To understand the geochemical characteristics of iron and sulfur and the extent of iron-sulfide minerals influencing heavy metal behaviour in metal-polluted sediments of Talhu Lake, two sites, in Meiliang Bay (ML) a...To understand the geochemical characteristics of iron and sulfur and the extent of iron-sulfide minerals influencing heavy metal behaviour in metal-polluted sediments of Talhu Lake, two sites, in Meiliang Bay (ML) and Wuli Lake (WL), were selected to study the fractionation of iron, sulfur and related heavy metals. There were relatively high concentrations of Fe^2+ and low concentrations of total S^2- in porewaters, indicating that conditions in these sediments favored iron reduction. The concentrations of acid volatile sulfides in sediments were 1.9-9.6 μmol g^-1 at ML and 1.0-11.7 μmool g^-1 at WL, both in the range of values detected in unpolluted lakes. Pyrite-S was 10.2-49.4 μmol g^-1 at ML and 10.3- 33.0 μmol g^-1 at WL, accounting for more than 69% of the reduced inorganic sulfur at both sites. The low degree of sulphidization (〈 14%) and pyritization (〈 10%) indicate that sulfate may be the limiting factor for pyrite formation. The extractability of Mn, Cu, Pb, Zn, Ni, and Cr in sediments all suggest that sulfides are not the major binding phase for these metals during early diagenesis. Sulfur may play a modest role in the geochemistry of iron and traced metals in the sediments.展开更多
In this paper, with the non-salient pole permanent magnet linear synchronous motor (PMLSM)being cited, by using Fourier transform method and "slot-by-slot", "pole -by-pole" current approach, a 3D e...In this paper, with the non-salient pole permanent magnet linear synchronous motor (PMLSM)being cited, by using Fourier transform method and "slot-by-slot", "pole -by-pole" current approach, a 3D electromagnetic field model of PMLSM is established. Special attention is paid to its structure and the influence of longitudinal and transverse end effect. The distribution of electromagnetic field of PMLSM can be obtained directly and promptly by using FFT algorithm. It can also be used for the analysis of other LSM.展开更多
we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystallin...we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystalline quality which drastically reduces the degradation of ferroelectric film by preventing hydrogen diffusion into ferroelectric film. This improvement enables us to commercialize highly-reliable 1T 1C FRAM with memory density of 4 Mb or larger.展开更多
The extrinsic mechanism for anomalous Hall effect in ferromagnets is extended to include the contributions both from spin-orbit-dependent impurity scattering and from the spin-orbit coupling induced by external electr...The extrinsic mechanism for anomalous Hall effect in ferromagnets is extended to include the contributions both from spin-orbit-dependent impurity scattering and from the spin-orbit coupling induced by external electric fields. The results obtained suggest that, within the framework of the extrinsic mechanisms, the anomalous Hall current in a ferromagnet may also contain a substantial amount of dissipationless contribution independent of impurity scattering. After the contribution from the spin-orbit coupling induced by external electric fields is included, the total anomalous Hall conductivity is about two times larger than that due to soin-orbit dependent impurity scatterings.展开更多
The full-potential linearized augmented plane wave (FPLAPW) method with the generalized gradient approximations (GGA) is applied to study the compound [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<...The full-potential linearized augmented plane wave (FPLAPW) method with the generalized gradient approximations (GGA) is applied to study the compound [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> (NITmPy = 2 - (3' - Pyridy1) -4, 4, 5, 5 - tetramethylimidazolin - 1 - oxy1 - 3 - oxide). The total density of states (DOS) and the partial density of states (pDOS) are calculated to explain the electronic and the magnetic properties of [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB>. It is found that [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> is stable in the ferromagnetic state and the magnetic moment of the molecule mainly comes from the Cu atoms (0.518 μ<SUB>B</SUB>) with partial contribution from N, O atoms of nitronyl nitroxide radicals. There exist orbital hybridization between 3d orbital of Cu and p orbitals of N(1) (from pyridyl rings of the NITmPy ligands) and N(4) (from azido group) and the weak direct exchange interactions between Cu and O atoms of nitronyl nitroxides. In addition, the bridging carbon atom (C(6)) carries a significant negative spin density (-0.019 μ<SUB>B</SUB>). The sign alternation of the magnetic moment along zthe pyridyl ring is obtained, which agrees with experiments.展开更多
