双电层电粘度对薄膜润滑影响的试验研究与数值分析

由于固液界面处存在双电层,理论和试验研究都表明该效应对薄膜润滑有较为明显的影响。首先,利用自行设计的外加电场重构双电层装置进行了组合滑块水润滑试验,结果分析表明:双电层所引起的电粘度效应对流体润滑中摩擦因数有明显影响,另外当摩擦副的材料不同时,摩擦因数的变化规律不同。然后,又对KCl(氯化钾)溶液进行了组合滑块试验,进一步研究了离子浓度对电粘度效应的影响,在不同速度和溶液浓度的工况下,对摩擦因数进行了测量。结果表明:低浓度溶液使摩擦因数明显增加,浓度高时摩擦因数减小;随着速度的增加,双电层效应对摩擦因数的影响减小。最后,对试验工况进行了数值分析。

双电层电粘度对润滑性能的影响研究

根据双电层理论,建立了关于流体润滑中的双电层引起的电粘度效应的数学模型,并通过组合滑块水润滑试验考察了双电层的电粘度效应对流体润滑性能的影响.结果表明:双电层所引起的电粘度效应对流体润滑下的摩擦系数具有明显影响;当在速度较低时,摩擦系数明显增大;随着速度的增加,摩擦系数增大幅度减小;试验结果同所建立的数学模型相符.

薄膜油润滑中电粘度效应影响研究

利用组合滑块油润滑试验考察了双电层的电粘度效应对薄膜润滑性能的影响,采用施加外加电场和添加添加剂两种方法以改变润滑剂中离子浓度进行试验研究。结果表明:双电层引起的电粘度效应对摩擦因数有明显影响,摩擦因数随着外加电场的增强而变大,当外电场增大到一定程度时摩擦因数开始减小;在离子浓度较小时,摩擦因数随着离子浓度的增加而增大,当离子浓度增大到一定程度时摩擦因数开始减小。

薄膜润滑中双电层效应影响分析

根据Poisson Boltzmann双电层理论, 详细推导了润滑区中双电层产生的流动电场, 并进一步建立了考虑双电层电粘度效应的薄膜润滑数学模型。然后, 对润滑中双电层效应进行了数值分析, 对不同的电粘度公式进行了比较, 结果表明薄膜润滑中, 双电层的电粘度效应使流体粘度显著增加, 同时润滑膜厚也明显增加。

强电场作用下极细颗粒黏土渗流特性分析

采用常水头渗流法试验,利用数据直流电源提供强电场,研究极细颗粒黏土的渗流的电场效应,在相同试验条件下完成了人工高岭土与人工膨润土按一定比例混合的试样的渗流特性测试。测试结果表明,外加电场对极细颗粒黏土的渗流特性有相当显著的影响,随着电场强度的升高,试样的渗透系数呈先减小后增大的趋势;在相同的电场强度下,试样的渗透系数会随着时间逐步变化,最终趋于稳定。对有无电场作用下渗流后的试样分别进行压汞试验,测试结果表明,在强电场作用下黏土颗粒产生重新排列,从而改变了孔隙结构和尺度,使渗透系数有所增加。试验结果分析认为,电场作用下,黏土颗粒和孔隙水都会产生极化现象,土颗粒和水分子在这种静电力作用下作定向排列,从而改变了试样的孔隙分布情况和孔隙水的粘度,进而影响孔隙水渗流特性。

薄膜润滑中双电层效应的理论分析与实验研究

建立了考虑双电层效应的有限宽组合滑块薄膜润滑数学模型,并利用组合滑块与圆盘的滑动摩擦试验对双电层效应进行研究,利用实验结果修正了润滑过程中双电层效应的计算,给出电粘度的计算公式并进行数值分析.结果表明:在薄膜厚度较薄的情况下,双电层效应使得流体的等效粘度随膜厚减小而迅速增加;随着膜厚增加,双电层的电粘度效应逐渐减弱;随着电场强度增加,双电层的电粘度效应增加,当电场强度达到一定程度时,双电层的电粘度效应开始减弱.

