采用电极感应熔化气雾化制粉法(electrode induction gas atomization,EIGA)制备粉末过程中,非限制式喷嘴的结构设计直接决定气雾化粉末的质量;非限制式喷嘴结构中不合理的喷射角度常常会引起反喷、片状粉、细粉收率低等问题,严重影响...采用电极感应熔化气雾化制粉法(electrode induction gas atomization,EIGA)制备粉末过程中,非限制式喷嘴的结构设计直接决定气雾化粉末的质量;非限制式喷嘴结构中不合理的喷射角度常常会引起反喷、片状粉、细粉收率低等问题,严重影响粉末的生产效率和质量。采用商业计算流体动力学(computationalfluiddynamics,CFD)软件Fluent,以自主设计的第三代EIGA制备高温合金粉末装置中非限制式喷嘴为研究对象进行数值模拟建模,对带有气体回流区的非限制式喷嘴在熔体初次雾化过程中,喷射角度对反喷现象的影响以及反喷产生的机理进行了研究。结果表明,非限制式喷嘴射流角度过大时,熔体液滴会出现明显反喷现象;当非限制式喷嘴射流角度过小时,熔体液流雾化前过热度不足,生产的粉末球形度较差。因此,在优化设计非限制式喷嘴时,要应尽量控制气体回流区位置低于非限制式喷嘴熔体入口位置,保证合金熔体的过热度,同时防止反喷等现象。展开更多
Ti0.5Al0.25Ni0.25 alloy prepared by vacuum induction melting was studied.The phase composition was analyzed with X-ray technique and EDS analysis,and its electrochemical properties were investigated at various tempera...Ti0.5Al0.25Ni0.25 alloy prepared by vacuum induction melting was studied.The phase composition was analyzed with X-ray technique and EDS analysis,and its electrochemical properties were investigated at various temperatures.Electrochemical reaction kinetic parameters were also studied with proper electrochemical techniques.The influence of the secondary corrosion reaction on the anodic linear polarization measurement was also analyzed by theoretical simulation.The results show that,proper ball-milling with nickel powders is beneficial to electrochemical performance.The theoretical simulation proves that,the existence of the side reaction can disturb the measurement of electrochemical reaction kinetic parameters.展开更多
文摘采用电极感应熔化气雾化制粉法(electrode induction gas atomization,EIGA)制备粉末过程中,非限制式喷嘴的结构设计直接决定气雾化粉末的质量;非限制式喷嘴结构中不合理的喷射角度常常会引起反喷、片状粉、细粉收率低等问题,严重影响粉末的生产效率和质量。采用商业计算流体动力学(computationalfluiddynamics,CFD)软件Fluent,以自主设计的第三代EIGA制备高温合金粉末装置中非限制式喷嘴为研究对象进行数值模拟建模,对带有气体回流区的非限制式喷嘴在熔体初次雾化过程中,喷射角度对反喷现象的影响以及反喷产生的机理进行了研究。结果表明,非限制式喷嘴射流角度过大时,熔体液滴会出现明显反喷现象;当非限制式喷嘴射流角度过小时,熔体液流雾化前过热度不足,生产的粉末球形度较差。因此,在优化设计非限制式喷嘴时,要应尽量控制气体回流区位置低于非限制式喷嘴熔体入口位置,保证合金熔体的过热度,同时防止反喷等现象。
文摘Ti0.5Al0.25Ni0.25 alloy prepared by vacuum induction melting was studied.The phase composition was analyzed with X-ray technique and EDS analysis,and its electrochemical properties were investigated at various temperatures.Electrochemical reaction kinetic parameters were also studied with proper electrochemical techniques.The influence of the secondary corrosion reaction on the anodic linear polarization measurement was also analyzed by theoretical simulation.The results show that,proper ball-milling with nickel powders is beneficial to electrochemical performance.The theoretical simulation proves that,the existence of the side reaction can disturb the measurement of electrochemical reaction kinetic parameters.
