Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution tr...Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution transmission electron microscope （HRTEM）, energy dispersive X-ray （EDX） spectroscope, X-ray diffraction （XRD）, and X-ray photoelectron spectroscope （XPS） characterizations on the product B show that the thickness of the carbon shells of CEINPs in the product B is in the range of ca. 0.5-5.3 nm, i. e., which can be as thin as only two layers of graphite. The average diameter of the CEINPs is about 24. 7 nm. The total content of Fe element in the product B is 77.0 wt%. The saturation magnetization （Ms） and coercivity （Hc） of the product B are 107.4 emu/g and 143 Oe. resnectivelv. The formation of the CEINPs in the oroduct B is discussed briefly.展开更多
文摘Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution transmission electron microscope （HRTEM）, energy dispersive X-ray （EDX） spectroscope, X-ray diffraction （XRD）, and X-ray photoelectron spectroscope （XPS） characterizations on the product B show that the thickness of the carbon shells of CEINPs in the product B is in the range of ca. 0.5-5.3 nm, i. e., which can be as thin as only two layers of graphite. The average diameter of the CEINPs is about 24. 7 nm. The total content of Fe element in the product B is 77.0 wt%. The saturation magnetization （Ms） and coercivity （Hc） of the product B are 107.4 emu/g and 143 Oe. resnectivelv. The formation of the CEINPs in the oroduct B is discussed briefly.
