The generation of oxide charge for 4nm pMOSFETs under hot-carrier stress is investigated by the charge pumping measurements.Firstly,the direct experimental evidences of logarithmic time dependence of hole trapping is ...The generation of oxide charge for 4nm pMOSFETs under hot-carrier stress is investigated by the charge pumping measurements.Firstly,the direct experimental evidences of logarithmic time dependence of hole trapping is observed for pMOSFETs with different channel lengths under hot-carrier stress.Thus,the relationships of oxide charge generation,including electron trapping and hole trapping effects,with different stress voltages and channel lengths are analyzed.It is also found that there is a two-step process in the generation of oxide charge for pMOSFETs.For a short stress time,electron trapping is predominant,whereas for a long stress time,hole trapping dominates the generation of oxide charge.展开更多
Common solar-driven photoelectrochemical(PEC) cells for water splitting were designed by using semiconducting photoactive materials as working photoelectrodes to capture sunlight. Due to the thermodynamic requirement ...Common solar-driven photoelectrochemical(PEC) cells for water splitting were designed by using semiconducting photoactive materials as working photoelectrodes to capture sunlight. Due to the thermodynamic requirement of 1.23 eV and kinetic energy loss of about 0.6 eV, a photo-voltage of 1.8 V produced by PEC cells is generally required for spontaneous water splitting. Therefore, the minimum bandgap of1.8 eV is demanded for photoactive materials in single-photoelectrode PEC cells, and the bandgap of about 1 eV for back photoactive materials is appropriate in tandem PEC cells. All these PEC cells cannot effectively utilize the infrared light from 1250 to 2500 nm. In order to realize the full spectrum utilization of solar light, here, we develop a solar-driven PEC water splitting system integrated with a thermoelectric device. The key feature of this system is that the thermoelectric device produces a voltage as an additional bias for the PEC system by using the temperature difference between the incident infrared-light heated aqueous electrolyte in the PEC cell as the hot source and unirradiated external water as the cold source. Compared to a reference PEC system without the thermoelectric device, this system has a significantly improved overall water splitting activity of 1.6 times and may provide a strategy for accelerating the application of full spectrum solar light-driven PEC cells for hydrogen production.展开更多
As a simple binary compound, p-type SnS shows great competitiveness in thermoelectrics due to the certain appealing carrier and phonon transport behaviors, coupled with its cost-effectiveness, earth-abundance and envi...As a simple binary compound, p-type SnS shows great competitiveness in thermoelectrics due to the certain appealing carrier and phonon transport behaviors, coupled with its cost-effectiveness, earth-abundance and environmental compatibility. To promote the application of low-cost thermoelectric devices, we synthesized n-type SnS crystals through bromine doping. Herein, we report a high in-plane power factor of ~28 μW cm^(-1)K^(-2), and attribute it to an outstanding in-plane carrier mobility in the crystal form and the large Seebeck coefficient benefitting from the low carrier concentration. The calculations of elastic properties show that the low lattice thermal conductivity in SnS is closely related to its strong anharmonicity. Combining the excellent electrical transport properties with low thermal conductivity, a final ZT of ~0.4 is attained at 300 K, projecting a conversion efficiency of ~5% at 873 K along the in-plane direction.展开更多
During the past six years comprehensive research programs have been conducted at the Beijing Polytechnic University to provide a better understanding of heat transfer characteristics of existing and condidate cool- in...During the past six years comprehensive research programs have been conducted at the Beijing Polytechnic University to provide a better understanding of heat transfer characteristics of existing and condidate cool- ing techniques for electronic and microelectronic devices.This paper provides a review and summary of the programs with emphasis on direct liquid cooling.Included in this review are the heat transfer investigations related to the following cooling modes:liquid free,mixed and forced convection,liquid jet impingement,flowing liquid film cooling,pool boiling,spray cooling,foreign gas jet impingement in liquid pool,and forced convection air-cooling.展开更多
