基于灰色马尔科夫链的生态园区建筑电气密度预测研究

为解决当前电气密度预测误差大的问题,提出基于灰色马尔科夫链的生态园区建筑电气密度预测方法。监测生态园区建筑电气密度变化,对采集到的数据进行预处理。划分数据状态并构建三角形隶属函数获得模糊状态向量,结合马尔科夫链与灰色模型完成电气密度预测。实验结果表明,所提方法的预测误差小、精度高,具有可行性。

Electric field distribution in 75 kA drained aluminum reduction cell

Current distribution in a drained aluminum reduction cell is critical due to its influence on the current efficiency, electrolysis stability, anodes and cathodes integrity. A finite element model was developed to simulate the electric field in a 75 kA drained aluminum reduction cell. The current distribution and influences of the cathode inclination angle and anode-cathode distance (ACD) were studied. The results show that relatively large horizontal current density appears in the aluminum film, and the maximum value reaches 600 kA/m2. As the cathode inclination angle increases from 2° to 15°, the maximum current density of the metal pad increases by 15%, while the maximum current density of the aluminum-wettable coating layer decreases by 27%. The influence of the ACD on the current distribution is not obvious.

Microscopic mechanism of perfluorocarbon gas formation in aluminum electrolysis process

In view of the unclear cause of perfluorocarbons(PFCs)emission in the anode effect stage of aluminum electrolysis,the microscopic formation mechanism of PFCs was studied by density functional theory calculation and X-ray photoelectron spectroscopy(XPS).It is found that the discharge of fluorine containing anions([F]−)on carbon anode first causes the substitution of C—H by C—F and further results in the saturation of aromatic C—C bonds,leading to the appearance of—CF_(3)or—C_(2)F_(5)group through six-carbon-ring opening.Elimination of—CF_(3)and—C_(2)F_(5) with F atom could be a likely mechanism of CF_(4) and C_(2)F_(6) formation.XPS results confirm that different types of—CF_(x) group can be formed on anode surface during electrolysis,and the possibility that[F]−discharges continuously at the C edge and finally forms different C—F bonds in quantum mechanical calculation was verified.

Effect of BaO addition on relative density and electric conductivity of xNi/10NiO-NiFe_2O_4 cermets

xNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets and those doped with 1% BaO （mass fraction） were prepared by cold isostatic pressing at 200 MPa and sintering in nitrogen atmosphere at 1 473 K. The effects of BaO addition on relative density, microstructure and electric conductivity of cermets were investigated. The results show that relative densities ofxNi/10NiO-NiFe2O4 cermets （x=5, 10, 17） doped with 1% BaO at 1 473 K in nitrogen atmosphere are increased by 0.49%, 1.45% and 2.99% compared with those of the undoped BaO cermets, respectively. Moreover, the electric conductivities （21.98, 28.37 and 50.10 S/cm） of xNi/10NiO-NiFe2O4 cermets （x=5, 10, 17） doped with 1% BaO at 1 233 K are improved compared with those （18.70, 22.79 and 39.58 S/cm） of xNi/lONiO-NiFe2O4 cermets （x=5, 10, 17）, respectively. This indicates that perhaps the addition of BaO or formation of BaFe204 and Ba2Fe2O5 has an active effect on electric conductivities ofxNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets.

Development of Numerical Model for Radio Frequency Atmospheric Pressure Glow Discharges in Argon

A one-dimensional,self-consistent fluid model is developed for a computational investigation on discharge characteristics and dynamics of radio frequency(RF) glow discharges in atmospheric argon,which are demonstrated through the spatial and temporal profiles of plasma species,electric field,and mean electron energy.Furthermore,in the discharge current density range from 7.1 mA/cm2 to 119.5 mA/cm2,different discharge operation modes of α and γ are indicated by changing differential conductivity of voltage-current characteristics and sheath dynamics in terms of sheath voltage and sheath thickness.

