改进盐水工艺 稳定电槽电压

结合离子膜槽电压急剧上升的具体情况，分析影响槽电压上升的主要原因。指出盐水质量是保证电槽正常工作的重要因素，介绍了改进盐水工艺，稳定电槽电压的措施。

Effect of gas bubble on cell voltage oscillations based on equivalent circuit simulation in aluminum electrolysis cell

A method to investigate the effect of gas bubble on cell voltage oscillations was established. The whole aluminum electrolysis cell was treated as a resistance circuit, and the dynamic simulation of the cell equivalent circuit was modeled with Matlab/Simulink simulation software. The time-series signals of cell voltage and anode current were obtained under different bubble conditions, and analyzed by spectral and statistical analysis methods. The simulation results show that higher bubble release frequency has a significant effect on the cell voltage oscillations. When the bubble coverage of one anode block exceeds 80%, the cell voltage may exceed its normal fluctuation amplitude. The simulation also proves that the anode effect detected by computer in actual production is mainly the whole cell anode effect.

Influence of nano-CeO_2 on coating structure and properties of electrodeposited Al/α-PbO_2/β-PbO_2

Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide （CeO2） were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electrodes and the impact of α-PbO2 as the intermediate layer. The results show that using α-PbO2 as the intermediate layer will benefit the crystallization of β-PbO2 and β-PbO2 is more suitable as the surface layer than α-PbO2. CeO2 dopants change the crystallite size and crystal structure, enhance the catalytic activity, and even change the deposition mechanism of PbO2. The doping of CeO2 in the PbO2 electrodes can enhance the electro-catalytic activity, which is helpful for oxygen evolution, and therefore reduce the cell voltage.

Effect of SnO_2 intermediate layer on performance of Ti/SnO_2/MnO_2 electrode during electrolytic-manganese process

SnO2intermediate layers were coated on the titanium(Ti)substrate by thermal decomposition.Scanning electronmicroscope(SEM)and X-ray diffraction(XRD)results show that uniform SnO2intermediate layers with rutile crystal structure weresuccessfully achieved.According to the results of linear sweep voltammetry(LSV),oxygen evolution potential(OEP)of theTi/SnO2/MnO2electrodes decreases with increasing SnO2content,indicating that the electro-catalytic oxidation activity of theelectrode increases.Accelerated service life tests results demonstrate that SnO2intermediate layer can improve the service life of theTi/SnO2/MnO2electrode.As the content of SnO2intermediate layer increases,the cell voltage and the energy consumption decreaseapparently.

关于2万t烧碱整流机组效率的分析

引入整流机组效率拐点的概念,通过日效率曲线形象地给出了2万t烧碱整流机组效率的拐点,并分析了效率低的原因,提出了增加槽数和保证足够的导通角以节约电能的方案。

Excess Heat Power Registration in High Voltage Electrolysis Cell Experiments

Experimental research of the heat and high-energy processes occurring in the cathode solid medium in the high voltage electric discharge system （electrolysis cell and glow discharge device） is presented. The experiments were carried out： Electrolysis in heavy water with a Pd cathode, electrolysis in light water with Ni and Pd cathodes, the glow discharge in deuterium with a Pd cathode. Excess heat was observed in experiments with high-voltage electrolysis （1,000 V or more）. The experiments showed that the maximum excess heat power values of 5-8 W for glow discharge and 180-280 W for high-voltage electrolysis and heat efficiency up to 170% for glow discharge, and 800% for high-voltage electrolysis. The production of impurity nuclide yield showing a shift of up to a few per cent from natural isotopic abundances was detected by spark mass spectrometry and by secondary ionic mass spectrometry. The authors propose based on these experimental results a phenomenological model for low energy nuclear reaction.

A Mach-Zehnder interferometer electro-optic switch with ultralow voltage-length product using poled-polymer/silicon slot waveguide

By using poled-polymer/silicon slot waveguides in the active region and the Pockels effect of the poled-polymer,we propose a kind of Mach-Zehnder interferometer(MZI) electro-optic(EO) switch operated at 1 550 nm.Structural parameters are optimized for realizing normal switching function.Dependencies of switching characteristics on the slot waveguide parameters are investigated.For the silicon strip with dimension of 170 nm×300 nm,as the slot width varies from 50 nm to 100 nm,the switching voltage can be as low as 1.0 V with active region length of only 0.17–0.35 mm,and the length of the whole device is only about 770–950 μm.The voltage-length product of this switching structure is only 0.17–0.35 V·mm,and it is at least 19–40 times smaller than that of the traditional polymer MZI EO switch,which is 6.69 V·mm.Compared with our previously reported MZI EO switches,this switch exhibits some superior characteristics,including low switching voltage,compact device size and small wavelength dependency.