A novel micro-machined diamagnetic stable.levitation system (MDSLS) which is composed of a free permanent magnetic rotor, a ring lifting permanent magnet and two diamagnetic stabilizers was presented. The static and...A novel micro-machined diamagnetic stable.levitation system (MDSLS) which is composed of a free permanent magnetic rotor, a ring lifting permanent magnet and two diamagnetic stabilizers was presented. The static and dynamic stable characters of MDSLS were analyzed. The coupled non-linear differential equations were used to describe six-degree-of-freedom motion of the levitated rotor, and the equivalent surface current and combined dia- magnetic image current method were utilized to model the interaction forces and torques between the lifting perma- nent magnet and rotor permanent magnet and also between the rotor permanent magnet and diamagnetic sub- strates. Because of difficulty to get analytical solution, the numerical calculation based on Runge-Kutta method was used to solve the dynamic model. The vibration frequencies were identified b~ fast Fourier transform (FFT) analysis. According to their resonance characteristics and parameters, the translational and angular dynamic stiff- ness were also calculated. The results show that the levitation of the rotor in MDSLS is stable, and the MDSLS is potential for the application in levitation inertial sensor.展开更多
The effect of hydrogen inhibitor on partial current densities ofZn, Fe and differential capacitance of electrode/electrolyte interface, and adsorbing type of hydrogen inhibitor were studied by the methods of electroch...The effect of hydrogen inhibitor on partial current densities ofZn, Fe and differential capacitance of electrode/electrolyte interface, and adsorbing type of hydrogen inhibitor were studied by the methods of electrochemistry. The mechanism of current efficiency improvement were explained from the point of valence electron theory. The results indicate that the partial current density of Fe increases in addition of hydrogen inhibitor, which reaches the maximum of 0.14 A/dm^2 when current density is 0.2 A/din〈 Differential capacitance of electrode/electrolyte interface decreases obviously from 20.3μF/cm^2 to 7 μF/cm^2 rapidly with the concentration varying from 0 to 20 mL/L, because hydrogen inhibitor chemically adsorbs on active points of Fe electrode surface selectively. Element S in hydrogen inhibitor with negative electricity and strong capacity of offering electron shares isolated electrons with Fe. The adsorption of H atom is inhibited when adsorbing on active points of Fe electrode surface firstly, and then current efficiency of Zn-Fe alloy electroplating is improved accordingly.展开更多
The paper presents a mathematical model ofbrushless DC machine induced by permanent magnets. Its construction uses the classical model of permanent magnet synchronous machine and induced model of power inverter using ...The paper presents a mathematical model ofbrushless DC machine induced by permanent magnets. Its construction uses the classical model of permanent magnet synchronous machine and induced model of power inverter using the serraphil form. The results of the computer simulation were presented for such states: startup, work under active constant load and the behavior of the machine in terms of exponential and stepping change of the power inverter's control angle.展开更多
The flux-weakening performance of a permanent magnet brushless AC drive was investigated using both floating-point and fixed-point DSP controllers. A significant current oscillation was observed when the drive was ope...The flux-weakening performance of a permanent magnet brushless AC drive was investigated using both floating-point and fixed-point DSP controllers. A significant current oscillation was observed when the drive was operated at high-speed in the flux-weakening mode with the fixed-point DSP. The investigation showed that this was due to the on-line compensation of the winding resistance voltage drop and quantisation errors associated with the fixed-point architecture of the DSP. A simple look-up table scheme is proposed to eliminate the oscillation and to achieve extended flux-weakening capability.展开更多
A 3-D FEA (finite element analysis) transient and steady-state design proposal for high-speed with Nd-Fe-Br (reversible) magnets in aerospace application will be examined under design considerations of n = 12,000 ...A 3-D FEA (finite element analysis) transient and steady-state design proposal for high-speed with Nd-Fe-Br (reversible) magnets in aerospace application will be examined under design considerations of n = 12,000 rpm, short-duty, sinusoidal drive, low cogging, high efficiency at peak torque, and etc. for an ARWM (aerospace retraction wheel motor). In construction, the PMs (permanent magnets) fixed on the rotor core which is surface-mOunted magnets retained by a carbon-fiber bandage. Redundant windings, resistant to fault propagation have accounted. Besides, an axial water-jacket housing without end-cap cooling has involved. All performed characteristic performances of the correlated ARWM will verify by comparison through 2-D and 3-D FEA results. In this paper, design process has dealing with determination of various kinds of losses such as electromagnetic and mechanical losses. In terms of both classified losses, copper, stator back iron, stator tooth, PM, rotor back iron, air-friction and sleeve losses were calculated. The 3-D end-winding effects were included in the modeled ARWM by the authors.展开更多
基金the National Natural Science Foundation of China (No.40730528)the National High Technology Research and Development Program (863 Program) of China (No.2007AA06Z411)the Social Development Plan of Jiangsu Province (No.BS2007161).