The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of ...The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of our society needs advanced thermal management with low,even zero,energy consumption.Harvesting water from the atmosphere,followed by moisture desorption to dissipate heat,is an efficient and feasible approach for zero-energy-consumption thermal management.However,current methods are limited by the low absorbance of water,low water vapor transmission rate(WVTR)and low stability,thus resulting in low thermal management capability.In this study,we report an innovative electrospinning method to process hierarchically porous metal–organic framework(MOF)composite fabrics with high-efficiency and zero-energy-consumption thermal management.The composite fabrics are highly loaded with MOF(75 wt%)and their WVTR value can be up to 3138 g m^(-2) d^(-1).The composite fabrics also exhibit stable microstructure and performance.Under a conventional environment(30℃,60%relative humidity),the composite fabrics adsorb water vapor for regeneration within 1.5 h to a saturated value Wsat of 0.614 g g^(-1),and a corresponding equivalent enthalpy of 1705.6 J g^(-1).In the thermal management tests,the composite fabrics show a strong cooling capability and significantly improve the performance of thermoelectric devices,portable storage devices and wireless chargers.These results suggest that hierarchically porous MOF composite fabrics are highly promising for thermal management of intermittent-operation electronic devices.展开更多
Thermoelectric devices require thermoelectric materials with high figure-of-merit(ZT)values in the operating temperature range.In recent years,the Zintl phase compound,n-Mg_(3)Sb_(2),has received much attention owing ...Thermoelectric devices require thermoelectric materials with high figure-of-merit(ZT)values in the operating temperature range.In recent years,the Zintl phase compound,n-Mg_(3)Sb_(2),has received much attention owing to its rich chemistry and structural complexity.However,it hardly achieves high ZT values throughout the medium temperature range.Herein,by increasing the sintering temperature as much as possible,we successfully increased the average grain size of the compound by 15 times,and the grain boundary scattering was manipulated to obtain high carrier mobility of up to 180 cm^(2)V^(-1)s^(-1).Simultaneously,we optimized the Mg content for ultralow lattice thermal conductivity.We first doped the Mg_(3)Sb_(2)-based materials with boron for higher sintering temperature,good thermal stability,and higher hardness.The synergistic optimization of electrical and thermal transport resulted in excellent ZT values(0.62 at 300 K,1.81 at 773 K)and an average ZT of 1.4(from300 to 773 K),which are higher than the state-of-the-art values for n-type thermoelectric materials,demonstrating a high potential in device applications.展开更多
Thermoelectric oxide nanofibers prepared by electrospinning are expected to have reduced thermal conductivity when compared to bulk samples. Measurements of nanofibers' thermal conductivity is challenging since it in...Thermoelectric oxide nanofibers prepared by electrospinning are expected to have reduced thermal conductivity when compared to bulk samples. Measurements of nanofibers' thermal conductivity is challenging since it involves sophisticated sample preparation methods. In this work, we present a novel method suitable for measurements of thermal conductivity of a single nanofiber. A microelectro- mechanical (MEMS) device has been designed and fabricated to perform thermal conductivity measurements on a single nanofiber. A special Si template was designed to collect and transfer individual nanofibers onto a MEMS device. Pt was deposited by a focused ion beam to reduce the effective length of a prepared nanofiber. La0.95r0.05CoO3 nanofibers with diameters of 140 run and 290 run were studied and characterized using this approach at room temperature. Measured thermal conductivities yielded values of 0.7W-m 1-K-1 and 2.1 W.m-I'K-1, respectively. Our measurements in La0.95r0.05CoO3 nanofibers confirmed that a decrease of linear dimensions has a profound effect on its thermal conductivity.展开更多
A full solution of two-dimensional Navier-Stokes and energy equation was conducted numerically to analyze the natural convection of the horizontal strip with an adiabatic substrate. The main features of such convectio...A full solution of two-dimensional Navier-Stokes and energy equation was conducted numerically to analyze the natural convection of the horizontal strip with an adiabatic substrate. The main features of such convection are: (i) the leading and trailing edge effect, (ii) the non-boundary layer effect, and (iii) the side edge effect. The results are compared with the boundary layer theory and experimental data.展开更多
Hydrothermal deposition of antimony selenosulfide(Sb_(2)(S,Se_(3)))has enabled solar cell applications to surpass the 10%efficiency threshold.This deposition process involves the reaction of three precursor materials:...Hydrothermal deposition of antimony selenosulfide(Sb_(2)(S,Se_(3)))has enabled solar cell applications to surpass the 10%efficiency threshold.This deposition process involves the reaction of three precursor materials:Sb,S,and Se.However,this process generates an unfavourable gradient of Se and S anions in the Sb_(2)(S,Se)_(3)film,which limits further efficiency improvements.Herein,we demonstrate how NH_(4)F can be used as an additive to regulate the band gradient of the Sb_(2)(S,Se)_(3)and modify the surface of the CdS electron-transporting layer.On the one hand,NH_(4)F inhibits the decomposition of Na_(2)S_(2)O_(3)and selenourea,which optimizes the deposition process and allows for adjustment of the Se/S ratio and their distribution in the Sb_(2)(S,Se)_(3)film.On the other hand,hydrolysis of NH_(4)F induces dissolution and redeposition of CdS,thereby effectively improving the morphology and crystallinity of the CdS substrate.Finally,the dual effect of NH_(4)F enables improved surface morphology and energy alignment of the Sb_(2)(S,Se)_(3)film,thus yielding a maximum efficiency of 10.28%,a 12%improvement over the control device.This study demonstrates an effective strategy for simultaneously modifying a sulfide-based substrate and regulating the element distribution during the deposition of a metal chalcogenide film for optoelectronic device applications.展开更多
