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电解负载法制备Pt/Al_2O_3/Al催化剂 被引量:4
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作者 汪利峰 应卫勇 +3 位作者 房鼎业 铃木幸治 樱井诚 龟山秀雄 《华东理工大学学报(自然科学版)》 CAS CSCD 北大核心 2003年第5期452-455,479,共5页
以铝板阳极氧化生成的多孔质氧化膜为载体,采用电解负载法将铂负载在载体上,制得挥发性有机物催化燃烧的催化剂。从催化剂的负载量和催化活性出发,对电解负载的实验条件进行了探讨。研究结果表明,低浓度、低电流密度及较短的电解负载时... 以铝板阳极氧化生成的多孔质氧化膜为载体,采用电解负载法将铂负载在载体上,制得挥发性有机物催化燃烧的催化剂。从催化剂的负载量和催化活性出发,对电解负载的实验条件进行了探讨。研究结果表明,低浓度、低电流密度及较短的电解负载时间是较适宜的催化剂制备条件。实验还表明,利用电解负载法负载的催化组分在催化剂中分布均匀。 展开更多
关键词 挥发性有机物 Pt/Al2O3/Al催化剂 催化燃烧 电解负载
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中温固体氧化物燃料电池阳极基底及负载型电解质薄膜的研制 被引量:19
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作者 阎景旺 董永来 +1 位作者 于春英 江义 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2001年第5期804-814,共11页
在用固相反应法合成电解质材料La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)的基础上,研制出中温固体氧化物燃料电池LSGM+NiO阳极基底;考察了阳极基底孔隙率、孔径分布及电导率随组成变化的规律;研究了阳... 在用固相反应法合成电解质材料La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)的基础上,研制出中温固体氧化物燃料电池LSGM+NiO阳极基底;考察了阳极基底孔隙率、孔径分布及电导率随组成变化的规律;研究了阳极基底组成、微观结构、制备工艺等对负载型LSGM电解质薄膜成膜过程及质量的影响和负载型电解质薄膜在还原气氛中的结构稳定性;采用湿化学物理方法及等静压烧结工艺成功地制备出了厚度为20~50μm的负载型致密LSGM电解质薄膜.研究表明;NiO含量为60%的阳极基底具有适宜的烧结收缩率、孔隙率与孔径分布,且比表面积与比孔容积均较大,适合作为SOFC的阳极.随着NiO含量的增加,还原后阳极基底的电导率有所增大.其中低NiO含量的阳极基底在还原后的初生态,其电导率在交变信号的诱导下发生弛豫现象而迅速增大,并由离子导电性转变为金属导电性.而高NiO含量的阳极基底,其还原后的电导率随测量时间的延长变化很小,并从一开始就表现出金属导电的性质.采用无约束烧结程序制备的负载型LSGM电解质薄膜,表面为粗大的片状晶粒,还原后在晶界处产生裂纹.而采用等静压烧结程序制备的负载型LSGM电解质薄膜,表面为细小、形状规则的晶? 展开更多
关键词 中温 固体氧化物 燃料电池 阳极基底 负载电解质薄膜 LSGM 性能 电解质材料 合成
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Analytical Study, 1-D Optimization Modeling, and Testing of Electrode Supported Solid Oxide Electrolysis Cells
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作者 D.G. Milobar P.W. Li J.E. O'Brien 《Journal of Energy and Power Engineering》 2010年第7期15-26,共12页
This paper presents a straightforward model studying the performance of a solid oxide electrolysis cell at less computational effort while is still comprehensive accounting for details of all physics involved. The mod... This paper presents a straightforward model studying the performance of a solid oxide electrolysis cell at less computational effort while is still comprehensive accounting for details of all physics involved. The model is one dimensional and can be used to optimize SOECs that have composite electrodes. It includes an average mass transfer analysis used to simulate concentration polarization, activation polarization, as well as ohmic loss. The electrochemical reaction that occurs within the electrode functional layers has been accounted for in the calculation of the concentration polarization. This is believed to give a more realistic view of the mass transfer that occurs in SOECs with composite electrodes via a simple and straightforward one dimensional model. Experimental work with SOECs also has been done and some results are reported. The simulation results are compared with experimental data and the agreement is satisfactory. The model can be conveniently used for optimization of the SOEC electrodes and operational conditions. 展开更多
关键词 High temperature electrolysis solid oxide electrolysis cells hydrogen production.
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Ferroresonance at Open Phase Operating Conditions of Power Transformers
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作者 Hani Obeid 《Journal of Energy and Power Engineering》 2012年第10期1714-1717,共4页
The reliability of electric supply to consumers is one of the most important factors that determine the requirements imposed on modem utility companies. This paper presents the results of investigation by computer sof... The reliability of electric supply to consumers is one of the most important factors that determine the requirements imposed on modem utility companies. This paper presents the results of investigation by computer software of the overvoltages resulting from a ferroresonance conditions in MV networks at open phase operating condition with and without connection to earth on source and load sides of distribution transformer. This overvoltage may reach 4.2 pu on one of the HV side of transformer unswitched phases. The results of the study show that ferroresonance overvoltage may be controlled by replacing fuses with circuit breakers on HV side to ensure switching-off all phases. Insertion of resistor or reactor in the neutral of source and loadsides of the transformer with 5% active load will help in suppressing overvoltages. 展开更多
关键词 FERRORESONANCE OVERVOLTAGE open phase operating condition non-linear inductance.
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