用延迟脉冲场电离方法测量Na原子里德堡态的寿命

用可调谐激光两步激发布居Na原子高激发ns和nd态。在167V／cm的静电场中，借助stark混合使Na原子两步激发禁戒的nP态得到布居。用延迟脉冲场电离方法测量了ns（n=20～24）、np（n=19～23）和。nD（n=19～23）态的寿命。并对影响寿命的因素作了讨论。

QIF和MW模糊度分解方法的比较

基于准电离层方法和Melbourne-Wübbena(MW)方法,选择不同长度的基线利用实测数据进行分析,探讨两种方法对不同长度基线的适用性,为实际应用中模糊度分解方法的选择提供依据。

电离层残差辅助北斗三频伪距载波相位组合周跳探测

提出一种基于单差模型的电离层残差辅助伪距相位组合周跳探测方法。基于北斗三频实测数据,以波长、电离层延迟系数与噪声为约束条件,优化选取3个线性无关的超宽巷(EWL)、宽巷(WL)组合(0,-1,1)、(1,4,-5)、(4,-2,-3),并利用伪距相位组合法进行周跳的探测与修复。实验结果表明,这3个组合甚至可以实时探测出原始频点上1周的小周跳。针对三频伪距相位组合周跳探测法可能出现的误探情况,提出利用电离层残差法辅助三频伪距相位组合周跳探测的方法,即首先利用原始观测量求出历元间电离层残差,再将相邻历元间所求的历元间电离层残差二次作差。实验表明,该方法可以实时准确地探测与修复不同基线下单差的各类大小周跳。

薄层色谱-质谱联用技术及其进展

概述了薄层色谱同质谱的联用 (TLC MS)技术及其进展 ,着重介绍了TLC MS联用技术中的多种接口及已经开始广泛使用的几种较先进的电离方法。

大科学家与高师——记C.M.霍尔、R.米里肯与他们的导师F.F.朱艾特教授

美国的欧柏林音乐文理大学是一所著名的学府,有着优良的传统和较高的学术水平,曾经培养出三位诺贝尔奖获得者和一位大发明家。本文主要介绍C.M.霍尔在F.F.朱艾特教授指导下发明铝电解法的全过程和他经营铝企业的一生以及他的捐献对山西铭贤学校的影响。欧柏林大学、美国化学界为霍尔的发明举行了多次庆祝活动。他也获得"佩尔津奖章奖"这一国际殊荣。霍尔创办的美国铝业公司现在仍是美国的大企业之一。他的事迹对美国的化学工业和其他工业以及世界铝业的发展都有重要影响。

长波超长波传播色散对通信解码的影响

色散效应是造成无线通信信道码间串扰的主要因素之一.就长波超长波传播色散对通信解码的影响进行了讨论.根据长波超长波在地-电离层波导中和海水中传播的模方程计算出传播色散对信号的衰减特性;分析了在典型条件下长波超长波传播色散对通信造成的误码特性;最后根据长波超长波传播色散的衰减特性提出了对其进行补偿的有效方法,使传播色散对通信误码的影响减小到最低程度.

Determination of brominated diphenyl ethers in atmospheric particulate matter using selective pressurized liquid extraction and gas chromatography–mass spectrometry with a negative chemical ionization

This study describes the development and validation of a sensitive and reliable method for determination of polybrominated diphenyl ethers（PBDEs）in atmospheric particulate matter using selective pressurized liquid extraction（SPLE）and gas chromatography–mass spectrometry with a negative chemical ionization（GC-NCI-MS）.Extraction and clean-up were performed using PLE with 2 g florisil and 3 g silica placed in the extraction cells.Under optimal conditions,14 PBDEs were extracted at 70℃ using hexane/dichloromethane（50：50,v/v）as solvent.Validation of SPLE returned excellent recoveries for most analytes,with relative standard deviations mostly below20%.Method detection limits ranged from 0.13 to15.38 ng·mL^-1 for the GC-MS analyses.The method was successfully applied to atmospheric particulate matter of Beijing,where analytes were detected in the range of182.79 to 468.99 pg·m^-3.