鱼类血液电流变特性的初步研究

本文测定了白鲢和花鲢的ηs(b),Kb,EPM ESR和Hct等5个反映血液电流变性质的参数,并分析了它们之间的回归相关关系的形态,发现ηs(b)与Kb,Kb与Hct的回归相关形态与人类血液所具有的形态基本相似,不同的是,鱼血液的Kb与Hct的回归曲线是常用指数函数型,而人类则是自然指数函数型;鱼类也存在受红细胞膜表面电荷数量多寡左右的“电粘度”效应,ηs(b)和EPM二参数的回归关系形态是线性的。本文还讨论了鱼类红细胞的聚集性问题,指出ESR随EPM的增大而按对数规律减小。

Interactions of Cations with Electrodialyzed Clay Fraction of Soils as Inferred from Wien Effect in Soil Suspensions

The electrical conductivities (ECs) of suspensions containing 25 and 30 gkg^(-1) solids prepared from the electrodialyzed clay fraction (< 2μm in diameter) of latosol,yellow-brown soil, and black soil, dispersed in various nitrate solutions having concentrations of 1X 10^(-4)/z mol L^(-1), where z is the valence, and in distilled water, were measured at fieldstrengths ranging from 14 kV cm^(-1) to 210 kV cm^(-1). On the basis of analyses of the chargedensity and exchangeable ion composition on the surfaces of soil particles in the suspensions, andof the characters of the EC-field strength curves of the various suspensions, it was inferred thatthe increment of EC (ΔEC) and/or relative electrical conductivity (REC) can indicate the bondingstrength between cations and soil particles. The bonding strengths of various cations with the soilsdiminished in the order: K^+ > Zn^(2+) > Mg^(2+) = Ca^(2+) > Na^+ for latosol, Ca^(2+) > Zn^(2+) >Mg^(2+) = K^+ > Na^+ for yellow-brown soil, and Zn^(2+) ≥ Ca^(2+) ≥ Mg^(2+) > K^+ > Na^+ for blacksoil.

Separation of Water from Extra-viscous Oil under Microwave Radiation in the Presence of Inorganic Salts

Removal of water contained in extra-viscous crude oil is quite difficult because of the high viscosity and high resins content of heavy oil.The microwave technology was introduced for the separation of water from high-viscosity crude oil in the presence of sodium acetate.The decrease in zeta-potential of interface and the viscosity of crude oil are responsible for the accelerated separation of water under microwave irradiation.The influences of the concentration of sodium acetate in sample,irradiation pressure,irradiation time and irradiation power on the separation efficiency were investigated.The optimum technological condition for the refining process was determined.Upon treating the sample 1 (with a water concentration of 50%),the water removal rate was 98.44%,when the optimum conditions were identified to be a sodium acetate concentration of 2%,an irradiation pressure of 0.1 MPa,an irradiation time of 2 min,and an irradiation power of 225 W,with the recovery of sodium acetate reaching 97.88%.Upon treating the sample 2 (the concentration of water was 20%),the water removal rate was 93.85%,when the optimum conditions were determined to be a sodium acetate concentration of 3%,an irradiation pressure of 0.1 MPa,an irradiation time of 4 min,and an irradiation power of 375 W,with the recovery of sodium acetate reaching 93.54%.By using this method,the dehydration efficiency was increased rapidly.

Densities, conductivities, and viscosities of aqueous solutions of N-hexyl,methylpyrrolidinium bromide and N-butyl, methylpyrrolidinium bromide at different temperatures

The densities, conductivities, and viscosities were measured for ternary solutions of N-hexyl,methylpyrrolidinium bromide([PP1,6]Br)- N-butyl,methylpyrrolidinium bromide([PP1,4]Br)-H2 O and its binary subsystems [PP1,6]Br-H2 O and [PP1,4]Br-H2 O at(298.15, 303.15, 308.15, and 313.15) K, respectively. The results were used to test the predictability of the simple equations established for the prediction of density, conductivity,and viscosity of the mixed electrolyte solutions. The results show that the examined simple equations can offer good predictions for density, conductivity, and viscosity of the mixed ionic liquid solutions in terms of the corresponding properties of its binary subsystems of equal ionic strength.

Shear Viscosity of Hot QED at Finite Chemical Potential from Kubo Formula

Within the framework of finite temperature field theory this paper discusses the shear viscosity of hot QED plasma through Kubo formula at one-loop skeleton diagram level with a finite chemical potential The effective widths (damping rates) are introduced to regulate the pinch singularities and then gives a reliable estimation of the shear viscous coefficient.The finite chemical potential contributes positively compared to the pure temperature case. The result agrees with that from the kinetics theory qualitatively.

