基于学科理解的电性关系大概念教学初探

基于化学学科理解的视角,结合教学思想和实践经验,对物质转化提出“本源性”理解,进而将相应认识视角和思路应用于课堂教学,建构电性关系学科大概念。

Research on large-scale cascading failure of power systems using synergistic effect

This paper discusses the primary causes from the point of synergistic effects to improve power system vulnerability in the power system planning and safety operation. Based on the vulnerability conception in the complex network theory the vulnerability of the power system can be evaluated by the minimum load loss rate when considering power supply ability.Consequently according to the synergistic effect theory the critical line of the power system is defined by its influence on failure set vulnerability in N-k contingencies.The cascading failure modes are proposed based on the criterion whether the acceptable load curtailment level is below a preset value.Significant conclusions are revealed by results of IEEE 39 case analysis weak points of power networks and heavy load condition are the main causes of large-scale cascading failures damaging synergistic effects can result in partial failure developed into large-scale cascading failures vulnerable lines of power systems can directly lead the partial failure to deteriorate into a large blackout while less vulnerable lines can cause a large-scale cascading failure.

Theory-guided electrocatalyst engineering:From mechanism analysis to structural design

The exploitation of competent electrocatalysts is a key issue of the broad application of many promising electrochemical processes,including the hydrogen evolution reaction(HER),the oxygen evolution reaction(OER),the oxygen reduction reaction(ORR),the CO_(2) reduction reaction(CO_(2)RR)and the nitrogen reduction reaction(NRR).The traditional searches for good electrocatalysts rely on the trial-and-error approaches,which are typically tedious and inefficient.In the past decades,some fundamental principles,activity descriptors and catalytic mechanisms have been established to accelerate the discovery of advanced electrocatalysts.Hence,it is time to summarize these theory-related research advances that unravel the structure-performance relationships and enables predictive ability in electrocatalysis studies.In this review,we summarize some basic aspects of catalytic theories that are commonly used in the design of electrocatalysts(e.g.,Sabatier principle,d-band theory,adsorption-energy scaling relation,activity descriptors)and their relevance.Then,we briefly introduced the fundamental mechanisms and central challenges of HER,OER,ORR,CO_(2)RR and NRR electrocatalysts,and highlight the theory-based efforts used to address the challenges facing these electrocatalysis processes.Finally,we propose the key challenges and opportunities of theory-driven electrocatalysis on their future.

Resistivity measurement of conductive asphalt concrete based on two-electrode method

The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resistivity is always not equal to the real resistivity.To determine the real resistivity,a linear relationship of the measured resistivity,contact resistance and the real resistivity was established.Then experiments for six specimens with varying graphite contents were designed and performed to validate the formulation.Results of experiments demonstrate that the slope of the line represents contact resistance,and the intercept indicates the real resistivity.The effects of graphite content on contact resistance and real resistivity are also revealed.Finally,results show that the influence of contact resistance on accuracy of resisitvity measurement becomes more serious if graphite content is beyond 3%.Hence,it is the time to choose this novel methodology to determine the real resistivity of asphalt concrete by taking account of contact resistance.

Dependency-based importance measures of components in mechatronic systems with complex network theory

To compensate for the limitations of previous studies,a complex network-based method is developed for determining importance measures,which combines the functional roles of the components of a mechatronic system and their topological positions.First,the dependencies among the components are well-represented and well-calculated.Second,a mechatronic system is modeled as a weighted and directional functional dependency network(FDN),in which the node weights are determined by the functional roles of components in the system and their topological positions in the complex network whereas the edge weights are represented by dependency strengths.Third,given that the PageRank algorithm cannot calculate the dependency strengths among components,an improved PageRank importance measure(IPIM)algorithm is proposed,which combines the node weights and edge weights of complex networks.IPIM also considers the importance of neighboring components.Finally,a case study is conducted to investigate the accuracy of the proposed method.Results show that the method can effectively determine the importance measures of components.

Contribution of Iron and Aluminum Oxides to Electrokinetic Characteristics of Variable Charge Soils in Relation to Surface Charge

The contribution of iron and aluminum oxides to electrokinetic characteristics of variable charge soils was studied through determination of electrophoretic mobilities of the red soils treated with either removal of iron oxides or coating of aluminum oxides, and of those deferrated under natural conditions. After removal of the iron oxides, zeta potentials of the latosol and the red earth decreased obviously with a shift of IEP to a lower pH, from 6.4 to 5.3 and 4.1 to 2.4 for the former and the latter, respectively, and the electrokinetic change for the latosol was greater than for the red earth. Zeta potentials of the kaolinite sample increased markedly after coated with iron oxides. The striking effect of iron oxides on electrokinetic properties of the soils was also demonstrated by the electrokinetic differences between the samples from the red and white zones of a plinthitic horizon formed naturally, and between the samples from the gley and bottom horizons of a paddy soil derived from a red earth. The coatings of aluminum oxides on the latosol and the yellow earth made their zeta potentials rise pronouncedly and their IEPs move toward higher pHs, from 6.2 to 6.8 and 4.3 to 5.3 for the former and the latter, respectively. The samples with different particle sizes also exhibited some electrokinetic variation. The experiment showed that the effects of iron and aluminum oxides were closely related to the pH and type of the soils.

