研究了燃料电池系统测试平台空气供给系统背压阀的选取,目的是改善空气系统的动态响应特性。以15 k W燃料电池系统测试平台为例,给出系统相关参数的计算方法,对比分析了不同流量特性背压阀对空气供给系统的影响,对比了同一背压阀对不同...研究了燃料电池系统测试平台空气供给系统背压阀的选取,目的是改善空气系统的动态响应特性。以15 k W燃料电池系统测试平台为例,给出系统相关参数的计算方法,对比分析了不同流量特性背压阀对空气供给系统的影响,对比了同一背压阀对不同功率系统特性的影响和不同背压阀对同一系统特性的影响。采用已发表文献中的试验数据搭建了燃料电池系统模型并进行了开环压力控制系统动态响应特性的仿真,结果表明等百分比型背压阀更适合系统需求,适当选取Kv值(流量系数)较小的背压阀可以改善系统的调节精度,但对系统压力动态响应特性影响不大。展开更多
Through the comparison of various acquisition technology and related technology theory of the existing scheme, the paper analyze and design the power battery testing platform of the data acquisition system, and give t...Through the comparison of various acquisition technology and related technology theory of the existing scheme, the paper analyze and design the power battery testing platform of the data acquisition system, and give the research design scheme of the utility model through the design of the software on PC and CAN bus, which makes the full synchronization requirements acquisition unit; improve the linearity and stability of total voltage and current acquisition by the integrated circuit, and improve the system sampling rate, effectively complete the corresponding index. Finally, through experimental verification, to ensure the completion of the technical indicators.展开更多
The electrochemical behaviors of battery chemistry,especially the operating voltage,are greatly affected by the complex electrode/electrolyte interface,but the corresponding basis understanding is still largely unclea...The electrochemical behaviors of battery chemistry,especially the operating voltage,are greatly affected by the complex electrode/electrolyte interface,but the corresponding basis understanding is still largely unclear.Herein,the concept of regulating electrode potential by interface thermodynamics is proposed,which guides the improvement of the energy density of Zn-MnO_(2) battery.A cationic electrolyte strategy is adopted to adjust the charge density of electrical double layer,as well as entropy change caused by desolvation,thus,achieving an output voltage of 1.6 V(vs.Zn^(2+)/Zn)and a capacity of 400 mAh g^(-1).The detailed energy storage behaviors are also analyzed in terms of crystal field and energy level splitting.Furthermore,the electrolyte optimization benefits the efficient operation of Zn-MnO_(2) battery by enabling a high energy density of 532 Wh kg^(-1) based on the mass of cathode and a long cyclic life of more than 500 cycles.This work provides a path for designing high-energy-density aqueous battery via electrolyte strategy,which is expected to be extended to other battery systems.展开更多
Along with the explosive growth in the market of new energy electric vehicles,the demand for Li-ion batteries(LIBs)has correspondingly expanded.Given the limited life of LIBs,numbers of spent LIBs are bound to be prod...Along with the explosive growth in the market of new energy electric vehicles,the demand for Li-ion batteries(LIBs)has correspondingly expanded.Given the limited life of LIBs,numbers of spent LIBs are bound to be produced.Because of the severe threats and challenges of spent LIBs to the environment,resources,and global sustainable development,the recycling and reuse of spent LIBs have become urgent.Herein,we propose a novel green and efficient direct recycling method,which realizes the concurrent reuse of LiFePO_(4)(LFP)cathode and graphite anode from spent LFP batteries.By optimizing the proportion of LFP and graphite,a hybrid LFP/graphite(LFPG)cathode was designed for a new type of dualion battery(DIB)that can achieve co-participation in the storage of both anions and cations.The hybrid LFPG cathode combines the excellent stability of LFP and the high conductivity of graphite to exhibit an extraordinary electrochemical performance.The best compound,i.e.,LFP:graphite=3:1,with the highest reversible capacity(~130 mAhg^(-1) at 25 mAg^(-1)),high voltage platform of 4.95 V,and outstanding cycle performance,was achieved.The specific diffusion behavior of Li^(+) and PF_(6)^(-) in the hybrid cathode was studied using electrode kinetic tests,further clarifying the working mechanism of DIBs.This study provides a new strategy toward the large-scale recycling of positive and negative electrodes of spent LIBs and establishes a precedent for designing new hybrid cathode materials for DIBs with superior performance using spent LIBs.展开更多