The role of the symmetry and the flexibility of the anion on the characteristics of the nanostructures and the viscosities of ionic liquids

The transport properties of ionic liquids(ILs) are crucial properties in view of their applications in electrochemical devices. One of the most important advantages of ILs is that their chemical–physical properties and consequently their bulk performances can be well tuned by optimizing the chemical structures of their ions. This will require elucidating the structural features of the ions that fundamentally determine the characteristics of the nanostructures and the viscosities of ILs. Here we showed for the first time that the "rigidity", the order,and the compactness of the three-dimensional ionic networks generated by the anions and the cation head groups determine the formation and the sizes of the nanostructures in the apolar domains of ILs. We also found that the properties of ionic networks are governed by the conformational flexibility and the symmetry of the anion and/or the cation head group. The thermal stability of the nanostructures of ILs was shown to be controlled by the sensitivity of the conformational equilibrium of the anion to the change of temperature. We showed that the viscosity of ILs is strongly related to the symmetry and the flexibility of the constitute ions rather than to the size of the nanostructures of ILs. Therefore, the characteristics of the nanostructures and the viscosities of ILs, especially the thermal stability of the nanostructures, can be fine-tuned by tailoring the symmetry and the conformational flexibility of the anion.

Experimental study of viscosity characteristics of hightemperature heat transfer molten salts

In this paper several kinds of high temperature molten salts were investigated experimentally on viscosity-temperature characteristics with high-temperature viscometer.The viscosities of the molten salts were measured and compared with those from references to verify the reliability of the viscometer and measuring methods,and a good agreement was observed from the comparisons.Then,two new high-temperature molten salts were made from the HITEC salt by some additives and the viscosity-temperature profiles of them were obtained by experiments.The results show that the new molten salts have much lower viscosities,thus suitable for reducing the flow resistance in transportation system of high-temperature solar thermal power generation.

Method to Calculate Resistance of High-Speed Displacement Ship Taking the Effect of Dynamic Sinkage and Trim and Fluid Viscosity into Account

A method is presented to calculate the resistance of a high-speed displacement ship taking the effect of sinkage and trim and viscosity of fluid into account.A free surface flow field is evaluated by solving Reynolds averaged Navier-Stokes(RANS) equations with volume of fluid(VoF) method.The sinkage and trim are computed by equating the vertical force and pitching moment to the hydrostatic restoring force and moment.The software Fluent,Maxsurf and MATLAB are used to implement this method.With dynamic mesh being used,the position of a ship is updated by the motion of "ship plus boundary layer" grid zone.The hull factors are introduced for fast calculating the running attitude of a ship.The method has been applied to the ship model INSEAN2340 for different Froude numbers and is found to be efficient for evaluating the flow field,resistance,sinkage and trim.

Molecular catalysis for the steam reforming of ethanol

In this paper, the application of molecular catalysis for steam reforming of ethanol （SRE） is reviewed. Eight metals （Ni, Co, Cu Pt, Rh, Pd, Ir and Ru） have shown high catalytic activity for SRE. Among them Ni and Rh are very promising because of high d character in the metal bond and low metal-oxygen bonding （vs. metal-carbon）. They can effectively promote C-C bond cleavage in the rate-determining process during SRE. However, Rh is weak in water-gas-shift so that CH4 and CO become the main by-products at low reaction temperatures, while Ni catalysts suffer from rapid deactivation due to coking and sintering. Two low-temperature CO-free catalysts have been developed in our lab, namely Rh-Fe/Ca-Al2O3 and carbonyl-derived Rh-Co/CeO2, in which the presence of iron oxide or Co can promote water-gas-shift reaction and significantly improve the SRE performance. On the other hand, adding 3 wt% CaO to Ni/Al2O3 can greatly improve the catalyst stability because the Ca modification not only increases Ni concentration on the Ni/Ca-Al2O3 surface and 3d valence electron density, but also facilitates the water adsorption and coke gasification via water-gas-shift. The availability of abundant surface OH groups helps the formation and conversion of adsorbed formate intermediate. Hence, ethanol reaction on Ca-Al2O3-supported Ni, Pt, Pd and Rh catalysts are found to follow the formate-intermediated pathway, a new reaction pathway alternative to the traditional acetate-interrnediated pathway.