Modeling Relative Humidity Effects on Power Electronic Performance

Variations in the behavior of power supplies caused electrical behavior dependence with environmental conditions. by environmental conditions require accurate characterization of the This paper introduces models to help predict relative humidity （Rtt） and other environmental factors influence on sensitive circuitry in power electronic systems. The resistivity and permittivity of an insulator have been modeled using different water contents i.e. RH, such model also included the mechanical properties of the design. An application example of a high power density, high voltage DC-DC converter is used to verify the results.

Solvation structure and dynamics of Li and LiO_(2)and their transformation in non-aqueous organic electrolyte solvents from first-principles simulations

Density functional theory calculations together with ab initio molecular dynamics(AIMD)simulations have been used to study the solvation,diffusion and transformation of Li^(+)and LiO_(2)upon O_(2)reduction in three organic electrolytes.These processes are critical for the performance of Li-air batteries.Apart from studying the structure of the solvation shells in detail,AIMD simulations have been used to derive the diffusivity and together with the Blue Moon ensemble approach to explore LiO_(2)formation from Li^(+)and O_(2)−and the subsequent disproportionation of 2LiO_(2)into Li_(2)O_(2)+O_(2).By comparing the results of the simulations to gas phase calculations,the impact of electrolytes on these reactions is assessed which turns out to be more pronounced for the ionic species involved in these reactions.

Investigation of condition-induced bubble size and distribution in electroflotation using a high-speed camera

In the flotation process, bubble is a key factor in studying bubble-particle interaction and fine particle flo- tation. Knowledge on size distribution of bubbles in a flotation system is highly important. In this study, bubble distributions in different reagent concentrations, electrolyte concentrations, cathode apertures, and current densities in electroflotation are determined using a high-speed camera. Average bubble sizes under different conditions are calculated using Image-Pro@ Plus （Media Cybernetics@, MD, USA） and SigmaScan@ Pro （Systat Software, CA, USA） software. Results indicate that the average sizes of bubbles, which were generated through 38, 50, 74, 150, 250, 420, and 1000 μm cathode apertures, are 20.2, 29.5, 44.6, 59.2, 68.7, 78.5, and 88.8 μm, respectively. The optimal current density in electroflotation is 20 A/m2. Reagent and electrolyte concentrations, current density, and cathode aperture are important factors in controlling bubble size and nucleation. These factors also contribute to the control of fine- Particle flotation.

Cubic imidazolate frameworks-derived CoFe alloy nanoparticles-embedded N-doped graphitic carbon for discharging reaction of Zn-air battery

The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthesized CoFe alloy nanoparticle-embedded N-doped graphitic carbon(CoFe/NC)nanostructures as ORR electrocatalysts.The ZIF-67(zeolitic imidazolate framework,ZIF)nanocubes were first synthesized,followed by an introduction of Fe2+ions to form CoFe-ZIF precursors via a simple ion-exchange route.Subsequently,the CoFe/NC composites were synthesized through a facile pyrolysis strategy.The ORR activity and the contents of cobalt and iron could be effectively adjusted by controlling the solution concentration of Fe2+ions used for the ion exchange and the pyrolysis temperature.The CoFe/NC-0.2-900 composite(synthesized with 0.2 mmol of FeSO4·7H2O at a pyrolysis temperature of 900℃)exhibited ORR activity that was superior to the other samples owing to a synergistic effect of the bimetal,especially considering the extremely high limiting current density of 6.4 mA cm^-2 compared with that of Pt/C(5.1 mA cm^-2).Rechargeable Zn-air batteries were assembled employing CoFe/NC-0.2-900 and NiFeP/NF(NiFeP supported on nickel foam(NF))as the catalysts for the discharging and charging processes,respectively,The above materials achieved reduced discharging and charging platforms,high power density,and prolonged cycling stability compared with conventional Pt/C+RuO2/C catalysts.

Effects of manganese dioxide additives on the electrical characteristics of Al-doped ZnO varistors

The effects of manganese dioxide (MnO 2 ) additives on the electrical characteristics of the Al-doped ZnO varistors are investigated. The leakage current densities of the samples decrease first and then increase again with the increase of the amount of MnO 2 additives. Correspondingly, the nonlinear coefficients of the samples keep on increasing and then decrease. In addition, the donor densities increase monotonously with the amount of the doped MnO 2 increasing. The effects of MnO 2 additives on the electrical characteristics of the samples are different from the conclusion of previous literatures. The reasons of the distinct effects are supposed to be related with the donor and interface state densities of the samples.