Recovery of Dyestuffs from Dilute Solution with Two-phase Electrophoresis

Two-phase electrophoresis was used to separate the dyestuffs from their dilute solutions. Several dyestuffs (naphthol green B, acid-chrome blue K, methyl blue and direct fast torquoise blue GL, and n-butanol) were treated in a self-designed experimental setup and the mass transfer characteristics in this process were studied. The results confirm the potential of this technique for recovering dyestuffs from their dilute solutions.

Synthesis and Ionic Conduction of Cation-deficient Apatite La9.33-2x/3MxSi6O26 Doped with Mg, Ca, Sr

Apatite-type lanthanum silicate with special conduction mechanism via interstitial oxygen has attracted considerable interest in recent years. In this work, pure powder of La9.33 2x/3MxSi6O26 （M=Mg, Ca, Sr） is prepared by the sol-gel method with sintering at 1000℃. The powder is characterized by X-ray diffraction （XRD） and scanning electron micrograph （SEM）. The apatite can be obtained at relatively low temperature as compared to the conventional solid-state reaction method. The measurements of conductivity of a series of doped samples La9.33-2x/3MxSi6O26 （M=Ca, Mg, Sr） indicate that the type of dopant and the amount have a significant effect on the conductivity. The greatest decrease in conductivity is observed for Mg doping, following the Ca and the Sr doped apatites. The effect is ultimately attributed to the amount of oxygen interstitials, which is affected by the crystal lattice distortion arising from cation vacancies.

State-to-state Photoionization Dynamics of Vanadium Nitride by Two-color Laser Photoionization and Photoelectron Methods

We have conducted a two-color visible-ultraviolet （VIS-UV） resonance-enhanced laser pho- toionization and pulsed field ionization-photoelectron （PFI-PE） study of gaseous vana- dium mononitride （VN） in the total energy range of 56900-59020 cm-1. The VN molecules were selectively excited to single rotational levels of the intermediate VN（D3H0, v＇=0） state by using a VIS dye laser prior to photoionization by employing a UV laser. This two-color scheme allows the measurements of rovibronically selected and re- solved PFI-PE spectra for the VN＋（X2A; v＋=0, 1, and 2） ion vibrational bands. By simulating the rotationally resolved PFI-PE spectra, J＋=3/2 is determined to be the lowest rotational level of the ground electronic state, indicating that the symmetry of the ground VN＋ electronic state is 2A3/2. The analysis of the PFI-PE spectra for VN＋ also yields accurate values for the adiabatic ionization energy for the formation of VN＋（X2A3/2）, IE（VN）=56909.5＋0.8 cm-1 （7.05588±0.00010 eV）, the vibrational fre- quency wc＋=1068.0±0.8 cm-1, the anharmonicity constant wc＋Xe＋=5.8±0.8 cm-1, the rotational constants Be＋=0.6563±0.0005 cm-1 and ae＋=0.0069±0.0004 cm-1, and the equi-librium bond length, re＋=1.529A, for VN＋（X2A3/2）; along with the rotational constants Bc＋=0.6578i0.0028 cm-1 and a＋=0.0085±0.0028 cm-1, and the equilibrium bond length re＋=1.527A for VN＋（X2As/2）, and the spin-orbit coupling constant A=153.3±0.8 cm-1 for VN＋（X2/k5/2,3/2）. The highly precise energetic and spectroscopic data obtained in the present study are valuable for benchmarking the predictions based on state-of-the-art ab initio quantum calculations.

Precision Tension Control System Using Magnetic Particle Clutch

The control of the stability of the filament tension is one of the crucial techniques ensuring the component quality of the composite materials. The open-loop tension control system, with industrial control computer as the core, magnetic particle clutch as the actuator, equipped with compensation technique is researched and manufactured. It can assure the tension control stability of the yarn in filament winding process and increase the control precision of the whole system.

