An optimal design method for an aircraft low-power thermoelectric refrigeration system（TRS）is proposed using an existing experimental model as the research platform under given aircraft flight conditions.The variati...An optimal design method for an aircraft low-power thermoelectric refrigeration system（TRS）is proposed using an existing experimental model as the research platform under given aircraft flight conditions.The variation curves of the cooling capacities and the refrigeration coefficients of the system running at three flight altitudes are investigated.The performance of the system is evaluated by the minimum-entropy-generation method and the performance penalty is also calculated.The power variation curves of the cooling system are obtained by an electric power experiment.The peak values of these curves are less than the maximal electric power supply of airborne equipment,proving that the use of the low-power TRS for airborne equipment is feasible.The COP,cooling capacity and entropy generation of the system are relative to the flight altitude and the current of the TRS.Through the analyses of these data,the optimal values of the COP are obtained,and the optimization measures are proposed to maximize the use of the advantages of the TRS.展开更多
This paper presents a low power,truly random number generator （TRNG） based on a simple chaotic map of the Bernoulli shift,which is extended to remain robustness in implementation. The map is realized by switched-cur...This paper presents a low power,truly random number generator （TRNG） based on a simple chaotic map of the Bernoulli shift,which is extended to remain robustness in implementation. The map is realized by switched-current techniques that can fully integrate it in a cryptosystem on a chip. A pipelined architecture post-processed by a simple XOR circuit is used to improve the entropy. The TRNG is fabricated in an HJTC 0.18μm CMOS mixed signal process,and the statistical properties are investigated by measurement results. The power consumption is only 1.42mW and the truly random output bit rate is 10Mbit/s.展开更多
With the entropy generation minimization （EGM） method, the thermodynamical performance optimization in a thermoelectric refrigeration system is studied. The optimization is affected by the irreversibility of heat tr...With the entropy generation minimization （EGM） method, the thermodynamical performance optimization in a thermoelectric refrigeration system is studied. The optimization is affected by the irreversibility of heat transfer caused by finite temperature differences, the heat leak between external heat reservoirs and the internal dissipation of working fluids. EGM is taken as an objective function for the optimization. The objective function and design parameters are obtained. Optimal performance curves are presented by thermal and electronic parameters. Effects of these parameters on general and optimal performances are investigated. Results are helpful in determining optimal design conditions in real thermoelectric refrigeration systems.展开更多
The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ...The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ensemble (GCE) that the kinetic energy distribution of the solute is a common characteristic of the entropy and the distribution of solute zones.Under the assumptions. EI of the solute system is directly proportional to the logarithm of the difference between one and one half of the substantial separation ratio. the ratio of moles of a sparated solute to its total moles. and EIPUT is direchy proportional to corrected separation rate of separation system. EI or EIPUT is a important bridge between separation efficiency of chromatography or electrophoresis and operating parameters, especially. when nonequilibriumthermodynamics(NET) would be adopted.展开更多
The oxidation behaviors of high-entropy alloys AlxCoCrFeNi(x=0.15, 0.4) in supercritical water at 550 and 600 °C were studied, and compared with HR3 C steel. All oxide films formed on alloys are composed of spine...The oxidation behaviors of high-entropy alloys AlxCoCrFeNi(x=0.15, 0.4) in supercritical water at 550 and 600 °C were studied, and compared with HR3 C steel. All oxide films formed on alloys are composed of spinel type(Fe, Cr)3O4 oxides. Compared with the oxide film on HR3 C steel, thinner oxide films with smaller size of oxide particles were realized on Al0.15 CoCrFeNi and Al0.4CoCrFeNi, indicating a superior oxidation resistance of Al0.15 CoCrFeNi and Al0.4CoCrFeNi to HR3 C steel. Electrochemical test results reveal that surface oxide films greatly affect the electrochemical corrosion behavior of the oxidized alloys in 3.5% Na Cl solution. The relatively high corrosion resistance of oxidized Al0.15 CoCrFeNi and HR3 C is attributed to the formation of thick and multi-layer oxides.展开更多