Trapping and diffusion behaviors of helium at vacancy in iron from first principles

We investigate the structure,trapping,and diffusion behaviors of helium(He) at vacancy in a Fe single crystal using first-principles simulations.Vacancy with more space can provide the lower electron density region for He binding in comparison with intrinsic Fe,causing He to diffuse into the vacancy inner easily.We provide the quantitative microscopic studies related to the atomic-level thermo-kinetic trapping processes.Moreover,such physical viewpoint can be applied to other vacancy-like defects such as vacancy clusters,void and grain boundaries which can open a space with reduced electron density region to increase He binding in metals and metal alloys.

The global star formation law of galaxies revisited in the radio continuum

We study the global star formation law, the relation between the gas and star formation rate （SFR） in a sample of 130 local galaxies with infrared （IR） luminosities spanning over three orders of magnitude （109-1012 Lo）, which includes 91 normal spiral galaxies and 39 （ultra）luminous IR galaxies [（U）LIRGs]. We derive their total （atomic and molecular） gas and dense molecular gas masses using newly available HI, CO and HCN data from the literature. The SFR of galaxies is determined from total IR （8-1000 μm） and 1.4 GHz radio continuum （RC） luminosities. The galaxy disk sizes are defined by the de-convolved elliptical Gaussian FWHM of the RC maps. We derive the galaxy disk-averaged SFRs and various gas surface densities, and investigate their relationships. We find that the galaxy disk-averaged surface density of dense molecular gas mass has the tightest correlation with that of SFR （scatter -0.26 dex）, and is linear in log-log space （power-law slope of N=1.03±0.02） across the full galaxy sample. The correlation between the total gas and SFR surface densities for the full sample has a somewhat larger scatter （-0.48 dex）, and is best fit by a power-law with slope 1.45±0.02. However, the slope changes from -1 when only normal spirals are considered, to -1.5 when more and more （U）LIRGs are included in the fitting. When different CO-to-H2 conversion factors are used to infer molecular gas masses for normal galaxies and （U）LIRGs, the bi-modal relations claimed recently in CO observations of high-redshift galaxies appear to also exist in local populations of star-forming galaxies.

Increasing trend of lightning activity in the South Asia region

Lightning is an important natural source of wildfires and oxynitride,and hence significantly influences ecological systems and atmospheric chemistry.Here,we choose South Asia,an important region for global water reallocation and global climate changes,to examine lightning variations based on the longest existing lightning dataset from the OTD/LIS observations.We identify a clear increase in lightning density in the research region,increasing at a rate of 0.096 fl km^(-2)a^(-1)over the last two decades.Multiple linear regression analysis is adopted to identify the main influencing factors among ten potential thermodynamic or microphysical factors and the crucial areas contributing to the increases in lightning.The surface latent heat flux along the west coast of the Indian subcontinent is the largest contributor,explaining52%of the lightning variance and contributing to a 0.025 fl km^(-2)a^(-1)increase.The sea surface temperature in the Arabian Sea,the convective available potential energy(CAPE)over the northwestern Indian subcontinent,and the wind shear along the northwestern coast also make important contributions to the lightning increase,indicating that the thermodynamic effects overwhelm the microphysical effects on lightning activity over the South Asia region.

High loading cotton cellulose-based aerogel self-standing electrode for Li-S batteries

Lithium-sulfur(Li-S) batteries have attracted considerable attention due to their high energy density(2600 Wh kg-1). However, its commercialization is hindered seriously by the low loading and utilization rate of sulfur cathodes. Herein, we designed the cellulose-based graphene carbon composite aerogel(CCA) self-standing electrode to enhance the performance of Li-S batteries. The CCA contributes to the mass loading and utilization efficiency of sulfur, because of its unique physical structure: low density(0.018 g cm-3), large specific surface area(657.85 m2 g-1), high porosity(96%), and remarkable electrolyte adsorption(42.25 times). Compared to Al(about 49%), the CCA displayed excellent sulfur use efficiency(86%) and could reach to high area capacity of 8.60 mAh cm-2 with 9.11 mgS loading. Meanwhile,the CCA exhibits the excellent potential for pulse sensing applications due to its flexibility and superior sensitivity to electrical response signals.

