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电弧炉粉尘球团非等温还原的动力学研究 被引量:13
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作者 彭兵 张传福 彭及 《北方工业大学学报》 2000年第3期52-58,共7页
在连续加热条件下 ,对电弧炉粉尘球团的还原过程动力学进行了研究 .电弧炉粉尘与碳和粘结剂白云石均匀混合后制粒 ,然后将球团置于热重分析仪中以平均 4 0 K/ min的速度加热至 150 0℃ ,并利用计算机对球团重量变化进行监控 .金属还原... 在连续加热条件下 ,对电弧炉粉尘球团的还原过程动力学进行了研究 .电弧炉粉尘与碳和粘结剂白云石均匀混合后制粒 ,然后将球团置于热重分析仪中以平均 4 0 K/ min的速度加热至 150 0℃ ,并利用计算机对球团重量变化进行监控 .金属还原率的计算中 ,考虑了球团的失重、水的蒸发、铅和锌在高温下挥发 .经实验研究证实电弧炉粉尘的还原分为 3个步骤 ,并建立了每一步骤的还原动力学方程 ,找出了有关的动力学参数表观活化能和频率因子 ,从而确定第 1步由化学反应控制 ,第 2步由扩散控制 ,第 3步与球团中的含碳量和加热温度有关 ,主要是铬的氧化物 ( Cr O)的还原 。 展开更多
关键词 电弧炉粉 化学动力学 非等温还原 电弧炉炼钢 尘处理
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Zinc leaching from electric arc furnace dust in alkaline medium 被引量:2
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作者 李宏煦 王洋 苍大强 《Journal of Central South University》 SCIE EI CAS 2010年第5期967-971,共5页
Physical and chemical properties of electric arc furnace (EAF) dust from Tianjin seamless Pipe Company were measured and analyzed. The zinc leaching tests in alkaline medium were carried out under variation of leach... Physical and chemical properties of electric arc furnace (EAF) dust from Tianjin seamless Pipe Company were measured and analyzed. The zinc leaching tests in alkaline medium were carried out under variation of leaching agent concentration, leaching temperature, leaching cumulative time and solid-to-liquid ratio. The thermodynamics and kinetics of the zinc leaching process were also analyzed. The results show that the EAF dust contains 10% (mass fraction) zinc and the median particle size is 0.69 μm. The zinc recovery of 73.4% is obtained tinder the condition of 90 ℃, 6 mol/L NaOH, and 60 min leaching time. With the increase of concentration of NaOH and the cumulative time, zinc leaching will be significantly increased. The kinetics study demonstrates that the leaching reaction is chemically controlled and the reaction activation energy is 15.73 kJ/mol. 展开更多
关键词 electric arc furnace (EAF) dust zinc leaching HYDROMETALLURGY THERMODYNAMICS leaching kinetics RECYCLING
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