Development of limestone calcined clay cement concrete in South China and its bond behavior with steel reinforcement

Limestone calcined clay cement(LC^3),consisting of ordinary Portland cement(OPC)clinker,calcined clay,limestone powder,and gypsum,has been considered a promising solution to current challenges in the cement and concrete industry,such as high carbon emissions,high energy consumption,and resource shortages.This study carries out a series of experimental investigations of LC^3-based paste,mortar,and concrete,including microstructural analyses(e.g.hydration product characterization and pore structure analysis)and macro-scale testing(e.g.workability and mechanical properties),using raw materials from south China.The results show that,in LC^3 paste,the replacement of clinker by calcined clay and limestone leads to an increased volume of small pores but decreased total volume of pores.The workability of LC^3 mortar and concrete can be readily tailored using conventional superplasticizers.When designed for comparable 28-d compressive strength,the LC^3 mortar and concrete tend to have lower early-age compressive strength,but comparable compressive strength and higher flexural strength than those of the OPC counterparts at late ages.This study also examines the bond-slip behavior between LC^3 concrete and steel bars and finds that the bond strength is comparable to that of OPC concrete with the same 28-d compressive strength,but that the LC^3 concrete-rebar interface exhibits higher bond-slip stiffness.These findings on LC^3 concrete provide fundamental information and guidance for furthering the application of LC^3 binder in structural concrete in the near future.

Effects of light curing modes and ethanol-wet bonding on dentin bonding properties

Objective： This study explored the effects of different light curing modes and ethanol-wet bonding on dentin bonding strength and durability. Methods： A total of 54 molars were randomly divided into three groups： Single Bond 2, Gluma Comfort Bond, and N-Bond. Based on the three light-curing modes and presence or absence of eth- anol pretreatment, the samples were assigned to six subgroups： high-light mode, ethanol pretreatment＋high-light mode, soft-start mode, ethanol pretreatment＋soft-start mode, standard mode, and ethanol pretreatment＋standard mode. All samples were bonded with resin based on the experimental groups. After 24 h and 6 months of water storage, a universal testing machine was used to measure microtensile bond strength. Scanning electron microscopy （SEM） was applied to observe mixed layer morphology. Results： The 24-h and 6-month microtensile bond strengths of the ethanol pretreatment groups were significantly higher than those of the non-ethanol pretreatment groups at the same light modes （P〈0.05）. With or without ethanol pretreatment, the microtensile bond strengths of the high-light modes were significantly lower than those of the soft-start modes and standard modes （P〈0.05）. The microtensile bond strengths of samples from the 6-month water storage group significantly decreased compared with those of samples from the 24-h water storage group （P〈0.05）. The soft-start groups and standard groups formed better mixed layers than the high-light mode groups, whereas the ethanol pretreatment groups formed more uniform mixed layers than those without ethanol pretreatment. Conclusions： Ethanol-wet bonding technique, soft-start, and standard modes could improve dentin bonding properties.

Biocompatible liquid metal coated stretchable electrospinning film for strain sensors monitoring system

Liquid metals(LMs)are potential inorganic materials which could be applied in flexible and deformable electronics owing to their fluidity,low viscosity,high metallic conductivity,and low toxicity.However,recently reported sensing devices based on LMs required complex processes with high cost.Herein,a flexible three-dimensional(3 D)conductive network was prepared by coating LM droplets onto an electrospun thermoplastic polyurethane(TPU)fiber film.The LM is suspended between the TPU fibers and self-coalesces into a vertically buckled and laterally mesh-like structure,which provides good biocompatibility,conductivity,and stretchability simultaneously.The LM-TPU composite-filmbased flexible device demonstrates a multitude of desired features,such as a widely workable stretching range(0%-200%),sufficient sensitivity under stretching strain(gauge factor(GF)of 0.2 at 200%strain),and outstanding stability and durability(9000 cycles).In vitro biocompatibility experiments show that the LM-TPU composite film directly attached to the skin has excellent biocompatibility.Such strain sensorbased integrated monitoring systems could monitor human body motions in real time,such as muscle movement and joint motion,revealing application prospects in healthcare and human-machine interfacing.