文摘To understand the geochemical characteristics of iron and sulfur and the extent of iron-sulfide minerals influencing heavy metal behaviour in metal-polluted sediments of Talhu Lake, two sites, in Meiliang Bay (ML) and Wuli Lake (WL), were selected to study the fractionation of iron, sulfur and related heavy metals. There were relatively high concentrations of Fe^2+ and low concentrations of total S^2- in porewaters, indicating that conditions in these sediments favored iron reduction. The concentrations of acid volatile sulfides in sediments were 1.9-9.6 μmol g^-1 at ML and 1.0-11.7 μmool g^-1 at WL, both in the range of values detected in unpolluted lakes. Pyrite-S was 10.2-49.4 μmol g^-1 at ML and 10.3- 33.0 μmol g^-1 at WL, accounting for more than 69% of the reduced inorganic sulfur at both sites. The low degree of sulphidization (〈 14%) and pyritization (〈 10%) indicate that sulfate may be the limiting factor for pyrite formation. The extractability of Mn, Cu, Pb, Zn, Ni, and Cr in sediments all suggest that sulfides are not the major binding phase for these metals during early diagenesis. Sulfur may play a modest role in the geochemistry of iron and traced metals in the sediments.
文摘In this paper, with the non-salient pole permanent magnet linear synchronous motor (PMLSM)being cited, by using Fourier transform method and "slot-by-slot", "pole -by-pole" current approach, a 3D electromagnetic field model of PMLSM is established. Special attention is paid to its structure and the influence of longitudinal and transverse end effect. The distribution of electromagnetic field of PMLSM can be obtained directly and promptly by using FFT algorithm. It can also be used for the analysis of other LSM.
文摘we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystalline quality which drastically reduces the degradation of ferroelectric film by preventing hydrogen diffusion into ferroelectric film. This improvement enables us to commercialize highly-reliable 1T 1C FRAM with memory density of 4 Mb or larger.
基金Supported by the National Natural Science Foundation of China under Grant No.10874049the State Key Program for Basic Research of China under Grant No.2007CB925204the Natural Science Foundation of Guangdong Province under Grant No.07005834
文摘The extrinsic mechanism for anomalous Hall effect in ferromagnets is extended to include the contributions both from spin-orbit-dependent impurity scattering and from the spin-orbit coupling induced by external electric fields. The results obtained suggest that, within the framework of the extrinsic mechanisms, the anomalous Hall current in a ferromagnet may also contain a substantial amount of dissipationless contribution independent of impurity scattering. After the contribution from the spin-orbit coupling induced by external electric fields is included, the total anomalous Hall conductivity is about two times larger than that due to soin-orbit dependent impurity scatterings.
文摘The full-potential linearized augmented plane wave (FPLAPW) method with the generalized gradient approximations (GGA) is applied to study the compound [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> (NITmPy = 2 - (3' - Pyridy1) -4, 4, 5, 5 - tetramethylimidazolin - 1 - oxy1 - 3 - oxide). The total density of states (DOS) and the partial density of states (pDOS) are calculated to explain the electronic and the magnetic properties of [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB>. It is found that [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> is stable in the ferromagnetic state and the magnetic moment of the molecule mainly comes from the Cu atoms (0.518 μ<SUB>B</SUB>) with partial contribution from N, O atoms of nitronyl nitroxide radicals. There exist orbital hybridization between 3d orbital of Cu and p orbitals of N(1) (from pyridyl rings of the NITmPy ligands) and N(4) (from azido group) and the weak direct exchange interactions between Cu and O atoms of nitronyl nitroxides. In addition, the bridging carbon atom (C(6)) carries a significant negative spin density (-0.019 μ<SUB>B</SUB>). The sign alternation of the magnetic moment along zthe pyridyl ring is obtained, which agrees with experiments.
