霍尔推力器通道宽度对电离特性的影响

为了研究霍尔推力器通道宽度对电离特性的影响,采用以数值模拟为主、实验验证为辅两种手段相结合的方式。所建立的数学模型是基于蒙特卡洛方法的二维完全动力学粒子模型,实验选择了与等离子体无接触的光谱诊断方法。计算和实验两方面的结果都发现随着宽度的增加,电子电离工质气体的速率增加,电离更加有效,而且电离区域变得集中的规律。通过进一步的计算发现,电离特性的明显差异和电子与壁面碰撞频率随宽度增加而减小,电子温度随之升高有着密切关系。电子温度升高一方面会对电离特性起到促进作用,另一方面也会使电离消耗的能量增加。由于稳态时的电子温度是由电子能量平衡机制决定的,因此对电子能量平衡方程进行深入分析之后发现,在研究通道宽度影响电离特性这一物理问题上,电子在壁面上的能量损失是决定电子温度的主导因素,而电离损失仅属于次要因素,宽度增加有利于改善推力器的电离特性。

类探月返回试验器稀薄气体电离特性分析

探月返回试验器以接近第二宇宙速度再入,绕流气体将发生较为严重的化学反应和电离,传统上发生在连续流区的通信黑障大幅向稀薄区域延伸。本文基于自主开发的稀有组分权重因子方法的DSMC计算平台,采用公开的外形和与探月返回试验器相似的飞行条件,针对第一次再入、第一次跳出和第二次再入的稀薄流域,重点考察类探月返回试验器的稀薄气体电离特性。通过电子数密度预测通信中断发生高度,其结果与飞行试验观测值具有良好的一致性,误差在2 km以内。计算结果还表明,与RAM-C II等细长体的联合电离不同,对于类探月返回试验器的大钝头体再入,主要电离来源是N、O与中性分子或原子碰撞导致的直接电离。

磁约束放电的电离特性研究

应用蒙特卡罗(Monte Carlo)方法模拟研究了磁约束Ar放电中的电离,考察了30 pd—4 kPa气压范围内横向磁场对电离的影响,得到了磁场作用的有效气压范围(低于600Pa)及最佳磁场值的概念。通过分析,对于磁约束放电方式有了进一步的认识,并对这种放电方式在一般离子激光器及溅射型金属激光器中的应用进行了讨论。

电离层特性影响下提升短波通信质量方法探析

短波通信在进行远距离通信时使用天波传输,天波主要靠大气层中电离层反射,针对短波天波随参信道信号稳定性差、容易遭受干扰等特点,进一步分析电离层特性对短波通信的影响因素,进而发现短波通信频率选择与电离层特性的匹配规律,从而改善短波天波传输时的信号质量与稳定性。

用电离层特性参量提取等效风场信息

导出了利用中低纬电离层特性参量获取电离层F层峰区高度上等效风场（包含电场和风场信息在内）的基本方程,并尝试用该方法从电离层特性参量（峰高和临频）提取等效风场信息.利用武汉站 DGS-256电离层数字测高仪数据及由美国 Massachusetts Lowell大学最新版的剖面反演程序换算得到F层峰高,获得了武汉地区夏季至日点附近、冬季至日点附近、冬季地磁特别宁静的九天和冬季平均等效风场的初步特征.并利用 Fejer经验电场模式计算冬季电场引起的垂直漂移,估计电场和风场对武汉地区的垂直等效风场的贡献大小.结果表明:等效风场呈现出白天与夜晚幅度和方向的差异、至日点附近冬季与夏季白天的幅度差异以及明显的凌晨凹陷现象;平均情况下,垂直等效风场幅度和方向的变化主要是由中性风引起,受电场的影响不大.

计算电离层VLF波传输特性的时域有限差分算法

在星载甚低频（VLF）通信技术中,研究甚低频信号在电离层中的传输特性具有重要意义。现有的利用时域有限差分（FDTD）算法研究电离层传输特性大多基于高频脉冲信号,且传播模型相对粗略,计算存在一定误差。为此,建立了更为精确的电离层各向异性传播模型,对常规的FDTD算法引入变步长因子,并用该算法对VLF波在电离层中的场强衰减进行了数值计算,研究了昼夜变化及频率对其传输特性的影响。仿真结果与卫星实测数据对比表明：与常规的FDTD算法以及全波分析方法相比,引入变步长因子的FDTD算法精度更高;在VLF频段,降低频率有利于电磁波穿透电离层,且白天的衰减明显大于夜间;VLF波在射入电离层并穿透D层时衰减严重（30-40 d B）,约为F1层中衰减的3倍。

电离层延迟及其特性的公式推导

电离层延迟是影响全球导航卫星系统(GNSS)导航定位精度的重要来源,而如何正确理解测距码和载波受到的电离层延迟及其特性一直是本科教学中的重点、难点问题。本文从相、码速度,即相速和群速的计算作为出发点,通过公式严格推导出对应的电离层延迟,并直观地获取了电离层延迟特性.