Micro heat pipe(MHP) is applied to implement the efficient heat transfer of light emitting diode(LED) device.The fabrication of MHP is based on micro-electro-mechanical-system(MEMS) technique,15 micro grooves were etc...Micro heat pipe(MHP) is applied to implement the efficient heat transfer of light emitting diode(LED) device.The fabrication of MHP is based on micro-electro-mechanical-system(MEMS) technique,15 micro grooves were etched on one side of silicon(Si) substrate,which was then packaged with aluminum heat sink to form an MHP.On the other side of Si substrate,three LED chips were fixed by die bonding.Then experiments were performed to study the thermal performance of this LED device.The results show that the LED device with higher filling ratio is better when the input power is 1.0 W; with the increase of input power,the optimum filling ratio changes from 30% to 48%,and the time reaching stable state is reduced; when the input power is equal to 2.5 W,only the LED device with filling ratio of 48% can work normally.So integrating MHP into high-power LED device can implement the effective control of junction temperature.展开更多
This paper discusses air forced convection heat transfer from inline protruding elements arranged in eight rows. The streamwise and spanwise spacings between elements were varied using a splitter plate that can be pos...This paper discusses air forced convection heat transfer from inline protruding elements arranged in eight rows. The streamwise and spanwise spacings between elements were varied using a splitter plate that can be positioned at three different modular configurations. A set of empirical formulas waspresented to correlate the experimental data for the design of air cooling systems. Arrays of components with one odd-size module have been tested also. Experimental results show that blocks near the entrance and behind the odd-size module have improved performance compared with uniform arrangements. Accordingly, temperature sensitive components are suggested to be arranged in these locations.展开更多
We report thermoelectric transport measurements across a graphene/hexagonal boron nitride (h-BN)/graphene heterostructure device. Using an AC lock-in technique, we are able to separate the thermoelectric contributio...We report thermoelectric transport measurements across a graphene/hexagonal boron nitride (h-BN)/graphene heterostructure device. Using an AC lock-in technique, we are able to separate the thermoelectric contribution to the I-V characteristics of these important device structures. The temperature gradient is measured optically using Raman spectroscopy, which enables us to explore thermoelectric transport produced at material interfaces, across length scales of just 1-2 nm. Based on the observed thermoelectric voltage (AV) and tem- perature gradient (AT), a Seebeck coefficient of -99.3 μV/K is ascertained for the heterostructure device. The obtained Seebeck coefficient can be useful for understanding the thermoelectric component in the cross-plane I-V behaviors of emerging 2D heterostructure devices. These results provide an approach to probing thermoelectric energy conversion in two-dimensional layered heterostructures.展开更多
Thermal management is a key issue in the integrated circuit(IC)design.In this paper,the superposition strategy was experimentally validated using a modeling IC device,which was fabricated by laboratory-level microfabr...Thermal management is a key issue in the integrated circuit(IC)design.In this paper,the superposition strategy was experimentally validated using a modeling IC device,which was fabricated by laboratory-level microfabrication technique.Metal thin film resistors on the top of dielectric layer were used to analogize the multiple hot-spots in the modeling IC device.The measured temperature rise with multiple hot-spots agrees well with the predictions given by the superposition calculations.With the help of the superposition strategy,thermal management of IC device can be significantly simplified by decomposing the system into sub-systems and optimizing each part individually.The influence coefficients in the superposition strategy extracted from the experimental measurement offer the IC designers a useful engineering tool to facility the thermal optimization and evaluate the thermal performance of IC devices.展开更多
文摘The generation of oxide charge for 4nm pMOSFETs under hot-carrier stress is investigated by the charge pumping measurements.Firstly,the direct experimental evidences of logarithmic time dependence of hole trapping is observed for pMOSFETs with different channel lengths under hot-carrier stress.Thus,the relationships of oxide charge generation,including electron trapping and hole trapping effects,with different stress voltages and channel lengths are analyzed.It is also found that there is a two-step process in the generation of oxide charge for pMOSFETs.For a short stress time,electron trapping is predominant,whereas for a long stress time,hole trapping dominates the generation of oxide charge.