A new primal-dual path-following interior-point algorithm for linearly constrained convex optimization

In this paper, a primal-dual path-following interior-point algorithm for linearly constrained convex optimization(LCCO) is presented.The algorithm is based on a new technique for finding a class of search directions and the strategy of the central path.At each iteration, only full-Newton steps are used.Finally, the favorable polynomial complexity bound for the algorithm with the small-update method is deserved, namely, O(√n log n /ε).

Optimization strategies for separation of sulfadiazines using Box-Behnken design by liquid chromatography and capillary electrophoresis

Development of effective chromatographic or electrophoretic separation involves judicious deciding of selection of optimal experimental conditions that can provide an adequate resolution at a reasonable run time for the separation of interested components. Box-Behnken factorial design was effectively applied for the separation optimization of eight structurally related sulfonamides using capillary zone electrophorosis and reverse high performance liquid chromatography. Optimum values for volume ratio of THF to H2O in eluent, column temperature and flow rate of eluent are found as 12 to 88, 35℃ and 1.0 mL/min, respectively. Box-Behnken modified optimization model is extended to separation by capillary electrophoresis (CE). While using CE, a satisfactory separation is achieved with a minimum resolution larger than 1.0 for a separation time less than 10 min.

Changes of Resistance During Polyelectrolyte-enhanced Stirred Batch Ultrafiltration

The permeation flux or the resistance in the ultrafiltration process is mainly limited by osmotic pressure, and it may originate from various kinds of polymer interactions. However, the real origin of permeation resistance hasn＇t been clarified yet in the light of polymer solution nature. The removal of nitrate contamination by polyelectrolytes was carried out with stirred batch ultrafiltration. The polyelectrolyte concentrations both in permeate and retentate were analyzed with total organic carbon analyzer and permeate mass was acquired by electronic balance connected with computer. The total resistance was calculated and interpreted based on the osmotic pressures in three concentration regimes. In the dilute region, the resistance was proportional to polymer concentration; in the semidilute region, the resistance depended on polymer concentration in the parabolic relationship; in the highly concentrated solution regime, the osmotic pressure factor （OPF） would dominate the total resistance; and the deviation from OPF control could come from the electrostatic repulsion between the tightly compacted and charged polyelectrolyte particles at extremely concentrated solution regime. It was first found that dilute and semidilute concentration regions can be easily detected by plotting the leg-log curves of the polymer concentration versus the ratio of the total resistance to polymer concentration. The new concept OPF was defined and did work well at highly concentrated regime.

Separation of chalcopyrite and pyrite from a copper tailing by ammonium humate

Copper tailings constitute a large proportion of mine wastes. Some of the copper tailings can be recycled to recover valuable minerals. In this paper, a copper tailing was studied through the chemical analysis method, Xray diffraction and scanning electron microscope-energy dispersive spectrum. It turned out that chalcopyrite(Cu) and pyrite(S) were the main recoverable minerals in the tailing. In order to separate chalcopyrite from pyrite in low pulp pH, ammonium humate(AH) was singled out as the effective regulator. The depression mechanism of AH on the flotation of pyrite was proved by FTIR spectrum and XPS spectrum, demonstrating that there was a chemical adsorption between AH and pyrite. By Response Surface Methodology(RSM), the interaction between AH, pulp pH and iso-butyl ethionine(Z200) was discussed. It was illustrated that the optimal dosage of AH was 1678 g·t^(-1) involving both the recovery of Cu and S. The point prediction by RSM and the closed-circuit flotation displayed that the qualified Cu concentrate and S concentrate could be obtained from the copper tailing.The study indicated that AH was a promising pyrite depressor in the low pulp pH from copper tailings.

