In this paper, a novel micro drop solvent extraction technique jonied with low temperature ETV-ICP-AES for ultra trace element analysis is reported. The apparatus of micro drop solvent extraction was designed, and pre...In this paper, a novel micro drop solvent extraction technique jonied with low temperature ETV-ICP-AES for ultra trace element analysis is reported. The apparatus of micro drop solvent extraction was designed, and preliminary investigation was made for the extraction of ultra trace La by a micro drop of 0.05 mol/L PMBP-benzene(2 μL). It was found that 500-fold concentration of ultra-trace La in 1 mL solution was achieved in 0.2 mL of glass chamber by a single micro drop of PMBP-benzene suspended on the tip of a 10 μL of microsyringe. The future development of micro drop solvent extraction technique in atomic spectrometry was briefly discussed.展开更多
A new method of combination micro column packed with 2 ethylhexyl hydrogen 2 ethylhexyl phosphonate(P 507 ) extraction resin with electrothermal vaporization inductively coupled plasma atomic emission spectrometry(ETV...A new method of combination micro column packed with 2 ethylhexyl hydrogen 2 ethylhexyl phosphonate(P 507 ) extraction resin with electrothermal vaporization inductively coupled plasma atomic emission spectrometry(ETV ICP AES) for separation and determination of trace rare earth elements(lanthanum, europium, yttrium and ytterbium) has been developed. Various influencing factors, such as the acidity of solution, flow rate and the volume of the sample, the length of the micro column on the separation and the preconcentration are examined in detail, the effect of the existence of organic matrix and the pre ashing temperature on determination of rare earth elements by ETV ICP AES has also been studied.展开更多
文摘In this paper, a novel micro drop solvent extraction technique jonied with low temperature ETV-ICP-AES for ultra trace element analysis is reported. The apparatus of micro drop solvent extraction was designed, and preliminary investigation was made for the extraction of ultra trace La by a micro drop of 0.05 mol/L PMBP-benzene(2 μL). It was found that 500-fold concentration of ultra-trace La in 1 mL solution was achieved in 0.2 mL of glass chamber by a single micro drop of PMBP-benzene suspended on the tip of a 10 μL of microsyringe. The future development of micro drop solvent extraction technique in atomic spectrometry was briefly discussed.
文摘A new method of combination micro column packed with 2 ethylhexyl hydrogen 2 ethylhexyl phosphonate(P 507 ) extraction resin with electrothermal vaporization inductively coupled plasma atomic emission spectrometry(ETV ICP AES) for separation and determination of trace rare earth elements(lanthanum, europium, yttrium and ytterbium) has been developed. Various influencing factors, such as the acidity of solution, flow rate and the volume of the sample, the length of the micro column on the separation and the preconcentration are examined in detail, the effect of the existence of organic matrix and the pre ashing temperature on determination of rare earth elements by ETV ICP AES has also been studied.