基金This work was supported by the National Natural Science Foundation of China(51825204 and 51629201)the Key Research Program of Frontier Sciences CAS(QYZDB-SSW-JSC039).
文摘Common solar-driven photoelectrochemical(PEC) cells for water splitting were designed by using semiconducting photoactive materials as working photoelectrodes to capture sunlight. Due to the thermodynamic requirement of 1.23 eV and kinetic energy loss of about 0.6 eV, a photo-voltage of 1.8 V produced by PEC cells is generally required for spontaneous water splitting. Therefore, the minimum bandgap of1.8 eV is demanded for photoactive materials in single-photoelectrode PEC cells, and the bandgap of about 1 eV for back photoactive materials is appropriate in tandem PEC cells. All these PEC cells cannot effectively utilize the infrared light from 1250 to 2500 nm. In order to realize the full spectrum utilization of solar light, here, we develop a solar-driven PEC water splitting system integrated with a thermoelectric device. The key feature of this system is that the thermoelectric device produces a voltage as an additional bias for the PEC system by using the temperature difference between the incident infrared-light heated aqueous electrolyte in the PEC cell as the hot source and unirradiated external water as the cold source. Compared to a reference PEC system without the thermoelectric device, this system has a significantly improved overall water splitting activity of 1.6 times and may provide a strategy for accelerating the application of full spectrum solar light-driven PEC cells for hydrogen production.
基金supported by Beijing Natural Science Foundation (JQ18004)the National Key Research and Development Program of China (2018YFA0702100 and 2018YFB0703600)+4 种基金the National Natural Science Foundation of China (51772012)Shenzhen Peacock Plan team (KQTD2016022619565991)the National Postdoctoral Program for Innovative Talents (BX20200028)the 111 Project (B17002)support from the National Science Fund for Distinguished Young Scholars (51925101)。
文摘As a simple binary compound, p-type SnS shows great competitiveness in thermoelectrics due to the certain appealing carrier and phonon transport behaviors, coupled with its cost-effectiveness, earth-abundance and environmental compatibility. To promote the application of low-cost thermoelectric devices, we synthesized n-type SnS crystals through bromine doping. Herein, we report a high in-plane power factor of ~28 μW cm^(-1)K^(-2), and attribute it to an outstanding in-plane carrier mobility in the crystal form and the large Seebeck coefficient benefitting from the low carrier concentration. The calculations of elastic properties show that the low lattice thermal conductivity in SnS is closely related to its strong anharmonicity. Combining the excellent electrical transport properties with low thermal conductivity, a final ZT of ~0.4 is attained at 300 K, projecting a conversion efficiency of ~5% at 873 K along the in-plane direction.
文摘During the past six years comprehensive research programs have been conducted at the Beijing Polytechnic University to provide a better understanding of heat transfer characteristics of existing and condidate cool- ing techniques for electronic and microelectronic devices.This paper provides a review and summary of the programs with emphasis on direct liquid cooling.Included in this review are the heat transfer investigations related to the following cooling modes:liquid free,mixed and forced convection,liquid jet impingement,flowing liquid film cooling,pool boiling,spray cooling,foreign gas jet impingement in liquid pool,and forced convection air-cooling.