Importance of Food Physics, to Fulfill the Expectations of Modern Food Technologies

The paper deals with some questions of important aspects of food safety and application of principles of food physics in the food sector. Food production and processing of quality food and safe food are today of primary importance. Food production is based on the principles of Good Agricultural Practice （GAP）, Good Manufactoring Practice （GMP） and Good Hygiene Practice （GHP）. Recently, the industrial food processing is focused dominantly on the quality, and one of the basic requirements of the quality is the safety. There are different methods and techniques to produce safe food. The up-to-date food technologies and quality measurements （quality control and quality assurance） involve the application of different physical methods, e.g., high pressure, pulsing electrical field, nondestructive techniques, e.g., nuclear magnetic resonance （NMR）, near infrared reflectance, near infrared transmittance （NIR-NIT）, photo acoustic spectroscopy （PAS） and instrumental neutron activation analysis （INAA） for chemical composition determination, radiation techniques, nanofiltration and reverse osmosis （RO） as well. Using ionizing radiation （nuclear methods） and non-ionizing radiation technologies, it is possible to fulfill a lot of expectations： decrease of microbial contamination, improve of sensory properties, increase of storability, etc..

Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte

A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by LiF and PF5 at room temperature(20-30℃)for 4 h.The synthesized LiPF6 was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF6 reaches 99.98%.Thermal stability of self-synthesized LiPF6 was analyzed by differential thermal analysis and thermogravimetry.The results indicate that the self-synthesized LiPF6 has higher purity,lower impurity contents and better thermal stability than the commercial LiPF6.

Effects of various sintering methods on microstructure and mechanical properties of CP-Ti powder consolidations

Effects of various sintering methods such as spark plasma sintering(SPS), hot pressing(HP) and electric resistance sintering(ERS) on the microstructure and mechanical properties of commercial pure titanium(CP-Ti) powder consolidations with particle size of <147 μm, <74 μm and <43 μm were studied. The smaller particle powders are densified to proceed at a higher rate. Dense titanium with relative density up to 99% is found to take place at 850 °C under 30 MPa of SPS and HP condition. However, in case of ERS, CP-Ti powders were densified almost at 950 °C under 30 MPa. The microstructure of sintered titanium is composed of equiaxed grains at 850-950 °C. The yield strength of sintered body composed of <43 μm powder is 858 MPa by using SPS at 850 °C under 30 MPa. When there is a higher content of small particle, the higher yield strength value is obtained both by using SPS and HP. However, when ERS is introduced, the highest yield strength is 441 MPa at 950 °C under 30 MPa, which shows much lower values than those by SPS and HP methods. ERS method takes much less sintering time compared with SPS and HP. Nevertheless, higher sintering temperature results in lower strength and elongation because of brittle fracture.

Recovering metals from printed circuit board scrap by a mechanical separation process

A mechanical separation process was developed for recovering metals from printed circuit board(PCB) scrap;it included three steps:impact crushing,sieving and fluidization separation.The mechanism of the technique was based on the difference in the crushabilities of metallic and nonmetallic materials in the PCBs that led to the concentrated distribution of metals in particles of larger sizes and nonmetals mostly in particles of smaller sizes.It was found that crushed PCB particles from 0.125 mm to 1.000 mm contained about 80% of metals in the PCBs.Metals acquired satisfactory liberation in particles smaller than 0.800 mm.The crushed PCB particles were sieved into fractions of different size ranges.Each fraction separately went through a gas-solid fluidized bed operating at a selected optimal gas velocity for the specific size range.Approximately 95% of metals in printed circuit board particles from 0.125 mm to 0.800 mm was recovered by the gas-fluidized bed separator at the selected optimal gas velocity.However,separation of metals from particles smaller than 0.125 mm was not satisfactory.Further study is needed on metal recovery from fine particles.

Calculation of the Safety Factor of the Ohmic HL-2A Single Null Divertor Discharge

The safety most important factor profile is one of the the plasma discharge. For limiter configuration, people usually use the following cylindrical approximation formula to calculate it q（r）=5r^2BT/RIp where r is the minor radius of the plasma toms, R is the major radius （in m） , BT is the toroidal magnetic field （in T）, Ip is the total toroidal current（in MA）.