Restructuring of well-defined Pt-based electrode surfaces under mild electrochemical conditions

Since the 1980s,single-crystal Pt electrodes with well-defined surface structures have been deemed stable under mild electrochemical conditions(e.g.,in the potential region of electric double layers,underpotential deposition of hydrogen,or mild hydrogen evolution/OH adsorption)and have served as model electrodes for unraveling the structure-performance relation in electrocatalysis.With the advancement of in situ electrochemical microscopy/spectroscopy techniques,subtle surface restructuring under mild electrochemical conditions has been achieved in the last decade.Surface restructuring can considerably modify electrocatalytic properties by generating/destroying highly active sites,thereby interfering with the deduction of the structure-performance relation.In this review,we summarize recent progress in the restructuring of well-defined Pt(-based)electrode surfaces under mild electrochemical conditions.The importance of the meticulous structural characterization of Pt electrodes before,during,and after electrochemical measurements is demonstrated using CO adsorption/oxidation,hydrogen adsorption/evolution,and oxygen reduction as examples.The implications of present findings for correctly identifying the reaction mechanisms and kinetics of other electrocatalytic systems are also briefly discussed.

The Interrelation between the NAO （North Atlantic Oscillation） and Regulated River Discharges at the Baltic Sea Drainage Basin

Both winter DJF （December, January, February） months and DJF season means long-term data series of 50 regulated rivers discharges rates and the NAO indices were analyzed for different spans. This study is dictated for： （1） detecting the exclusive impacts of the positive phases of NAO indices on rivers discharges rates by estimating the Linear Correlation Coefficient; （2） modeling the interrelations between the discharges rates and NAO indices by estimating the Linear Regression Models, both for manifesting the impact of the positive phase of NAO index; （3） estimating the Linear Trend Coefficient in the discharge series, for manifesting the contribution of the positive phase of NAO index. Discharge rates are mainly influenced by the two mechanisms： the positive phase of NAO index and the environmental conditions in specific catchments, that is where, the positive phase of the NAO index manifest its impact on the related rivers discharges and its contribution in the related configured trends. The discharges fluctuations patterns show some increase in the discharges values have been occurred in regions around the Northern Baltic Proper as well as in Southern Finland and Sweden. The rivers such as Lagan, Nissan, Helgean, Venta, Pamu, Porvoonjoki, Lapuanjoki, Oulujoki, Kyronjoki, Wisla, Eurajoki, Odra, Lielupe, Gota alv, Motala strom, Nykopingsan, Vuoksi, Kalajoki and Simojoki haven not linear discharges changes registered depending on the specificity of the environmental conditions at the catchments areas for those rivers. The positive phase of NAO index has a linear relation with impacted river discharge.

Reliability Investigation of PCs＇ SMPSs

Today reliability is one of the serious requirements of electronic systems. The numbers of system failures, repair cost, guarantee, etc. are estimated by reliability estimation. In this paper reliability of a switching power supply, which is used for personal computers, is evaluated. It will show that the most of failure rates depends on power circuit because of more stresses and dissipations. Derating effect of devices on the failure rate is discussed. A prototype power supply＇s waveforms are used for stress detection and calculation of dissipations.

A continuum theory of surface piezoelectricity for nanodielectrics

In this paper,a phenomenological continuum theory of surface piezoelectricity accounting for the linear superficial interplay between electricity and elasticity is formulated primarily for elastic dielectric materials.This theory is inspired by the physical idea that once completely relaxed,an insulating free dielectric surface will sustain a nontrivial spontaneous surface polarization in the normal direction together with a tangential self-equilibrated residual surface stress field.Under external loadings,the surface Helmholtz free energy density is identified as the characteristic function of such surfaces,with the in-plane strain tensor of surface and the surface free charge density as the independent state variables.New boundary conditions governing the surface piezoelectricity are derived through the variational method.The resulting concepts of charge-dependent surface stress and deformationdependent surface electric field reflect the linear electromechanical coupling behavior of nanodielectric surfaces.As an illustrative example,an infinite radially polarizable piezoelectric nanotube with both inner and outer surfaces grounded is investigated.The novel phenomenon of possible surface-induced polarity inversion is predicted for thin enough nanotubes.