Ash-free coal as fuel for direct carbon fuel cell

This work describes the performance of the direct carbon fuel cell(DCFC)fuelled by ash-free coal.Employing coal in the DCFC might be problematic,mainly because of the ash deposition after the cell reactions.In the study,the carbonaceous ash-free component of coal is obtained,which is then evaluated as the DCFC fuel and compared with raw coal,active carbon,carbon black,and graphite.The electrolyte-supported SOFC structure is adapted to build the DCFC.The DCFC based on the ash-free coal fuel exhibits good performance with regard to the maximum power density,day-by-day measurements,and durability at continuous run.When the carbon fuels are internally gasified to H2 and CO,the power density is generally much improved,compared to N2 pyrolysis environment.The power generation is most likely related to the concentration of pyrolyzed gases as well as the electrochemical reactivity of the solid carbon.

Laser tuned field emission of the carbon nanotube arrays grown on an optical fiber

Laser was coupled into an optical fiber,on which covered a layer of well-aligned carbon nanotubes(CNTs)serving as cathode,to tune the field emission of the cathode.CNT arrays as field emission cathode were synthesized by chemical vapor deposition(CVD)on a naked fiber core.When the laser was coupled into the fiber,the turn-on voltage(Vto at a current density of 1 mA cm?2)decreased from 1.0 to 0.9 kV and the emission current density increased from 0.83 mA cm?2(at a 1 kV bias voltage)to3.04 mA cm?2 on 40μm diameter fiber.A photon absorption mechanism is attributed to the field emission improvement.The estimated effective work function of CNT arrays on the optical fiber decrease from 4.89 to 4.29 eV.The results show the possibility of constructing a waveguide type laser modulated field emission cathode.

Geometrical structures, and electronic and transport properties of a novel two-dimensional β-GaS transparent conductor

Two-dimensional （2D） materials are highly promising for flexible electronics, and graphene is the only well-studied transparent conductor. Herein, density functional theory has been used to explore a new transparent conducting material via adsorption of H on a 2D β-GaS sheet. This adsorption results in geometrical changes to the local structures around the H. The calculated electronic structures reveal metallic characteristics of the 2D α-GaS material upon H adsorption and a large optical band gap of 2.72 eV with a significant Burstein-Moss shift of 0.67 eVo The simulated electrical resistivity is as low as 10^-4 Ω.cm, comparable to the benchmark for ITO thin films.

Implementation of the Earth-based planetary radio occultation inversion technique

The planetary radio occultation technique is one of the earliest suggested and achieved methods to detect the planetary atmosphere,and has been conducted by almost every deep space planetary probe.The principles,modules,inversion results and primary analysis of the SHAO Planetary Occultation observation Processing system(SPOPs) are presented in this paper.Utilizing open-loop and closed-loop Doppler residual data of the Mars Express radio occultation experiment provided by ESA PSA and NASA PDS,the temperature,pressure,molecular number density profiles of Martian atmosphere and electron density profiles of the ionosphere are successfully retrieved,and the results are validated by the released radio science level 04 products of the ESA MaRS group.This system can also process the atmosphere radio occultation observations of other planets and theirs natural satellites.The implementation of the planetary radio occultation technique is of significance to China's YH-1 Mars exploration project,as well as for future planetary exploration missions from China.

An electron momentum spectroscopic study of naphthalene in gas phase

We report the experimental and theoretical investigation of the complete valence shell binding energy spectra and momentum profiles of naphthalene (C 10 H 8),using our high resolution electron momentum spectrometer,at impact energies of 1500 eV and 600 eV.The observed momentum profiles were compared with the Hartree-Fock (HF) and density functional theory (DFT) calculations,and the binding energy spectrum was compared with the Outer valence Green's function (OVGF) calculations.The impact energy dependent discrepancy between observed momentum distributions and calculations under the plane wave impulse approximation was ascribed to the distorted wave effects.