A thrust for looking multifunctional materials for applications in civil engineering structures has attracted interest among researchers across the globe.Cement based Ba0.85Ca0.15Zr0.1Ti0.88Sn0.02O3(BCZT.Sn)composites...A thrust for looking multifunctional materials for applications in civil engineering structures has attracted interest among researchers across the globe.Cement based Ba0.85Ca0.15Zr0.1Ti0.88Sn0.02O3(BCZT.Sn)composites were prepared for electrocaloric applications with varying BCZT.Sn to cement ratio.Hysteresis loops showed some signature of saturation in cement composites.However,loops of pure sample were saturated due to its ferroelectric nature.Furthermore,these composites were explored for the first time in solid state refrigeration technology namely electrocaloric effect(ECE).Peak electrocaloric performance shows an adiabatic temperature changes of 0.71,0.64 and 0.50 K and isothermal entropy changes of 0.86,0.80 and 0.65 J/(kg.K)for BCZT.Sn,10%and 15%cement composites,respectively,under application of 0-29 kV/cm electric field.The adiabatic temperature change in cement based composites is comparable with that of the BCZT-Sn ferroelectric ceramics.Furthermore,the dielectric constant(εr)of composites with different ceramic contents at room temperature reveals that dielectric constant increases with an increase in BCZT-Sn proportion in composites.These cement based BCZT.Sn composite materials may be used in solid state refrigeration as they are fairly competitive with the pristine sample.展开更多
We study the dynamics of the entropy correlations and entanglement in a system of interaction of a superconducting charge qubit with a single-mode resonant cavity subject to noise considered as two-state random phase ...We study the dynamics of the entropy correlations and entanglement in a system of interaction of a superconducting charge qubit with a single-mode resonant cavity subject to noise considered as two-state random phase telegraph noise. We show that although the noise has an apparent suppressing effect on the evolution of the entropies of the qubit and the field and also on the entanglement in the system, the entropy exchange between the qubit and the field is independent of it during the time evolution of the system.展开更多
In this work, we discussed the stochastic thermodynamics of mesoscopic electron transfer reactions between ions and electrodes. With a relationship between the reaction rate con- stant and the electrode potential, we ...In this work, we discussed the stochastic thermodynamics of mesoscopic electron transfer reactions between ions and electrodes. With a relationship between the reaction rate con- stant and the electrode potential, we find that the heat dissipation βq equals to the dynamic irreversibility of the reaction system minus an internal entropy change term. The total en- tropy change Ast is defined as the summation of the system entropy change As and the heat dissipation/βq such that △st=△s＋βq. Even though the heat dissipation depends linearly on the electrode potential, the total entropy change is found to satisfy the fluctuation theo- rem 〈e-△st 〉=1, and hence a second law-like inequality reads （△st）≥0. Our study provides a practical methodology for the stochastic thermodynamics of electrochemical reactions, which may find applications in biochemical and electrochemical reaction systems.展开更多
文摘An optimal design method for an aircraft low-power thermoelectric refrigeration system（TRS）is proposed using an existing experimental model as the research platform under given aircraft flight conditions.The variation curves of the cooling capacities and the refrigeration coefficients of the system running at three flight altitudes are investigated.The performance of the system is evaluated by the minimum-entropy-generation method and the performance penalty is also calculated.The power variation curves of the cooling system are obtained by an electric power experiment.The peak values of these curves are less than the maximal electric power supply of airborne equipment,proving that the use of the low-power TRS for airborne equipment is feasible.The COP,cooling capacity and entropy generation of the system are relative to the flight altitude and the current of the TRS.Through the analyses of these data,the optimal values of the COP are obtained,and the optimization measures are proposed to maximize the use of the advantages of the TRS.
文摘This paper presents a low power,truly random number generator （TRNG） based on a simple chaotic map of the Bernoulli shift,which is extended to remain robustness in implementation. The map is realized by switched-current techniques that can fully integrate it in a cryptosystem on a chip. A pipelined architecture post-processed by a simple XOR circuit is used to improve the entropy. The TRNG is fabricated in an HJTC 0.18μm CMOS mixed signal process,and the statistical properties are investigated by measurement results. The power consumption is only 1.42mW and the truly random output bit rate is 10Mbit/s.