基金supported by the National Natural Science Foundation of China(51877132,U19A20105,and 52003153)the Program of Shanghai Academic Research Leader(21XD1401600)。
文摘The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of our society needs advanced thermal management with low,even zero,energy consumption.Harvesting water from the atmosphere,followed by moisture desorption to dissipate heat,is an efficient and feasible approach for zero-energy-consumption thermal management.However,current methods are limited by the low absorbance of water,low water vapor transmission rate(WVTR)and low stability,thus resulting in low thermal management capability.In this study,we report an innovative electrospinning method to process hierarchically porous metal–organic framework(MOF)composite fabrics with high-efficiency and zero-energy-consumption thermal management.The composite fabrics are highly loaded with MOF(75 wt%)and their WVTR value can be up to 3138 g m^(-2) d^(-1).The composite fabrics also exhibit stable microstructure and performance.Under a conventional environment(30℃,60%relative humidity),the composite fabrics adsorb water vapor for regeneration within 1.5 h to a saturated value Wsat of 0.614 g g^(-1),and a corresponding equivalent enthalpy of 1705.6 J g^(-1).In the thermal management tests,the composite fabrics show a strong cooling capability and significantly improve the performance of thermoelectric devices,portable storage devices and wireless chargers.These results suggest that hierarchically porous MOF composite fabrics are highly promising for thermal management of intermittent-operation electronic devices.
基金supported by the National Natural Science Foundation of China(51771065 and 51871082)the Natural Science Foundation of Heilongjiang Province of China(ZD2020E003)。
文摘Thermoelectric devices require thermoelectric materials with high figure-of-merit(ZT)values in the operating temperature range.In recent years,the Zintl phase compound,n-Mg_(3)Sb_(2),has received much attention owing to its rich chemistry and structural complexity.However,it hardly achieves high ZT values throughout the medium temperature range.Herein,by increasing the sintering temperature as much as possible,we successfully increased the average grain size of the compound by 15 times,and the grain boundary scattering was manipulated to obtain high carrier mobility of up to 180 cm^(2)V^(-1)s^(-1).Simultaneously,we optimized the Mg content for ultralow lattice thermal conductivity.We first doped the Mg_(3)Sb_(2)-based materials with boron for higher sintering temperature,good thermal stability,and higher hardness.The synergistic optimization of electrical and thermal transport resulted in excellent ZT values(0.62 at 300 K,1.81 at 773 K)and an average ZT of 1.4(from300 to 773 K),which are higher than the state-of-the-art values for n-type thermoelectric materials,demonstrating a high potential in device applications.
文摘Thermoelectric oxide nanofibers prepared by electrospinning are expected to have reduced thermal conductivity when compared to bulk samples. Measurements of nanofibers' thermal conductivity is challenging since it involves sophisticated sample preparation methods. In this work, we present a novel method suitable for measurements of thermal conductivity of a single nanofiber. A microelectro- mechanical (MEMS) device has been designed and fabricated to perform thermal conductivity measurements on a single nanofiber. A special Si template was designed to collect and transfer individual nanofibers onto a MEMS device. Pt was deposited by a focused ion beam to reduce the effective length of a prepared nanofiber. La0.95r0.05CoO3 nanofibers with diameters of 140 run and 290 run were studied and characterized using this approach at room temperature. Measured thermal conductivities yielded values of 0.7W-m 1-K-1 and 2.1 W.m-I'K-1, respectively. Our measurements in La0.95r0.05CoO3 nanofibers confirmed that a decrease of linear dimensions has a profound effect on its thermal conductivity.
文摘A full solution of two-dimensional Navier-Stokes and energy equation was conducted numerically to analyze the natural convection of the horizontal strip with an adiabatic substrate. The main features of such convection are: (i) the leading and trailing edge effect, (ii) the non-boundary layer effect, and (iii) the side edge effect. The results are compared with the boundary layer theory and experimental data.
基金the National Natural Science Foundation of China(22005293 and U19A2092)the National Key Research and Development Program of China(2019YFA0405600).
