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电极界面缓冲层对P3HT:PC_(61)BM太阳能电池热稳定性的影响(英文) 被引量:3
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作者 武娜 骆群 +1 位作者 吴振武 马昌期 《物理化学学报》 SCIE CAS CSCD 北大核心 2015年第7期1413-1420,共8页
基于溶液法加工制备的聚合物太阳能电池的高温热稳定性是决定器件能否兼容后续高温热封装工艺,如热压封装、高温原子层沉积(ALD)等的一个关键.本文分别利用聚(3,4-乙烯二氧噻吩)-聚苯乙烯磺酸(PEDOT:PSS)和Mo O3作为阳极缓冲层,以及Zn O... 基于溶液法加工制备的聚合物太阳能电池的高温热稳定性是决定器件能否兼容后续高温热封装工艺,如热压封装、高温原子层沉积(ALD)等的一个关键.本文分别利用聚(3,4-乙烯二氧噻吩)-聚苯乙烯磺酸(PEDOT:PSS)和Mo O3作为阳极缓冲层,以及Zn O和Li F作为阴极缓冲层,制备了结构为氧化铟锡(ITO)/阳极缓冲层/3-己基取代聚噻吩:(6,6)-苯基C61-丁酸甲酯(P3HT:PC61BM)/阴极缓冲层/Al的太阳能电池,系统地比较研究了不同界面缓冲材料对器件光电转换性能及稳定性的影响,特别是在高温煺火条件下器件的性能稳定性差异.结果表明,聚合物太阳能电池的热稳定性同器件的结构以及所用的缓冲层材料有密切的相关性.其中,利用Mo O3及Zn O分别作为阳极与阴极界面修饰层的P3HT:PC61BM器件在120-150°C的温度范围内能够较好地保持器件的光电转换性能.这一结果为后续需要高温封装工艺的器件提供了有意义的结构优化指导.此外,研究结果还表明利用Zn O作为阴极缓冲层能够改善器件的长时间稳定性. 展开更多
关键词 聚合物太阳能电池 热稳定性 金属氧化物纳米粒子 电极缓冲层
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Significant Enhancement in Built-in Potential and Charge Carrier Collection of Organic Solar Cells using 4-(5-hexylthiophene-2-yl)-2,6-bis(5- trifluoromethyl)thiophen-2-yl)pyridine as a Cathode Buffer Layer
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作者 臧月 曹康丽 +2 位作者 黄江 张清 于军胜 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第5期593-599,I0004,共8页
An electron transporting material of TFTTP (4-(5-hexylthiophene-2-yl)-2,6-bis(5-trifluoromethyl)thiophen-2-yl)pyridine) was investigated as a cathode buffer layer to enhance the power efficiency of organic sola... An electron transporting material of TFTTP (4-(5-hexylthiophene-2-yl)-2,6-bis(5-trifluoromethyl)thiophen-2-yl)pyridine) was investigated as a cathode buffer layer to enhance the power efficiency of organic solar cells (OSCs) based on subphthalocyanine and C60. The overall power conversion efficiency was increased by a factor of 1.31 by inserting the TFTTP interfacial layer between the active layer and metallic cathode. The inner mechanism responsible for the performance enhancement of OSCs was systematically studied with the simulation of dark diode behavior and optical field distribution inside the devices as well as the characterization of device photocurrent. The results showed that the TFTTP layer could significantly increase the built-in potential in the devices, leading to the enhanced dissociation of charge transfer excitons. In addition, by using TFTTP as the buffer layer, a better Ohmic contact at C60/metal interface was formed, facilitating more efficient free charge carrier collection. 展开更多
关键词 Organic solar cells Cathode buffer layer Built-in potential Charge carrier collection Optical spacer effect
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Inverted Organic Solar Cells with Improved Performance using Varied Cathode Buffer Layers 被引量:1
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作者 Zhi-qiang Guan Jun-sheng Yu +1 位作者 Yue Zang Xing-xin Zeng 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第5期625-630,I0004,共7页
Organic solar cells with inverted planar heterojunction structure based on subphthalocya- nine and C60 were fabricated using several kinds of materials as cathode buffer layer (CBL), including tris-8-hydroxy-quinoli... Organic solar cells with inverted planar heterojunction structure based on subphthalocya- nine and C60 were fabricated using several kinds of materials as cathode buffer layer (CBL), including tris-8-hydroxy-quinolinato aluminum (Alq3), bathophenanthroline (Bphen), bathocuproine, 2,3,8,9,14,15-hexakis-dodecyl-sulfanyl-5,6,11,12,17,18-hexaazatrinaphthylene (HATNA), and an inorganic compound of Cs2CO3. The influence of the lowest unoccupied molecular orbital level and the electron mobility of organic CBL on the solar cells perfor- mance was compared. The results showed that Alq3, Bphen, and HATNA could significantly improve the device performance. The highest efficiency was obtained from device with an- nealed HATNA as CBL and increased for more than 7 times compared with device without CBL. Furthermore~ the simulation results with space charge-limited current theory indicated that the Schottky barrier at the organic/electrode interface in inverted OSC structure was reduced for 27% by inserting HATNA CBL. 展开更多
关键词 Organic solar cell Inverted structure Subphthalocyanine/C60 Cathode bufferlayer Space charge-limited current theory
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