基金The National Natural Science Foundation ofChina (No60402003)The Weaponry Pre-liminary Research Foundation of China (No9140A09020706JW0314)
文摘A novel micro-machined diamagnetic stable.levitation system (MDSLS) which is composed of a free permanent magnetic rotor, a ring lifting permanent magnet and two diamagnetic stabilizers was presented. The static and dynamic stable characters of MDSLS were analyzed. The coupled non-linear differential equations were used to describe six-degree-of-freedom motion of the levitated rotor, and the equivalent surface current and combined dia- magnetic image current method were utilized to model the interaction forces and torques between the lifting perma- nent magnet and rotor permanent magnet and also between the rotor permanent magnet and diamagnetic sub- strates. Because of difficulty to get analytical solution, the numerical calculation based on Runge-Kutta method was used to solve the dynamic model. The vibration frequencies were identified b~ fast Fourier transform (FFT) analysis. According to their resonance characteristics and parameters, the translational and angular dynamic stiff- ness were also calculated. The results show that the levitation of the rotor in MDSLS is stable, and the MDSLS is potential for the application in levitation inertial sensor.
基金Projects(50274073) supported by the National Natural Science Foundation of China
文摘The effect of hydrogen inhibitor on partial current densities ofZn, Fe and differential capacitance of electrode/electrolyte interface, and adsorbing type of hydrogen inhibitor were studied by the methods of electrochemistry. The mechanism of current efficiency improvement were explained from the point of valence electron theory. The results indicate that the partial current density of Fe increases in addition of hydrogen inhibitor, which reaches the maximum of 0.14 A/dm^2 when current density is 0.2 A/din〈 Differential capacitance of electrode/electrolyte interface decreases obviously from 20.3μF/cm^2 to 7 μF/cm^2 rapidly with the concentration varying from 0 to 20 mL/L, because hydrogen inhibitor chemically adsorbs on active points of Fe electrode surface selectively. Element S in hydrogen inhibitor with negative electricity and strong capacity of offering electron shares isolated electrons with Fe. The adsorption of H atom is inhibited when adsorbing on active points of Fe electrode surface firstly, and then current efficiency of Zn-Fe alloy electroplating is improved accordingly.
文摘The paper presents a mathematical model ofbrushless DC machine induced by permanent magnets. Its construction uses the classical model of permanent magnet synchronous machine and induced model of power inverter using the serraphil form. The results of the computer simulation were presented for such states: startup, work under active constant load and the behavior of the machine in terms of exponential and stepping change of the power inverter's control angle.
文摘The flux-weakening performance of a permanent magnet brushless AC drive was investigated using both floating-point and fixed-point DSP controllers. A significant current oscillation was observed when the drive was operated at high-speed in the flux-weakening mode with the fixed-point DSP. The investigation showed that this was due to the on-line compensation of the winding resistance voltage drop and quantisation errors associated with the fixed-point architecture of the DSP. A simple look-up table scheme is proposed to eliminate the oscillation and to achieve extended flux-weakening capability.
文摘A 3-D FEA (finite element analysis) transient and steady-state design proposal for high-speed with Nd-Fe-Br (reversible) magnets in aerospace application will be examined under design considerations of n = 12,000 rpm, short-duty, sinusoidal drive, low cogging, high efficiency at peak torque, and etc. for an ARWM (aerospace retraction wheel motor). In construction, the PMs (permanent magnets) fixed on the rotor core which is surface-mOunted magnets retained by a carbon-fiber bandage. Redundant windings, resistant to fault propagation have accounted. Besides, an axial water-jacket housing without end-cap cooling has involved. All performed characteristic performances of the correlated ARWM will verify by comparison through 2-D and 3-D FEA results. In this paper, design process has dealing with determination of various kinds of losses such as electromagnetic and mechanical losses. In terms of both classified losses, copper, stator back iron, stator tooth, PM, rotor back iron, air-friction and sleeve losses were calculated. The 3-D end-winding effects were included in the modeled ARWM by the authors.