文摘Hydrothermal deposition of antimony selenosulfide(Sb_(2)(S,Se_(3)))has enabled solar cell applications to surpass the 10%efficiency threshold.This deposition process involves the reaction of three precursor materials:Sb,S,and Se.However,this process generates an unfavourable gradient of Se and S anions in the Sb_(2)(S,Se)_(3)film,which limits further efficiency improvements.Herein,we demonstrate how NH_(4)F can be used as an additive to regulate the band gradient of the Sb_(2)(S,Se)_(3)and modify the surface of the CdS electron-transporting layer.On the one hand,NH_(4)F inhibits the decomposition of Na_(2)S_(2)O_(3)and selenourea,which optimizes the deposition process and allows for adjustment of the Se/S ratio and their distribution in the Sb_(2)(S,Se)_(3)film.On the other hand,hydrolysis of NH_(4)F induces dissolution and redeposition of CdS,thereby effectively improving the morphology and crystallinity of the CdS substrate.Finally,the dual effect of NH_(4)F enables improved surface morphology and energy alignment of the Sb_(2)(S,Se)_(3)film,thus yielding a maximum efficiency of 10.28%,a 12%improvement over the control device.This study demonstrates an effective strategy for simultaneously modifying a sulfide-based substrate and regulating the element distribution during the deposition of a metal chalcogenide film for optoelectronic device applications.
基金supported by the State Key Development Program for Basic Research of China(No.2011CB013105)
文摘Micro heat pipe(MHP) is applied to implement the efficient heat transfer of light emitting diode(LED) device.The fabrication of MHP is based on micro-electro-mechanical-system(MEMS) technique,15 micro grooves were etched on one side of silicon(Si) substrate,which was then packaged with aluminum heat sink to form an MHP.On the other side of Si substrate,three LED chips were fixed by die bonding.Then experiments were performed to study the thermal performance of this LED device.The results show that the LED device with higher filling ratio is better when the input power is 1.0 W; with the increase of input power,the optimum filling ratio changes from 30% to 48%,and the time reaching stable state is reduced; when the input power is equal to 2.5 W,only the LED device with filling ratio of 48% can work normally.So integrating MHP into high-power LED device can implement the effective control of junction temperature.
文摘This paper discusses air forced convection heat transfer from inline protruding elements arranged in eight rows. The streamwise and spanwise spacings between elements were varied using a splitter plate that can be positioned at three different modular configurations. A set of empirical formulas waspresented to correlate the experimental data for the design of air cooling systems. Arrays of components with one odd-size module have been tested also. Experimental results show that blocks near the entrance and behind the odd-size module have improved performance compared with uniform arrangements. Accordingly, temperature sensitive components are suggested to be arranged in these locations.
文摘We report thermoelectric transport measurements across a graphene/hexagonal boron nitride (h-BN)/graphene heterostructure device. Using an AC lock-in technique, we are able to separate the thermoelectric contribution to the I-V characteristics of these important device structures. The temperature gradient is measured optically using Raman spectroscopy, which enables us to explore thermoelectric transport produced at material interfaces, across length scales of just 1-2 nm. Based on the observed thermoelectric voltage (AV) and tem- perature gradient (AT), a Seebeck coefficient of -99.3 μV/K is ascertained for the heterostructure device. The obtained Seebeck coefficient can be useful for understanding the thermoelectric component in the cross-plane I-V behaviors of emerging 2D heterostructure devices. These results provide an approach to probing thermoelectric energy conversion in two-dimensional layered heterostructures.
基金supported by the National Science and Technology Major Project of China(Grant No.2009ZX02038-02)the Doctoral Fund of Ministry of Education of China(Grant No.20130001110006)
文摘Thermal management is a key issue in the integrated circuit(IC)design.In this paper,the superposition strategy was experimentally validated using a modeling IC device,which was fabricated by laboratory-level microfabrication technique.Metal thin film resistors on the top of dielectric layer were used to analogize the multiple hot-spots in the modeling IC device.The measured temperature rise with multiple hot-spots agrees well with the predictions given by the superposition calculations.With the help of the superposition strategy,thermal management of IC device can be significantly simplified by decomposing the system into sub-systems and optimizing each part individually.The influence coefficients in the superposition strategy extracted from the experimental measurement offer the IC designers a useful engineering tool to facility the thermal optimization and evaluate the thermal performance of IC devices.