To disclose the effect of contact force and electrode gap on the material transfer behavior of Ag-based contact material, arc-erosion tests of the Ag-4wt.%TiB2 contact material were performed for 5000 operations at 24...To disclose the effect of contact force and electrode gap on the material transfer behavior of Ag-based contact material, arc-erosion tests of the Ag-4wt.%TiB2 contact material were performed for 5000 operations at 24 V/16 A under resistive load on an electric contact material testing system. The arc energy and arc duration were investigated, the surface morphologies of eroded anode and cathode were characterized, the mass changes after arc-erosion tests were determined, and the material transfer behavior was discussed as well. The results show that contact force has a significant effect on the arc energy, arc duration and erosion morphology, but has no impact on the material transfer mode. However, electrode gap not only influences the arc energy, arc duration and surface morphology, but also changes the material transfer mode. At 1 mm, the material transfers from anode to cathode. Nevertheless, an opposite mode presents at 4 mm, which is from cathode to anode.展开更多
The photo-corrosion of electrodeposited polycrystalline CdSe electrode was inhibited effectively by coating a thin layer of the conductive polyaniline （PAN） film. The relation between the performance and internal ba...The photo-corrosion of electrodeposited polycrystalline CdSe electrode was inhibited effectively by coating a thin layer of the conductive polyaniline （PAN） film. The relation between the performance and internal band structure of such film-covered PAN/CdSe electrode was studied by the electrochemical modulation reflectance spectrum （EMRS）. EMRS of both CdSe and PAN/CdSe electrodes in K4Fe（CN）6/K3Fe（CN）6 solution exhibited typical France-Keidysh oscillations, by which the values of the energy gap and flat band potential were determined. The EMRS results indicated that the energy band structure of CdSe electrode was not changed after coated with PAN film, so that the photoelectrochemical characteristic of PAN/CdSe electrode was rather similar to that of CdSe electrode.展开更多
基金Projects(51274163,51605146) supported by the National Natural Science Foundation of ChinaProject(U1502274) supported by Key Program of the National Natural Science Foundation of China+2 种基金Project(2018M632769) supported by the China Postdoctoral Science FoundationProject(2017SKY-WK010) supported by the Research Fund of Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources,ChinaProject(18JK0722) supported by Special Research Program of Shaanxi Provincial Department of Education,China
文摘To disclose the effect of contact force and electrode gap on the material transfer behavior of Ag-based contact material, arc-erosion tests of the Ag-4wt.%TiB2 contact material were performed for 5000 operations at 24 V/16 A under resistive load on an electric contact material testing system. The arc energy and arc duration were investigated, the surface morphologies of eroded anode and cathode were characterized, the mass changes after arc-erosion tests were determined, and the material transfer behavior was discussed as well. The results show that contact force has a significant effect on the arc energy, arc duration and erosion morphology, but has no impact on the material transfer mode. However, electrode gap not only influences the arc energy, arc duration and surface morphology, but also changes the material transfer mode. At 1 mm, the material transfers from anode to cathode. Nevertheless, an opposite mode presents at 4 mm, which is from cathode to anode.
文摘The photo-corrosion of electrodeposited polycrystalline CdSe electrode was inhibited effectively by coating a thin layer of the conductive polyaniline （PAN） film. The relation between the performance and internal band structure of such film-covered PAN/CdSe electrode was studied by the electrochemical modulation reflectance spectrum （EMRS）. EMRS of both CdSe and PAN/CdSe electrodes in K4Fe（CN）6/K3Fe（CN）6 solution exhibited typical France-Keidysh oscillations, by which the values of the energy gap and flat band potential were determined. The EMRS results indicated that the energy band structure of CdSe electrode was not changed after coated with PAN film, so that the photoelectrochemical characteristic of PAN/CdSe electrode was rather similar to that of CdSe electrode.
