以电炉灰和转炉干法(Lurgi and Thyssen Method,LT)灰为研究对象,研究了单一电炉灰和LT灰及冶金尘泥混合物料在压团工艺不同参数、游离钙不同消解率条件下对团块性能的影响。结果表明,电炉灰和LT灰的消解程度对团块性能影响显著,两者的...以电炉灰和转炉干法(Lurgi and Thyssen Method,LT)灰为研究对象,研究了单一电炉灰和LT灰及冶金尘泥混合物料在压团工艺不同参数、游离钙不同消解率条件下对团块性能的影响。结果表明,电炉灰和LT灰的消解程度对团块性能影响显著,两者的消解率均超过75%时,对压团的影响较小;推荐适宜的压团工艺参数为:黏结剂用量为4%、压团含水率为13%~14%,成型压力为20 MPa;适当降低电炉灰配比及提高电炉灰消解程度能改善压团强度、降低黏结剂用量。展开更多
Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusio...Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusion of the resulting leaching residues with caustic soda. The experimental results show that the extraction of zinc is heavily dependent on the contents of iron in the dusts. The higher iron content, the lower extraction of zinc is obtained. 53% and 38% of zinc can be extracted when both dusts were directly contacted with 5mol·L^-1 NaOH solution for 42h. The remaining zinc left in the leaching residues, which supposed to be present as zinc ferrites, can be further leached when the residues were fused with caustic soda. Quantitative extraction of zinc can be obtained from the leaching residue of Sample A while only 85% from Sample B. The extractability of zinc from dusts wit hvarious contents of iron is compared. The production flowsheet for zinc from the dusts using the process proposed is discussed.展开更多
Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash...Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash deposition was performed from the analogous objective of a 410 t/h boiler economizer to verify the rationality and reliability of the ash-deposition-monitoring model presented in order to increase the security and economy in economizer running. The analog experiment platform is a tube-shell exchanger that conforms well to the conditions of a self-modeling area. The analog flue gas in the shell side is the heated air mixed with ash, and in the tube side the fluid is water heated by the flue gas. The fluid state in the water side and the flue gas side follows the second self-modeling area. A 4-factor-3-level orthogonal table was used to schedule 9 operation conditions of orthogonal experiment, with the 4 factors being heat power, flue gas velocity, ashes grain diameter and adding ashes quantity while the three levels are different values due to different position classes in every factor. The ash deposition thermal resistances is calculated by the model with the measure parameters of temperature and pressure drop. It shows that the values of the ash deposition thermal resistances gradually increase up to a stable state. And the experimental results are reliable by F testing method at α= 0.001. Therefore, the model can be applied in online monitoring of ash deposition in a boiler economizers in power plants and provides scientific decision on ash deposition prediction and sootblowing.展开更多
Glass-ceramics obtained from the electric arc furnace molten slag of incinerator fly ash was produced by applying nucleation and crystallization through heat treatment process. The effects of nucleating agent （TiO2 a...Glass-ceramics obtained from the electric arc furnace molten slag of incinerator fly ash was produced by applying nucleation and crystallization through heat treatment process. The effects of nucleating agent （TiO2 and Cr2O3） on the crystallization kinetics and heat treatment schedule of the slag were investigated. The results show that the nucleating agents changed the crystallization phase and morphology of the obtained glass-ceramics. The optimum heat treatment schedule of the glass with TiO2 was determined as nucleation at 952 K for 1.5 h and crystal growth at 1 258 K for 1.5 h, while those values with Cr203 were estimated at 971 K for 2 h and at 1 238 K for 2 h. TiO2 acting as nucleating agent could decrease the activation energy of the slag and shorten the total thermal treatment time in comparison with Cr2O3. The glass-ceramics obtained under the optimum heat treatment condition was environmentfriendly and had remarkable physical/mechanical properties and chemical durability.展开更多
文摘以电炉灰和转炉干法(Lurgi and Thyssen Method,LT)灰为研究对象,研究了单一电炉灰和LT灰及冶金尘泥混合物料在压团工艺不同参数、游离钙不同消解率条件下对团块性能的影响。结果表明,电炉灰和LT灰的消解程度对团块性能影响显著,两者的消解率均超过75%时,对压团的影响较小;推荐适宜的压团工艺参数为:黏结剂用量为4%、压团含水率为13%~14%,成型压力为20 MPa;适当降低电炉灰配比及提高电炉灰消解程度能改善压团强度、降低黏结剂用量。
文摘Extractability of zinc from two types of electric arc furnace (EAF) dusts containing 24.8% and 16.8% of zinc respectively (denoted as Sample A and Sample B) were tested using direct alkaline leaching followed by fusion of the resulting leaching residues with caustic soda. The experimental results show that the extraction of zinc is heavily dependent on the contents of iron in the dusts. The higher iron content, the lower extraction of zinc is obtained. 53% and 38% of zinc can be extracted when both dusts were directly contacted with 5mol·L^-1 NaOH solution for 42h. The remaining zinc left in the leaching residues, which supposed to be present as zinc ferrites, can be further leached when the residues were fused with caustic soda. Quantitative extraction of zinc can be obtained from the leaching residue of Sample A while only 85% from Sample B. The extractability of zinc from dusts wit hvarious contents of iron is compared. The production flowsheet for zinc from the dusts using the process proposed is discussed.
文摘Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash deposition was performed from the analogous objective of a 410 t/h boiler economizer to verify the rationality and reliability of the ash-deposition-monitoring model presented in order to increase the security and economy in economizer running. The analog experiment platform is a tube-shell exchanger that conforms well to the conditions of a self-modeling area. The analog flue gas in the shell side is the heated air mixed with ash, and in the tube side the fluid is water heated by the flue gas. The fluid state in the water side and the flue gas side follows the second self-modeling area. A 4-factor-3-level orthogonal table was used to schedule 9 operation conditions of orthogonal experiment, with the 4 factors being heat power, flue gas velocity, ashes grain diameter and adding ashes quantity while the three levels are different values due to different position classes in every factor. The ash deposition thermal resistances is calculated by the model with the measure parameters of temperature and pressure drop. It shows that the values of the ash deposition thermal resistances gradually increase up to a stable state. And the experimental results are reliable by F testing method at α= 0.001. Therefore, the model can be applied in online monitoring of ash deposition in a boiler economizers in power plants and provides scientific decision on ash deposition prediction and sootblowing.
基金Supported by the National Natural Science Foundation of China(No.51378332 and No.20806051)Science and Technology Project of Housing and Urban-Rural Ministry(No.2014-K4-014)Chinese Postdoctoral Science Foundation(No.2013M530872)
文摘Glass-ceramics obtained from the electric arc furnace molten slag of incinerator fly ash was produced by applying nucleation and crystallization through heat treatment process. The effects of nucleating agent （TiO2 and Cr2O3） on the crystallization kinetics and heat treatment schedule of the slag were investigated. The results show that the nucleating agents changed the crystallization phase and morphology of the obtained glass-ceramics. The optimum heat treatment schedule of the glass with TiO2 was determined as nucleation at 952 K for 1.5 h and crystal growth at 1 258 K for 1.5 h, while those values with Cr203 were estimated at 971 K for 2 h and at 1 238 K for 2 h. TiO2 acting as nucleating agent could decrease the activation energy of the slag and shorten the total thermal treatment time in comparison with Cr2O3. The glass-ceramics obtained under the optimum heat treatment condition was environmentfriendly and had remarkable physical/mechanical properties and chemical durability.