表面活性剂水溶液池热核沸腾传热的试验研究

对表面活性剂SDS、CTAB、Triton X-114和Triton X-100水溶液物性及其池核沸腾传热进行了试验,重点探讨了表面活性剂分子结构参数和溶液物性对沸腾传热的影响。结果表明:表面活性剂溶液沸腾传热效果、表面活性剂相对分子质量对表面活性剂溶液沸腾传热的影响规律都与表面活性剂的电离特性密切相关,离子型表面活性剂SDS与CTAB溶液的沸腾传热系数比值与相对分子质量的比值成-0.22的指数关系,而非离子表面活性剂Triton X-114和Triton X-100溶液不存在指数关系。动态表面张力和热流密度相等时,SDS和CTAB溶液沸腾传热特性差异主要受相对分子质量和平衡接触角的影响,而Triton X-100和Triton X-114溶液则受质量分数、EO基团数、浊点和动力黏度的综合作用。

电解质概念教学中存在的问题及解决对策

通过对学生访谈和作业反馈情况来看,学生对电解质概念的内涵和外延存在不同程度的曲解.通过对教材概念的呈现方式、教学过程和学习方式的反思后提出：电解质概念的教学不宜利用导电实验引入,不宜用导电性作为判断依据;相关练习未能澄清概念关键点;电解质概念教学让学生感受到了过多挫败感,而非成就感.最后提出电解质概念教学应强化本质特征,突出电离特性,促进概念理解.

Analysis of GPS ionospheric scintillation signal amplitude fading characteristics at low latitude

The received satellite signal amplitude is attenuated greatly due to the strong ionospheric scintillation for lowlatitude regions, which causes the GPS tracking loop＇s loss of lock, the positioning errors to increase, and navigation to be interrupted. To solve the above problems, a novel signal processing algorithm is proposed based on the GPS L1 software receiver during strong ionospheric scintillation using the multi-channel intermediate frequency（IF） data sampling system. Tens of thousands of fading events are obtained based on the signal intensity measurement. The amplitude fading characteristics in the lowlatitude region are analyzed,including fading duration, time separation between fades and the numbers of signal intensity fading events. The fading thresholds are set to be 15 and 10 dB, respectively. The main fading time is very short in- 15 dB fading threshold, which generally is less than 20 ms. The main time separation between fades is less than 2 s in a single one-hour period from the time 23： 00 to 24： 00. Therefore, it has the characteristic of a short reacquisition time for the receiver designed to reduce the probability of simultaneous loss of lock for some satellites.Subsequently, the acquisition, tracking and PVT（position,velocity and time） calculations are completed by the customdesigned software receiver. The results show that the impact analysis of ionospheric scintillation on GPS amplitude attenuation in the lowlatitude region is helpful for designing the advanced tracking algorithm and to improve the robustness and accuracy of the GPS receiver.

基于极光光谱图像的氧辐射特征仿真推演

极光分光光谱仪成像所得重要辐射特征包括氧原子所激发的557.7、630.0、636.4 nm谱线,这些谱线和入射电离层的高能电子能通量、中高层大气粒子成分密度等都有着紧密联系.本文结合引发极光的电子碰撞反应物理机制构建氧辐射特征仿真模型,利用极光光谱图像557.7、630.0 nm谱线估计最接近真实成像情况下的入射电子能通量,实验结果表明仿真中基于假设光强比推演得到的氧辐射谱线像素预测值较真实值高估了1~1.29倍.

