 唐旻奕 程寒 《分析科学学报》 CAS CSCD 北大核心 2020年第5期725-733,共9页
本文制备了直径分别为5nm、20nm和50nm的球形纳米金颗粒(AuNPs),通过一步恒电位沉积法将AuNPs修饰到碳纤维微电极的表面上以获得AuNPs改性的碳纤维微电极(AuNPs/CFME),并研究了电极修饰前后对多巴胺(DA)、去甲肾上腺素(NE)、抗坏血酸(AA... 本文制备了直径分别为5nm、20nm和50nm的球形纳米金颗粒(AuNPs),通过一步恒电位沉积法将AuNPs修饰到碳纤维微电极的表面上以获得AuNPs改性的碳纤维微电极(AuNPs/CFME),并研究了电极修饰前后对多巴胺(DA)、去甲肾上腺素(NE)、抗坏血酸(AA)、K_3[Fe(CN)_6]的电化学响应。结果表明,AuNPs/CFME对带正电荷的儿茶酚胺类神经递质具有明显的电催化作用,对带负电荷的物质具有明显的屏蔽作用。球形AuNPs的尺寸越小,其催化屏蔽效果越好。在高浓度AA共存下,差分脉冲伏安法(DPV)峰值电流与DA浓度在0.1~10.0μmol/L的范围呈线性相关,检出限(S/N=3)为0.013μmol/L。本文开发了一种简便高效的方法,用于选择性检测带正电的DA并屏蔽荷负电物质,已将其应成功应用于小鼠血清样品中高浓度AA共存下DA的选择性测定。 展开更多
关键词 纳米金颗粒 碳纤维微 催化效果 电屏蔽效果 多巴胺 抗坏血酸 差分脉冲伏安法
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Enhanced photoresponsivity and hole mobility of MoTe_2 phototransistors by using an Al_2O_3 high-κ gate dielectric 被引量:5
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作者 Wenjie Chen Renrong Liang +2 位作者 Jing Wang Shuqin Zhang Jun Xu 《Science Bulletin》 SCIE EI CSCD 2018年第15期997-1005,共9页
Molybdenum ditelluride (MoTe2) has been demonstrated great potential in electronic and optoelectronic applications. However, the reported effective hole mobility remains far below its theoretical value. Herein, taki... Molybdenum ditelluride (MoTe2) has been demonstrated great potential in electronic and optoelectronic applications. However, the reported effective hole mobility remains far below its theoretical value. Herein, taking advantage of high-κ screening effect, we have fabricated back-gated MoTe2 transistors on an Al2O3 high-κ dielectric and systematically investigated the electronic and optoelectronic proper- ties. A high current on/off ratio exceeding 106 is achieved in the Al2O3-based MoTe2 transistors, and the hole mobility is demonstrated to be 150 cm2 V^-1 s^-1, compared to 0.2-20 cm^2 V^-1 s^-1 ever obtained from back-gated MoTe2 transistors in the literatures. Moreover, a considerable hole concentration of 1.2 × 10^13 cm 2 is attained in our Al2O3-based MoTe2 transistors owing to the strong gate control capa- bility, leading to a high on-state hole current of 6.1 μA μm^-1. After optimization, our Al2O3-based MoTe2 phototransistor exhibits outstanding photodetective performance, with a high responsivity of 543 AW^-1 and a high photogain of 1,662 at 405 nm light illumination, which are boosted around 419 times compared to the referential SiO2-based control devices. The mechanisms of photoconductivity in the Al2O3-based MoTe2 phototransistors have been analyzed in detail, and the photogating effect is considered to play an important role. This work may provide useful insight to improve carrier mobility in two-dimensional layered semiconductors and open opportunities to facilitate the development of high-performance photodetectors in the future. 展开更多
关键词 MoTe2 High-K dielectric PHOTOTRANSISTORS Hole mobility PHOTODETECTORS
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Modeling of an ionized electric field on the building near the UHVDC transmission line 被引量:8
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作者 ZHEN YongZan CUI Xiang LU TieBing 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第4期747-753,共7页
In this paper,a 3D upstream finite element method is developed to analyze the ionized electric field around the UHVDC transmission lines including the building near it.The ionized electric field around the building is... In this paper,a 3D upstream finite element method is developed to analyze the ionized electric field around the UHVDC transmission lines including the building near it.The ionized electric field around the building is reduced due to the shielding effect of the building and the shielding distance is about three times its height.The ionized electric field including the human body model on the building and away from the building is also taken into account.The ionized electric field distortion ratio of the human body model is discussed in this paper.The distortion ratios for the positions on the building are less than those on the ground. 展开更多
关键词 BUILDING finite element method (fem) human body HVDC ionized electric field
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