文摘研究了燃料电池系统测试平台空气供给系统背压阀的选取,目的是改善空气系统的动态响应特性。以15 k W燃料电池系统测试平台为例,给出系统相关参数的计算方法,对比分析了不同流量特性背压阀对空气供给系统的影响,对比了同一背压阀对不同功率系统特性的影响和不同背压阀对同一系统特性的影响。采用已发表文献中的试验数据搭建了燃料电池系统模型并进行了开环压力控制系统动态响应特性的仿真,结果表明等百分比型背压阀更适合系统需求,适当选取Kv值(流量系数)较小的背压阀可以改善系统的调节精度,但对系统压力动态响应特性影响不大。
文摘Through the comparison of various acquisition technology and related technology theory of the existing scheme, the paper analyze and design the power battery testing platform of the data acquisition system, and give the research design scheme of the utility model through the design of the software on PC and CAN bus, which makes the full synchronization requirements acquisition unit; improve the linearity and stability of total voltage and current acquisition by the integrated circuit, and improve the system sampling rate, effectively complete the corresponding index. Finally, through experimental verification, to ensure the completion of the technical indicators.
基金supported by the National Natural Science Foundation of China(52072411,51932011)the Natural Science Foundation of Hunan Province(2021JJ20060)the Fundamental Research Funds for the Central Universities of Central South University(2021zzts0093)。
文摘The electrochemical behaviors of battery chemistry,especially the operating voltage,are greatly affected by the complex electrode/electrolyte interface,but the corresponding basis understanding is still largely unclear.Herein,the concept of regulating electrode potential by interface thermodynamics is proposed,which guides the improvement of the energy density of Zn-MnO_(2) battery.A cationic electrolyte strategy is adopted to adjust the charge density of electrical double layer,as well as entropy change caused by desolvation,thus,achieving an output voltage of 1.6 V(vs.Zn^(2+)/Zn)and a capacity of 400 mAh g^(-1).The detailed energy storage behaviors are also analyzed in terms of crystal field and energy level splitting.Furthermore,the electrolyte optimization benefits the efficient operation of Zn-MnO_(2) battery by enabling a high energy density of 532 Wh kg^(-1) based on the mass of cathode and a long cyclic life of more than 500 cycles.This work provides a path for designing high-energy-density aqueous battery via electrolyte strategy,which is expected to be extended to other battery systems.
基金supported by the National Natural Science Foundation of China(52173246 and 91963118)the 111 Project(B13013)。
文摘Along with the explosive growth in the market of new energy electric vehicles,the demand for Li-ion batteries(LIBs)has correspondingly expanded.Given the limited life of LIBs,numbers of spent LIBs are bound to be produced.Because of the severe threats and challenges of spent LIBs to the environment,resources,and global sustainable development,the recycling and reuse of spent LIBs have become urgent.Herein,we propose a novel green and efficient direct recycling method,which realizes the concurrent reuse of LiFePO_(4)(LFP)cathode and graphite anode from spent LFP batteries.By optimizing the proportion of LFP and graphite,a hybrid LFP/graphite(LFPG)cathode was designed for a new type of dualion battery(DIB)that can achieve co-participation in the storage of both anions and cations.The hybrid LFPG cathode combines the excellent stability of LFP and the high conductivity of graphite to exhibit an extraordinary electrochemical performance.The best compound,i.e.,LFP:graphite=3:1,with the highest reversible capacity(~130 mAhg^(-1) at 25 mAg^(-1)),high voltage platform of 4.95 V,and outstanding cycle performance,was achieved.The specific diffusion behavior of Li^(+) and PF_(6)^(-) in the hybrid cathode was studied using electrode kinetic tests,further clarifying the working mechanism of DIBs.This study provides a new strategy toward the large-scale recycling of positive and negative electrodes of spent LIBs and establishes a precedent for designing new hybrid cathode materials for DIBs with superior performance using spent LIBs.