Interaction Between Charge Characteristics and Cu^(2+) Adsorption-Desorption of Soils with Variable or Permanent Charge

Charge characteristics and Cu2+ adsorption-desorption of soils with variable charge (latosol) and permanent charge (brown soil) and the relationship between them were studied by means of back-titration and adsorption equilibrium respectively. The amount of variable negative charge was much less in variable-charge soil than in permanent-charge soil and increased with the pH in the system, but the opposite trend occurred in the points of zero charge (PZCs). The amount of Cu2+ ions sorbed by permanent-charge soil was more than that by variable-charge soil and increased with the increase of Cu2+ concentration within a certain range in the equilibrium solution. The amount of Cu2+ ions desorbed with KC1 from permanent-charge soil was more than that from variable-charge soil, but the amount of Cu2+ ions desorbed with de-ionized water from permanent-charge soil was extremely low whereas there was still a certain amount of desorption from variable-charge soil. The increase of PZC of soils with variable or permanent charge varied with the increment of Cu2+ ions added. When the same amount of Cu2+ ions was added, the increments of PZC and variable negative surface charge of permanent-charge soil were different from those of variable-charge soil.

Synthesis and Ionic Conduction of Cation-deficient Apatite La9.33-2x/3MxSi6O26 Doped with Mg, Ca, Sr

Apatite-type lanthanum silicate with special conduction mechanism via interstitial oxygen has attracted considerable interest in recent years. In this work, pure powder of La9.33 2x/3MxSi6O26 （M=Mg, Ca, Sr） is prepared by the sol-gel method with sintering at 1000℃. The powder is characterized by X-ray diffraction （XRD） and scanning electron micrograph （SEM）. The apatite can be obtained at relatively low temperature as compared to the conventional solid-state reaction method. The measurements of conductivity of a series of doped samples La9.33-2x/3MxSi6O26 （M=Ca, Mg, Sr） indicate that the type of dopant and the amount have a significant effect on the conductivity. The greatest decrease in conductivity is observed for Mg doping, following the Ca and the Sr doped apatites. The effect is ultimately attributed to the amount of oxygen interstitials, which is affected by the crystal lattice distortion arising from cation vacancies.

Effect of Specific Adsorption of Ions on Electrokinetic Properties of Variable Charge Soils

Studies were carried out by using electrophoretic method on the effects of the specific adsorption of the anions,such as SO4^2-,PO4^3-,and F^- ions,the cations,such as Ca^2+,Mn^2+,Zn^2+,and Cu^2+,ions,and the anions and cations coexisting,such as Zn^2+ and SO4^2= ions,on electrokinetic properties of the red soils as typical variable charge soils in China concerning variation in the specific ion species and concentrations,with an emphasis on the interaction between soil colloid surfaces and the ions in soil solutions.The results showed that the adsorption of specific ions led to a very pronounced decrease in zeta potentials of the soil colloids and a shift of the IEPs to lower values for specific anions,and an obvious increase in zeta potentials of the soil colloids and a shift of the IEPs to higher values for specific cations.Under circumstances of the specific anions and cations coexisting,for instance,Zn^2+ and SO4^2- ions,the zeta potentials changed with values higher than the value for SO4^2- alone and lower than that for Zn^2+ alone,and the IEP was between that for Zn^2+ and that for SO4^2-.The adsorption of Zn^2+ and Cu^2+ ions resulted in a reversal of the zeta potentials,and appearance of two IEPs for Zn^2+ and no IEP for Cu^2+,exhibiting interesting special effects of these kinds of metal ions.The higher the concentrations of the ions,the greater the change of the electrokinetic properties.

Photo-electrochemical Lithium Insertion Characteristics of Carbon Nanotubes Modified with SrTiO3 Photocatalyst

Perovskite-type SrTiO3 nanoparticles were synthesized by direct hydrolysis-precipitation method and were employed to modify the surface of the carbon nanotubes to form a SrTiO3/CNTs composite. The photoelectrochemical lithium insertion characteristics of the SrTiO3/CNTs composite under xenon light irradiation were investigated. The results show that the light irradiation has little influence on the specific capacity of the CNTs electrode. However, for the SrTiO3/CNTs electrode irradiated by light, the lithium insertion capacity reaches about 251 mAh/g, much higher than that without light irradiation （170 mAh/g）. Cyclic voltammetry test reveals that the light irradiation can remarkably increase the reaction currents of lithium insertion and extraction. This may be attributed to the photo-excited intercalation of Li-ions into the CNTs by the SrTiO3 photocatalyst when irradiated by light.

Effect of modified starches on depression of diaspore

Four modified starches with selected charge characteristics including cationic starch(CAS),carboxymethyl starch(CMS),amphoteric starch(AMS) and soluble starch(SS) were investigated as depressants for diaspore in reverse flotation test using cationic collector(dodecylamine).Adsorption examination,Zeta potential measurement and Fourier transform infrared(FTIR) spectroscopy were used to clarify the role of the surface charge characteristics of starches in determining the adsorption behavior and depression performance as well as the mineral-starch interaction.Results show that the positively charged starches(CAS and AMS) display higher adsorption amounts and also better depression performance compared with the non-ionic(SS) and anionic starch(CMS),benefiting from the favorable electrostatic attraction with diaspore and also electrostatic repulsion with collector.FTIR spectroscopy proves the presence of hydrogen bonds and chemical complexation between mineral and starches in an integrated manner.