文摘With the entropy generation minimization （EGM） method, the thermodynamical performance optimization in a thermoelectric refrigeration system is studied. The optimization is affected by the irreversibility of heat transfer caused by finite temperature differences, the heat leak between external heat reservoirs and the internal dissipation of working fluids. EGM is taken as an objective function for the optimization. The objective function and design parameters are obtained. Optimal performance curves are presented by thermal and electronic parameters. Effects of these parameters on general and optimal performances are investigated. Results are helpful in determining optimal design conditions in real thermoelectric refrigeration systems.
文摘The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ensemble (GCE) that the kinetic energy distribution of the solute is a common characteristic of the entropy and the distribution of solute zones.Under the assumptions. EI of the solute system is directly proportional to the logarithm of the difference between one and one half of the substantial separation ratio. the ratio of moles of a sparated solute to its total moles. and EIPUT is direchy proportional to corrected separation rate of separation system. EI or EIPUT is a important bridge between separation efficiency of chromatography or electrophoresis and operating parameters, especially. when nonequilibriumthermodynamics(NET) would be adopted.
基金Projects(51134013,51171037,51101024)supported by the National Natural Science Foundation of China
文摘The oxidation behaviors of high-entropy alloys AlxCoCrFeNi(x=0.15, 0.4) in supercritical water at 550 and 600 °C were studied, and compared with HR3 C steel. All oxide films formed on alloys are composed of spinel type(Fe, Cr)3O4 oxides. Compared with the oxide film on HR3 C steel, thinner oxide films with smaller size of oxide particles were realized on Al0.15 CoCrFeNi and Al0.4CoCrFeNi, indicating a superior oxidation resistance of Al0.15 CoCrFeNi and Al0.4CoCrFeNi to HR3 C steel. Electrochemical test results reveal that surface oxide films greatly affect the electrochemical corrosion behavior of the oxidized alloys in 3.5% Na Cl solution. The relatively high corrosion resistance of oxidized Al0.15 CoCrFeNi and HR3 C is attributed to the formation of thick and multi-layer oxides.
文摘A thrust for looking multifunctional materials for applications in civil engineering structures has attracted interest among researchers across the globe.Cement based Ba0.85Ca0.15Zr0.1Ti0.88Sn0.02O3(BCZT.Sn)composites were prepared for electrocaloric applications with varying BCZT.Sn to cement ratio.Hysteresis loops showed some signature of saturation in cement composites.However,loops of pure sample were saturated due to its ferroelectric nature.Furthermore,these composites were explored for the first time in solid state refrigeration technology namely electrocaloric effect(ECE).Peak electrocaloric performance shows an adiabatic temperature changes of 0.71,0.64 and 0.50 K and isothermal entropy changes of 0.86,0.80 and 0.65 J/(kg.K)for BCZT.Sn,10%and 15%cement composites,respectively,under application of 0-29 kV/cm electric field.The adiabatic temperature change in cement based composites is comparable with that of the BCZT-Sn ferroelectric ceramics.Furthermore,the dielectric constant(εr)of composites with different ceramic contents at room temperature reveals that dielectric constant increases with an increase in BCZT-Sn proportion in composites.These cement based BCZT.Sn composite materials may be used in solid state refrigeration as they are fairly competitive with the pristine sample.
文摘We study the dynamics of the entropy correlations and entanglement in a system of interaction of a superconducting charge qubit with a single-mode resonant cavity subject to noise considered as two-state random phase telegraph noise. We show that although the noise has an apparent suppressing effect on the evolution of the entropies of the qubit and the field and also on the entanglement in the system, the entropy exchange between the qubit and the field is independent of it during the time evolution of the system.
基金supported by the National Natural Science Foundation of China(No.21403041 and No.21503048)the Startup Packages from Guizhou Education University
文摘In this work, we discussed the stochastic thermodynamics of mesoscopic electron transfer reactions between ions and electrodes. With a relationship between the reaction rate con- stant and the electrode potential, we find that the heat dissipation βq equals to the dynamic irreversibility of the reaction system minus an internal entropy change term. The total en- tropy change Ast is defined as the summation of the system entropy change As and the heat dissipation/βq such that △st=△s＋βq. Even though the heat dissipation depends linearly on the electrode potential, the total entropy change is found to satisfy the fluctuation theo- rem 〈e-△st 〉=1, and hence a second law-like inequality reads （△st）≥0. Our study provides a practical methodology for the stochastic thermodynamics of electrochemical reactions, which may find applications in biochemical and electrochemical reaction systems.
