Rechargeable lithium-oxygen(Li-O_(2))batteries have attracted wide attention due to their high energy density.However,the sluggish cathode kinetics results in high overvoltage and poor cycling performance.Ruthenium(Ru...Rechargeable lithium-oxygen(Li-O_(2))batteries have attracted wide attention due to their high energy density.However,the sluggish cathode kinetics results in high overvoltage and poor cycling performance.Ruthenium(Ru)-based electrocatalysts have been demonstrated to be promising cathode catalysts to promote oxygen evolution reaction(OER).It facilitates decomposition of lithium peroxide(Li_(2)O_(2))by adjusting Li_(2)O_(2) morphologies,which is due to the strong interaction between Ru-based catalyst and superoxide anion(O_(2))intermediate.In this review,the design strategies of Ru-based electrocatalysts are introduced to enhance their OER catalytic kinetics in Li-O_(2) batteries.Different configurations of Ru-based catalysts,including metal particles(Ru metal and alloys),single-atom catalysts,and Ru-loaded compounds with various substrates(carbon materials,metal oxides/sulfides),have been summarized to regulate the electronic structure and the matrix architecture of the Ru-based electrocatalysts.The structure-property relationship of Ru-based catalysts is discussed for a better understanding of the Li_(2)O_(2) decomposition mechanism at the cathode interface.Finally,the challenges of Ru-based electrocatalysts are proposed for the future development of Li-O_(2) batteries.展开更多
A power saving frequency difference controlling method was introduced by the double inverter and motor experiment system.The characters of the system under differ- ent loads were investigated.The theoretical analysis ...A power saving frequency difference controlling method was introduced by the double inverter and motor experiment system.The characters of the system under differ- ent loads were investigated.The theoretical analysis and experiment results show the frequency difference method is a ideal power saving speed regulation method for the dou- ble inverter and motor system.The experiment system is simply structured,convenient to operate and provides a new way of character testing for frequency conversion speed regulation.展开更多
The development status of the variable speed system of large power AC(alternating current)motor drive in China is introduced.The large power AC drive fed by AC-AC converters(cycloconverters)has developed greatly,and s...The development status of the variable speed system of large power AC(alternating current)motor drive in China is introduced.The large power AC drive fed by AC-AC converters(cycloconverters)has developed greatly,and some innovations on the theory and engineering technique have been realized.They have been applied to rolling mills,mine hoists,and so on,and remarkable economic and social benefit has been achieved.The development of AC drive fed by large power IGCT(integrated gate commutated thyristors)AC-DC-AC converter is also introduced.It has excellent performance and reliable operation,and has been used in traction.展开更多
In the early development of the wind energy, the majority of the wind turbines have been operated at constant speed. Subsequently, the number of variable-speed wind turbines installed in wind farms has increased. In t...In the early development of the wind energy, the majority of the wind turbines have been operated at constant speed. Subsequently, the number of variable-speed wind turbines installed in wind farms has increased. In this paper, a comparative performance of fixed and variable speed wind generators with Pitch angle control has been presented. The first is based on a squirrel cage Induction Generator (IG) of 315 kW rated power, connected directly to the grid. The second incorporated a Permanent Magnet Synchronous Generator (PMSG) of 750 kW rated power. The performances of each studied wind generator are evaluated by simulation works and variable speed operation is highlighted as preferred mode of operation.展开更多
In this work, the authors propose the study of a wind speed variable based on the DFAM (double fed asynchronous machine). The model of the turbine is drawn from the classical equations describing the operation of a ...In this work, the authors propose the study of a wind speed variable based on the DFAM (double fed asynchronous machine). The model of the turbine is drawn from the classical equations describing the operation of a variable wind speed. The torque generated by the turbine is applied to the DFAM directly connected on the network side and the stator via a bidirectional converter side rotor. This configuration allows velocity variations of ±30% around the synchronous speed and the converter is then sized to one third of the rated power of the machine. The DFAM is controlled by a control vector ensuring operation of the wind turbine power coefficient maximum.展开更多
基金the National Natural Science Foundation of China(22325902 and 51671107)Haihe Laboratory of Sustainable Chemical Transformations.
文摘Rechargeable lithium-oxygen(Li-O_(2))batteries have attracted wide attention due to their high energy density.However,the sluggish cathode kinetics results in high overvoltage and poor cycling performance.Ruthenium(Ru)-based electrocatalysts have been demonstrated to be promising cathode catalysts to promote oxygen evolution reaction(OER).It facilitates decomposition of lithium peroxide(Li_(2)O_(2))by adjusting Li_(2)O_(2) morphologies,which is due to the strong interaction between Ru-based catalyst and superoxide anion(O_(2))intermediate.In this review,the design strategies of Ru-based electrocatalysts are introduced to enhance their OER catalytic kinetics in Li-O_(2) batteries.Different configurations of Ru-based catalysts,including metal particles(Ru metal and alloys),single-atom catalysts,and Ru-loaded compounds with various substrates(carbon materials,metal oxides/sulfides),have been summarized to regulate the electronic structure and the matrix architecture of the Ru-based electrocatalysts.The structure-property relationship of Ru-based catalysts is discussed for a better understanding of the Li_(2)O_(2) decomposition mechanism at the cathode interface.Finally,the challenges of Ru-based electrocatalysts are proposed for the future development of Li-O_(2) batteries.
文摘A power saving frequency difference controlling method was introduced by the double inverter and motor experiment system.The characters of the system under differ- ent loads were investigated.The theoretical analysis and experiment results show the frequency difference method is a ideal power saving speed regulation method for the dou- ble inverter and motor system.The experiment system is simply structured,convenient to operate and provides a new way of character testing for frequency conversion speed regulation.
文摘The development status of the variable speed system of large power AC(alternating current)motor drive in China is introduced.The large power AC drive fed by AC-AC converters(cycloconverters)has developed greatly,and some innovations on the theory and engineering technique have been realized.They have been applied to rolling mills,mine hoists,and so on,and remarkable economic and social benefit has been achieved.The development of AC drive fed by large power IGCT(integrated gate commutated thyristors)AC-DC-AC converter is also introduced.It has excellent performance and reliable operation,and has been used in traction.
文摘In the early development of the wind energy, the majority of the wind turbines have been operated at constant speed. Subsequently, the number of variable-speed wind turbines installed in wind farms has increased. In this paper, a comparative performance of fixed and variable speed wind generators with Pitch angle control has been presented. The first is based on a squirrel cage Induction Generator (IG) of 315 kW rated power, connected directly to the grid. The second incorporated a Permanent Magnet Synchronous Generator (PMSG) of 750 kW rated power. The performances of each studied wind generator are evaluated by simulation works and variable speed operation is highlighted as preferred mode of operation.
文摘In this work, the authors propose the study of a wind speed variable based on the DFAM (double fed asynchronous machine). The model of the turbine is drawn from the classical equations describing the operation of a variable wind speed. The torque generated by the turbine is applied to the DFAM directly connected on the network side and the stator via a bidirectional converter side rotor. This configuration allows velocity variations of ±30% around the synchronous speed and the converter is then sized to one third of the rated power of the machine. The DFAM is controlled by a control vector ensuring operation of the wind turbine power coefficient maximum.