The Study of the Varying Characteristics of Cathodic Regions for Defective Coating in 3.5% Sodium Chloride Solution by EIS and WBE

The current distributions over carbon steel under iron red alkyd primer exposed to 3.5% sodium chloride solution were mapped using the wire beam electrode （WBE）. The electrochemical impedance spectroscopy （EIS） of the WBE was carded out to analyze the performance of coating delamination and corrosion behavior of carbon steel beneath defective coating. The EIS data revealed that protective capability of coating decreased with immersion time and the degree of cathodic delamination showed a rapid rise. The current density distribution of WBE indicated that cathodic sites was located at the defect at the beginning of immersion and gradually spread into the intact coating. The cathodic regions were distinguished from the anodic area and distributed over the WBE. The changes of cathodic sites could reflect the deterioration process of defective coating. The cathodic area ratio was a more useful parameter than the cathodic delamination degree to evaluate the coating cathodic delamination. The polarity reversals of electrodes at the defect and beneath coating were observed. A simple discussion of relationship between the blister and the polarity reversal was made from a standpoint of electrochemical distribution. WBE method was able to map and record the changes of local cathodic sites beneath defective coating in real time, which could provide more detailed information about the local degradation of coating.

Experimental study on thermal characteristics of LiFePO_4 power batteries

As an important high-energy chemical power source, lithium-ion power batteries come up to application problems of thermal performance, such as extended temperature range and high power charge ＆ discharge. LiFeP04 battery is applied and developed well recently, its charge and discharge experiment at different temperatures and hybrid pulse power characterization （HPPC） test are analyzed, and the optimal temperature range of LiFeP04 battery is put forward. In order to provide experimental suggestion of power battery application and its thermal management, internal resistance, influencing factor of electromotive force and entropy change state of charge （SOC）, battery thermal characteristic of different charge ＆ discharge rates are summarized.

The Effect of Ionizing Radiation and Magnetic Field on Deformation Properties of High Density PolyethylenelAcrylonitrile-Butadiene Composites

The effect of magnetic field and ionizing radiation on the mechanical properties of polymer blends consisting of high density polyethylene （HDPE） and acrylonitrile-butadiene rubber （NBR） has been investigated. The purpose of the work was to create HDPE/NBR blend composites of significantly different compositions （with an excess of HDPE, intermediate ones, and with an excess of NBR） and to investigate the role of composition on mechanical deformation properties under the influence of magnetic field. The investigation has importance from the engineering viewpoint, since thermoplastic composite materials have been used as structural elements in thermonuclear and engineering fields, like wires, insulation materials and others, which are frequently subjected to mechanical loadings under the effect of magnetic field greater than 1 T. One part of the blends has been irradiated with 5 MeV accelerated electrons up to absorbed dose D equal to 150 kGy. Unirradiated and the radiation modified blends have been exposed to a constant magnetic field with induction B equal to 1.0 T, 1.5 T and 1.7 T. It is found that the action of magnetic field decreases the elastic modulus of unirradiated materials. Decrement of elastic modulus is reduced with increase of the content of NBR in composites. It is also found that preliminary irradiation noticeably decreases the effect of magnetic field. Data of the influence of the magnetic field, radiation cross-linking, and the ratio of the components on the creep are also obtained.

Characteristics of fulvic acid by high voltage pulse discharge plasma

High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It was shown that： for the reason of thermolysis and oxidation, the pH and Oxidation Reduction Potential （ORP） of solution decreased gradually with the increase of peak voltage and fulvic acid solution concentration, meanwhile the temperature and turbidity of solution increased gradually. Adding hydrochlorid acid in the treatment could amplify the effect of plasma. When the concentration of NOM as the surrogate parameter, Ultraviolet Absorbancy Degree （UV254） increased slowly by the effect of plasma, while the degradation of Total Organic Carbon （TOC） was first-order reaction. The removal rate of TOC increased from 22.6% to 33.4% by high voltage pulse electrical field of 35 kv, and from 25.6% to 36.7% with the addition of hydrochlorid acid. This paper may provide some basis for the scale-up design of water treatment process by high voltage pulse discharge plasma with other technologies.